Harnessing the potential of MOF-derived metal oxide composites to optimize energy efficiency in batteries and supercapacitors

Journal of Energy Storage, Год журнала: 2024, Номер 87, С. 111447 - 111447

Опубликована: Март 26, 2024

Язык: Английский

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Electrolytes for Sodium Ion Batteries: The Current Transition from Liquid to Solid and Hybrid systems

Advanced Materials, Год журнала: 2024, Номер 36(35)

Опубликована: Май 29, 2024

Sodium-ion batteries (NIBs) have recently garnered significant interest in being employed alongside conventional lithium-ion batteries, particularly applications where cost and sustainability are relevant. The rapid progress NIBs will undoubtedly expedite the commercialization process. In this regard, tailoring designing electrolyte formulation is a top priority, as they profoundly influence overall electrochemical performance thermal, mechanical, dimensional stability. Moreover, electrolytes play critical role determining system's safety level lifespan. This review delves into recent advancements from liquid (organic ionic liquid) to solid quasi-solid (dry, hybrid, single ion conducting electrolyte) for NIBs, encompassing comprehensive strategies design across various materials, systems, their functional applications. objective offer strategic direction systematic production of safe investigate potential these designs real-world scenarios while thoroughly assessing current obstacles forthcoming prospects within rapidly evolving field.

Язык: Английский

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A Review of Anode Materials for Dual-Ion Batteries

Nano-Micro Letters, Год журнала: 2024, Номер 16(1)

Опубликована: Июль 24, 2024

Distinct from "rocking-chair" lithium-ion batteries (LIBs), the unique anionic intercalation chemistry on cathode side of dual-ion (DIBs) endows them with intrinsic advantages low cost, high voltage, and eco-friendly, which is attracting widespread attention, expected to achieve next generation large-scale energy storage applications. Although electrochemical reactions anode DIBs are similar that LIBs, in fact, match rapid insertion kinetics anions consider compatibility electrolyte system also serves as an active material, materials play a very important role, there urgent demand for rational structural design performance optimization. A review summarization previous studies will facilitate exploration optimization future. Here, we summarize development process working mechanism exhaustively categorize latest research their applications different battery systems. Moreover, design, reaction briefly discussed. Finally, fundamental challenges, potential strategies perspectives put forward. It hoped this could shed some light researchers explore more superior advanced systems further promote DIBs.

Язык: Английский

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Computational approach inspired advancements of solid-state electrolytes for lithium secondary batteries: from first-principles to machine learning

Chemical Society Reviews, Год журнала: 2024, Номер 53(6), С. 3134 - 3166

Опубликована: Янв. 1, 2024

The utilization of computational approaches at various scales, including first-principles calculations, MD simulations, multi-physics modeling, and machine learning techniques, has been instrumental in expediting the advancement SSEs.

Язык: Английский

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Inorganic All‐Solid‐State Sodium Batteries: Electrolyte Designing and Interface Engineering

Advanced Materials, Год журнала: 2023, Номер 36(1)

Опубликована: Сен. 20, 2023

Inorganic all-solid-state sodium batteries (IASSSBs) are emerged as promising candidates to replace commercial lithium-ion in large-scale energy storage systems due their potential advantages, such abundant raw materials, robust safety, low price, high-energy density, favorable reliability and stability. solid electrolytes (ISSEs) an indispensable component of IASSSBs, gaining significant attention. Herein, this review begins by discussing the fundamentals ISSEs, including ionic conductivity, mechanical property, chemical electrochemical stabilities. It then presents crystal structures advanced ISSEs (e.g., β/β''-alumina, NASICON, sulfides, complex hydride halide electrolytes) related issues, along with corresponding modification strategies. The also outlines effective approaches for forming intimate interfaces between working electrodes. Finally, current challenges critical perspectives developments possible directions improve interfacial contacts future practical applications highlighted. This comprehensive aims advance understanding development next-generation rechargeable IASSSBs.

