Solvent-Controlled Silver Catalyzed Radical Transformation of α-Imino-Oxy Acids with Cyclic Aldimines
Chemical Communications,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 1, 2025
A
silver-catalyzed
cross
coupling
of
cyclic
aldimines
and
α-imino-oxy
acids
has
been
developed.
The
solvent-dependent
reaction
could
selectively
deliver
either
imine
moiety
retained
nitriles
or
ring-opened
oxonitriles
in
moderate
yields.
Язык: Английский
Silver-catalyzed direct decarboxylative C H functionalization of azauracils with aliphatic carboxylic acids
Tetrahedron Letters,
Год журнала:
2025,
Номер
unknown, С. 155619 - 155619
Опубликована: Апрель 1, 2025
Язык: Английский
Mild Hydroalkylation of Terminal Olefins Via Decatungstate/Thiol Cooperative Photocatalysis
Organic Letters,
Год журнала:
2025,
Номер
unknown
Опубликована: Апрель 23, 2025
Here
we
report
the
use
of
a
tetrabutylammonium
decatungstate
(TBADT)/thiol
photocatalytic
system
for
selective
addition
acetone
and
other
simple
ketone,
nitrile,
chlorocarbon
functionalities
to
terminal
olefins.
This
avoids
energetic
reagents
such
as
peroxides
proceeds
under
mild
conditions
using
Earth-abundant
element
catalysts,
providing
sustainable
approach
C-C
bond
formation
activated
Initial
exploration
reveals
that
hydroalkylation
unactivated
olefins
is
also
possible,
though
in
lower
efficiency,
preliminary
mechanistic
experiments
are
consistent
with
radical
mechanism.
Язык: Английский
Photoinduced α-addition and hydrogenation of carbazole-based alkenes
Green Synthesis and Catalysis,
Год журнала:
2025,
Номер
unknown
Опубликована: Май 1, 2025
Язык: Английский
Photocatalyzed Acylation of Azauracil Derivatives with Aldehydes
The Journal of Organic Chemistry,
Год журнала:
2024,
Номер
89(15), С. 11083 - 11087
Опубликована: Июль 24, 2024
A
novel
approach
for
the
acylation
of
azauracil
derivatives
with
aldehydes
has
been
developed
utilizing
sodium
decatungstate
(NaDT)
as
a
photocatalyst.
This
method
demonstrates
broad
substrate
tolerance
and
yields
moderate
to
excellent
outcomes.
Notably,
it
aligns
green
chemistry
principles
by
eliminating
oxidants,
eco-friendly
energy
sources,
offering
high
scalability
operational
simplicity.
Язык: Английский