Metal–organic frameworks as highly effective platforms for enzyme immobilization–current developments and future perspectives DOI Creative Commons
Justyna Rogacka, Karolina Labus

Brazilian Journal of Chemical Engineering, Год журнала: 2024, Номер unknown

Опубликована: Окт. 18, 2024

Abstract This study presents a thorough overview of metal–organic frameworks’ (MOFs) utility as supports for enzyme immobilization. It details bibliometric analysis the field from 2014–2023, based on 911 Web Science articles. Research outlines functional properties MOFs, groups, and common immobilization techniques. showcases diverse enzyme-MOF combinations numerous applications, including industrial biocatalysis, medical diagnostics, drug development, biomass conversion, environmental protection, biosensor creation. Current development trends future directions are identified through literature analysis. Latent Dirichlet Allocation (LDA) modeling revealed key research themes over years, highlighting shifts in focus towards advanced catalytic methods adsorption Additionally, word cloud generated 2024 publications indicates an increasing emphasis specialized applications involving ZIFs, nanoparticles, magnetic structures. Key perspectives include new MOF materials, such biologically derived core–shell hierarchical porous nanoMOFs, mesoporous MOFs. Novel materials inspired by carriers, covalent organic frameworks (COFs) aerogels (MOAs), also highlighted. Lastly, emphasizes potential multienzymatic systems multifunctional MOF-enzyme composites, facilitating multiple functionalities within single system.

Язык: Английский

Enhanced catalytic performance of Candida rugosa lipase through immobilization on zirconium-2-methylimidazole: A novel biocatalyst approach DOI
Yaaser Q. Almulaiky, Tariq Altalhi, Reda M. El‐Shishtawy

и другие.

International Journal of Biological Macromolecules, Год журнала: 2024, Номер 279, С. 135211 - 135211

Опубликована: Авг. 30, 2024

Язык: Английский

Процитировано

10

MOF/Chitosan Composites: An Emerging Class of Multifunctional Materials for Diverse Applications DOI
Karzan A. Abdalkarim, Diary I. Tofiq, Rebaz F. Hamarawf

и другие.

Journal of Inorganic and Organometallic Polymers and Materials, Год журнала: 2025, Номер unknown

Опубликована: Март 14, 2025

Язык: Английский

Процитировано

2

Covalently immobilized β-galactosidase onto a novel alginate/lemon peel carrier: Catalytic, kinetic, stability studies, and its application in the production of whey high-protein beverage DOI Creative Commons
Mohamed A.A. Abdella, Mohamed E. Hassan, Tarek N. Soliman

и другие.

International Journal of Biological Macromolecules, Год журнала: 2025, Номер unknown, С. 142222 - 142222

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

2

Designable immobilization of D-allulose 3-epimerase on bimetallic organic frameworks based on metal ion compatibility for enhanced D-allulose production DOI

Huayang Tang,

Yi‐An Chen,

Dexun Fan

и другие.

International Journal of Biological Macromolecules, Год журнала: 2024, Номер 273, С. 133027 - 133027

Опубликована: Июнь 9, 2024

Язык: Английский

Процитировано

7

Innovative immobilization of β-glucosidase on amidoximated acrylic fabric integrated with magnetite Fe3O4 nanoparticles DOI
Yaaser Q. Almulaiky, Sami A. Al‐Harbi

International Journal of Biological Macromolecules, Год журнала: 2025, Номер unknown, С. 141172 - 141172

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

1

An Overview of Microorganisms Immobilized in a Gel Structure for the Production of Precursors, Antibiotics, and Valuable Products DOI Creative Commons
Dmitriy Berillo,

Turganova Malika,

B.B. BAIMAKHANOVA

и другие.

