Green Chemistry,
Год журнала:
2022,
Номер
24(15), С. 5813 - 5821
Опубликована: Янв. 1, 2022
COF-derived
nitrogen-doped-carbon
structure
supported
palladium
catalysts
exhibited
excellent
EOR
and
MOR
activities,
much
higher
than
those
of
commercial
Pd/C,
with
good
catalytic
stability.
ACS Catalysis,
Год журнала:
2023,
Номер
13(14), С. 9633 - 9655
Опубликована: Июль 8, 2023
As
a
class
of
persistent
pollutants
that
are
easily
bioaccumulatable
and
highly
biotoxic,
chlorinated
organic
exist
in
the
environment
pose
substantial
threat
to
ecological
safety.
The
electrocatalytic
hydrodechlorination
(EHDC)
technology
shows
advantages
high
efficiency,
simple
operation,
mild
reaction
conditions,
no
secondary
pollution
thus
promises
good
application
prospect
treatment
chlorine-containing
pollutants.
Pd-based
catalysts
considered
most
efficient
for
electroreductive
dechlorination
far,
yet
reserves
Pd
scarce,
price
is
often
prohibitively
high.
development
noble
metal
with
atom
utilization
non-noble
EHDC
has
become
hot
research
topic,
but
relevant
reviews
still
lacking.
In
this
paper,
progress
on
during
recent
years
reviewed
influence
catalyst
microstructure
regulation
performance
discussed
detail.
strategies
including
mechanisms
electronic
effect,
support
size
coordination
effect
enhancing
at
different
scales
(from
nanostructures
single
atoms)
summarized
proposed,
which
could
provide
guidance
from
atomic
scale.
At
end
review,
prospects
challenges
also
discussed.
The Chemical Record,
Год журнала:
2021,
Номер
21(8), С. 1985 - 2073
Опубликована: Июль 1, 2021
Design
and
preparation
of
low-cost,
effective,
novel
catalysts
are
important
topics
in
the
field
heterogeneous
catalysis
from
academic
industrial
perspectives.
Recently,
heteroatom-doped
porous
carbon/metal
materials
have
received
significant
attention
as
promising
divergent
organic
reactions.
Incorporation
heteroatom
into
carbon
framework
can
tailor
properties
carbon,
providing
suitable
interaction
between
support
metal,
resulting
superior
catalytic
performance
compared
with
those
traditional
pure
systems.
In
this
review,
we
try
to
underscore
recent
advances
design,
preparation,
application
towards
various
transformations.