Langmuir,
Год журнала:
2024,
Номер
40(36), С. 19228 - 19238
Опубликована: Авг. 26, 2024
The
hydrogenation
of
4-nitrophenol
using
carbon
dot-stabilized
gold
(Au)
nanoparticles
is
well-studied,
with
Au-H
species
known
to
catalyze
the
reaction.
However,
impact
specific
nitrogen
moieties
in
nitrogen-doped
dots
on
formation
and
catalytic
activity
remains
unexplored.
These
species,
acting
as
surface
ligands,
may
influence
properties
through
generation
via
H
ACS Omega,
Год журнала:
2024,
Номер
9(22), С. 23573 - 23583
Опубликована: Апрель 24, 2024
This
study
delves
into
the
green
synthesis
and
multifaceted
applications
of
three
types
carbon
quantum
dots
(CQDs),
namely,
CQDs-1,
CQDs-2,
CQDs-3.
These
CQDs
were
innovatively
produced
through
a
gentle
pyrolysis
process
from
distinct
plant-based
precursors:
genipin
with
glucose
for
extracted
gardenia
seeds
whole
Advanced
analytical
techniques,
including
X-ray
photoelectron
spectroscopy
(XPS)
Fourier-transform
infrared
(FT-IR),
employed
to
detail
CQDs'
structural
surface
characteristics,
revealing
their
unique
functional
groups
chemistries.
The
further
explores
bioimaging
potential,
where
confocal
fluorescence
microscopy
evidenced
swift
uptake
by
RSC Advances,
Год журнала:
2025,
Номер
15(9), С. 6974 - 6983
Опубликована: Янв. 1, 2025
The
effective
removal
of
nitrophenols
from
wastewater
is
crucial
due
to
their
high
carcinogenic
risk.
This
research
presents
the
development
a
copper-based
metal-organic
framework
(HKUST-1)
integrated
into
chitosan-graft-poly(acrylic
acid)
hydrogel.
hydrogel
composite
was
evaluated
as
catalyst
for
reducing
and
dyes
using
sodium
borohydride
(NaBH4)
agent.
Various
conditions
were
investigated
reduction
4-nitrophenol
(4-NP)
less
harmful
4-aminophenol
(4-AP),
including
dosage,
NaBH4
concentration,
initial
4-NP
temperature,
pH.
able
completely
reduce
within
25
minutes
at
dosage
3
g
L-1
concentration
300
mM.
rate
increased
with
higher
temperatures,
an
Arrhenius
activation
energy
54.4
kJ
mol-1.
Common
anions
found
in
surface
water,
such
Cl-,
NO3
-,
SO4
2-,
HCO3
had
slight
impact
on
4-NP.
When
tested
real
water
environments,
decreased,
but
complete
conversion
still
achieved.
Additionally,
successfully
reduced
100%
2-nitrophenol,
methyl
orange,
69%
Congo
red.
Overall,
has
shown
significant
potential
various
organic
pollutants
efficiency
easy
separation
through
filtration.
ACS Applied Materials & Interfaces,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 21, 2025
As
a
type
of
century-old
catalyst,
the
use
iron-based
materials
runs
through
Haber–Bosch
process
and
electrochemical
synthesis
ammonia
because
its
excellent
capability,
low
cost,
abundant
reserves.
How
to
continuously
improve
catalytic
activity
stability
for
nitrogen
fixation
has
always
been
goal
pursued
by
scientific
researchers.
Herein,
we
develop
free-standing
i.e.,
iron
nanoparticles
with
zinc
oxide
nanowire
array
support
(Fe/ZnO
NA),
which
exhibits
high
yield
∼54.81
μg
h–1
mgcat.–1
Faradaic
efficiency
(FE)
∼9.56%
in
0.5
M
potassium
hydroxide
solution,
along
good
reusability
durability.
Its
electrocatalytic
ability
is
superior
that
commercial
Fe
most
reported
Fe-based
catalysts,
thus
showing
great
competitiveness.
This
ZnO
NA
not
only
supplies
stable
homogeneous
dispersion
but
also
provides
very
beneficial
synergy
their
activity.
The
work
renews
traditional
catalysts
significance
promoting
industrialization
synthesis.