Gels, Год журнала: 2024, Номер 10(10), С. 646 - 646

Опубликована: Окт. 10, 2024

Using free microorganisms for industrial processes has some limitations, such as the extensive consumption of substrates growth, significant sensitivity to microenvironment, and necessity separation from product and, therefore, cyclic process. It is widely acknowledged that confining or immobilizing cells in a matrix support structure enhances enzyme stability, facilitates recycling, rheological resilience, lowers bioprocess costs, serves fundamental prerequisite large-scale applications. This report summarizes various cell immobilization methods, including several synthetic (polyvinylalcohol, polyethylenimine, polyacrylates, Eudragit) natural (gelatin, chitosan, alginate, cellulose, agar-agar, carboxymethylcellulose, other polysaccharides) polymeric materials form thin films, hydrogels, cryogels. Advancements production well-known antibiotics like penicillin cephalosporin by strains were discussed. Additionally, we highlighted cutting-edge research related strain producers peptide-based (polymyxin B, Subtilin, Tyrothricin, varigomycin, gramicidin S, friulimicin, bacteriocin), glusoseamines, polyene derivatives. Crosslinking agents, especially covalent linkers, significantly affect activity stability biocatalysts (penicillin G acylase, penicillinase, deacetoxycephalosporinase, L-asparaginase, β-glucosidase, Xylanase, urease). The molecular weight polymers an important parameter influencing oxygen nutrient diffusion, kinetics hydrogel formation, rigidity, rheology, elastic moduli, mechanical properties crucial long-term utilization. A comparison enzymatic between immobilized enzymes their native counterparts was explored. discussion not limited recent advancements biopharmaceutical field, microorganism immobilization, but also extended methods used sensor biosensor In this study, present data on advantages over (bacteria fungi) suspension states produce bioproducts metabolites-such antibiotics, enzymes, precursors-and determine efficiency optimal conditions process parameters maximize yield target products.

Язык: Английский

Процитировано

4

In-situ co-immobilization of lipase, lipoxygenase and L-cysteine within a metal-amino acid framework for conversion of soybean oil into higher-value products DOI
Xiaoxiao Liu, Kai Li,

Luona Ye

и другие.

Food Chemistry, Год журнала: 2024, Номер 458, С. 140187 - 140187

Опубликована: Июнь 24, 2024

Язык: Английский

Процитировано

3

NiII-containing l-glutamic acid cross-linked chitosan anchored on Fe3O4/f-MWCNT: a sustainable catalyst for the green reduction and one-pot two-step reductive Schotten–Baumann-type acetylation of nitroarenes DOI Creative Commons
Hossein Mousavi, Behzad Zeynizadeh, Morteza Hasanpour Galehban

и другие.

Nanoscale Advances, Год журнала: 2024, Номер 6(15), С. 3961 - 3977

Опубликована: Янв. 1, 2024

In this research, new catalytic applications of the Fe 3 O 4 / f -MWCNT-CS-Glu/Ni II nanocomposite have been introduced for efficient reduction and one-pot two-step reductive Schotten–Baumann-type acetylation nitroarenes in water.

Язык: Английский

Процитировано

3

Synthesis of UiO–66–NH2(Ti/Zr) and its Catalytic Conversion of Cellulose to 5-HMF DOI
Lingling Xu, Xiaomei Pan,

Lijing Gao

и другие.

Catalysis Letters, Год журнала: 2025, Номер 155(2)

Опубликована: Янв. 2, 2025

Язык: Английский

Процитировано

0

Valorization of food wastes by catalytic metal–organic frameworks/chitosan platform and microalgae cultivation DOI Open Access

Nguyễn Hoàng Ly,

Tan Phat Dao, Lalitha Gnanasekaran

и другие.

Journal of the Science of Food and Agriculture, Год журнала: 2025, Номер unknown

Опубликована: Фев. 11, 2025

Abstract Innovative technologies can convert food waste into an economic opportunity. A potential approach to be discussed in this review article is combining microalgae cultivation with catalytic metal–organic frameworks (MOFs) and chitosan platforms. Due the high availability of nutrients organic content, classified as one most promising feedstocks for bioprocessing. MOFs are known surface area, modulable porosity, property adsorb molecules thus being recently used efficient catalysts related valorization wastes. Chitosan a natural polyelectrolyte copolymer exhibiting excellent biological properties, making it attractive platform fabricate diverse biomedical materials. The recent research proposes another use – resource producing high‐value In particular, studies concentrate on designing molecular porous MOF platforms applications valorization. One important would tailor synthetic properties functionalities chitosan‐based allowing them efficiently utilized. facile strategy established herein provides new way combine converting desirable biomass. This delivers future‐oriented idea regarding how co‐participated harvesting followed by perspective challenges future. © 2025 Society Chemical Industry.

Язык: Английский

Процитировано

0