Tuning the morphology of supramolecular aggregates for nanocarrier‐based drug delivery DOI Open Access

Xiongtao Ji,

Na Wang, Jingkang Wang

и другие.

AIChE Journal, Год журнала: 2024, Номер unknown

Опубликована: Дек. 22, 2024

Abstract Due to the unique drug delivery mode and specific therapy, nano‐formulations are of interest for biomedical applications treating many diseases. However, traditional method nano‐formulation construction via additional carriers or structural modifications therapeutic drugs might be cumbersome low loading‐efficient. Herein, kinetics, accessible pathways, final outcomes supramolecular assembly processes investigated in detail. It was found that aggregates cephradine (CEP) undergoes a morphological transformation from anisotropic nanofiber (EtOH) isotropic spherical nanoparticle (H 2 O), similar “plants took root, sprouted, blossomed bore fruit.” Moreover, kinetics results reveal pathways nucleation elongation H O surface‐catalyzed secondary EtOH. The presented this work has potential used efficiently designing nano‐formulations.

Язык: Английский

Dynamic Tracking of Biological Processes Using Near-Infrared Fluorescent Single-Walled Carbon Nanotubes DOI Creative Commons
Srestha Basu, Adi Hendler‐Neumark, Gili Bisker

и другие.

ACS Applied Materials & Interfaces, Год журнала: 2024, Номер unknown

Опубликована: Окт. 8, 2024

Biological processes are characterized by dynamic and elaborate temporal patterns driven the interplay of genes, proteins, cellular components that crucial for adaptation to changing environments. This complexity spans from molecular organismal scales, necessitating their real-time monitoring tracking unravel active fuel living systems enable early disease detection, personalized medicine, drug development. Single-walled carbon nanotubes (SWCNTs), with unique physicochemical optical properties, have emerged as promising tools such processes. perspective highlights key properties SWCNTs make them ideal monitoring. Subsequently, it surveys studies utilizing track biological phenomena across hierarchical levels─from molecules cells, tissues, organs, whole organisms─acknowledging pivotal role in advancing this field. Finally, review outlines challenges future directions, aiming expand frontier using SWCNTs, contributing deeper insights novel applications biomedicine.

Язык: Английский

Процитировано

6

Metal-Ion Optical Fingerprinting Sensor Selection via an Analyte Classification and Feature Selection Algorithm DOI Creative Commons

Gabriel Petresky,

Michael Faran, Verena Wulf

и другие.

Analytical Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Март 27, 2025

Accurate analyte classification remains a significant challenge in sensor technologies. We present the Analyte Classification and Feature Selection Algorithm (ACFSA), computational tool designed to identify optimal combinations from unique fingerprint patterns for classification. applied ACFSA library of peptide-corona-functionalized single-walled carbon nanotubes (SWCNTs), developed as near-infrared fluorescent, semiselective fingerprinting set detecting heavy metal ions. Inspired by natural metal-ion complexation sites, each SWCNT this features peptide sequence containing various amino acids binding, revealing diverse optical response ions tested. The was further diversified using different chiralities photochemical modifications coronae. screening data fluorescence 30 resulting SWCNT-peptide sensors five analytes. Through iterative dimensionality reduction rational selection, algorithm identified minimal two-sensor with 0.02% error. final output is thus an classifier that serves pattern selected sensors. peptide-SWCNT system effective proof-of-concept, illustrating potential our platform generally applicable analytes selection other sensor–analyte experiments.

Язык: Английский

Процитировано

0

A Review on the Rheological Properties of Single Amino Acids and Short Dipeptide Gels DOI Creative Commons
Sérgio R. S. Veloso,

Mariangela Rosa,

Carlo Diaferia

и другие.

Gels, Год журнала: 2024, Номер 10(8), С. 507 - 507

Опубликована: Авг. 1, 2024

Self-assembled peptide-based hydrogels have attracted considerable interest from the research community. Particularly, low molecular weight gelators (LMWGs) consisting of amino acids and short peptides are highly suitable for biological applications owing to their facile synthesis scalability, as well biocompatibility, biodegradability, stability in physiological conditions. However, challenges understanding structure–property relationship lack design rules hinder development new with required properties several applications. Hereby, plethora gelators, this review discusses mechanical single acid dipeptide-based hydrogels. A mutual analysis these systems allows us highlight between gel sequence, preparation methods, or N capping groups. Additionally, recent advancements tuning gels’ rheological reviewed. In way, present aims help bridge knowledge gap structure properties, easing selection

Язык: Английский

Процитировано

1

Integrating Single-Walled Carbon Nanotubes into Supramolecular Assemblies: From Basic Interactions to Emerging Applications DOI Creative Commons
Verena Wulf, Gili Bisker

ACS Nano, Год журнала: 2024, Номер 18(43), С. 29380 - 29393

Опубликована: Окт. 21, 2024

Integrating single-walled carbon nanotubes (SWCNTs) into supramolecular self-assemblies harnesses the distinctive mechanical, optical, and electronic properties of nanoparticles alongside structural chemical assemblies. Organic molecules capable forming assemblies through hydrophobic, van der Waals, π–π interactions have been demonstrated to be particularly effective in dispersing functionalizing SWCNTs, as these same facilitate binding hydrophobic graphene-like surface SWCNTs. This review discusses a variety self-assembling structures that were shown integrate ranging from simple micelles ring complex DNA origami three-dimensional hydrogels formed by low-molecular-weight gelators. We explore integration SWCNTs various highlight emerging applications composite materials, such mechanical enforcement leveraging near-infrared (NIR) fluorescence for monitoring molecular self-assembly process. Notably, NIR which overlaps with biological transparency window, offers significant opportunities noninvasive sensing within platforms. Future research deeper understanding between different frameworks will expand potential SWCNT-integrated fields like biomedical engineering, devices, environmental sensing.

Язык: Английский

Процитировано

1

Tuning the morphology of supramolecular aggregates for nanocarrier‐based drug delivery DOI Open Access

Xiongtao Ji,

Na Wang, Jingkang Wang

и другие.

AIChE Journal, Год журнала: 2024, Номер unknown

Опубликована: Дек. 22, 2024

Abstract Due to the unique drug delivery mode and specific therapy, nano‐formulations are of interest for biomedical applications treating many diseases. However, traditional method nano‐formulation construction via additional carriers or structural modifications therapeutic drugs might be cumbersome low loading‐efficient. Herein, kinetics, accessible pathways, final outcomes supramolecular assembly processes investigated in detail. It was found that aggregates cephradine (CEP) undergoes a morphological transformation from anisotropic nanofiber (EtOH) isotropic spherical nanoparticle (H 2 O), similar “plants took root, sprouted, blossomed bore fruit.” Moreover, kinetics results reveal pathways nucleation elongation H O surface‐catalyzed secondary EtOH. The presented this work has potential used efficiently designing nano‐formulations.

Язык: Английский

Процитировано

0