Язык: Английский

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Engineering, Understanding, and Optimizing Electrolyte/Anode Interfaces for All-Solid-State Sodium Batteries

Electrochemical Energy Reviews, Год журнала: 2024, Номер 7(1)

Опубликована: Июль 4, 2024

Язык: Английский

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Synthesis and assessment of novel Na2S dispersed high performance nanocomposite gel polymer electrolyte intended for sodium batteries and electric double layer capacitors

Journal of Energy Storage, Год журнала: 2024, Номер 86, С. 111280 - 111280

Опубликована: Март 16, 2024

Язык: Английский

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Interface issues and challenges for NASICON-based solid-state sodium-metal batteries

Advanced Powder Materials, Год журнала: 2024, Номер 3(3), С. 100181 - 100181

Опубликована: Фев. 28, 2024

All-solid-state sodium (Na)-metal batteries (ASSSMBs) are considered promising candidates for large-scale energy storage systems due to their abundant resources, unparalleled safety performance, and impressive density. Na superionic conductors (NASICONs) among the best enablers of ASSSMBs in view high ionic conductivity, ease synthesis, excellent thermal stability good electrochemical/chemical compatibility with common electrodes. However, challenges surrounding NASICON/electrode interface, such as interfacial resistance dendrite formation, have hindered development practical based on NASICONs. This review starts an explicit summary interface problems between metallic anode NASICON arising from mechanical, chemical, electrochemical aspects (i.e., poor contact, insulating side-reaction products, irregular growth). Subsequently, we systematically analyze logically categorize modification strategies addressing provide a comprehensive discussion underlying enhancement mechanisms. As such, identify universal mechanisms by comparatively studying various strategies. Furthermore, briefly summarize cathode/electrolyte early-stage research efforts constructing stable fabricating high-performance composite cathodes. Finally, key suggestions future prospectives advancement NASICON-based outlined.

Язык: Английский

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Cobalt- and copper-doped NASICON-type LATP polymer composite electrolytes enabling lithium titania electrode for solid-state lithium batteries with high-rate capability and excellent cyclic performance

Journal of Energy Storage, Год журнала: 2024, Номер 95, С. 112559 - 112559

Опубликована: Июнь 17, 2024

Язык: Английский

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Insights into Tiny High‐Entropy Doping Promising Efficient Sodium Storage of Na₃V₂(PO₄)₂O₂F toward Sodium‐Ion Batteries

Advanced Energy Materials, Год журнала: 2024, Номер unknown

Опубликована: Окт. 31, 2024

Abstract Both high operation voltage and theoretical capacity promise polyanion‐type fluorophosphate Na 3 V 2 (PO 4 ) O F as a competitive cathode toward high‐energy‐density sodium‐ion batteries (SIBs). However, the intrinsic low kinetic characteristics seriously influence its high‐power property service life. To well address this, creative tiny high‐entropy (HE) doping methodology is purposefully developed to fabricate nanoscale 1.94 (Cr, Mn, Co, Ni, Cu) 0.06 (NVPOF‐HE) advanced materials for SIBs. The grain refinement effect induced by collaborative regulations from polyvinyl pyrrolidone HE heteroatomic reasonably proposed nanosizing particle dimension of NVPOF‐HE. Systematic experiments calculations authenticate that efficiently promotes electronic/ionic transport high‐voltage contribution, weakens lattice expansion over + ‐(de)intercalation processes. Thanks appealing virtues mentioned here, nano NVPOF‐HE, compared single‐ion/dual‐ion/triple‐ion doped cases, achieves even better ‐storage performance in terms both high‐rate capacities long‐term cycling stability. Furthermore, NVPOF‐HE assembled full SIBs deliver materials‐level energy density 463 Wh kg −1 electrochemical stability ≈93.8% retention after 1000 cycles at 5 C rate. More essentially, fundamental insights gained here provide significant scientific technological advancement high‐performance durable polyanionic cathodes next‐generation

Язык: Английский

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