Industrial Crops and Products, Год журнала: 2024, Номер 222, С. 119641 - 119641
Опубликована: Сен. 17, 2024
Язык: Английский
Annual Review of Chemical and Biomolecular Engineering, Год журнала: 2023, Номер 14(1), С. 141 - 163
Опубликована: Март 8, 2023
Are deep eutectic solvents (DESs) a promising alternative to conventional solvents? Perhaps, but their development is hindered by plethora of misconceptions. These are carefully analyzed here, beginning with the very meaning DESs, which has strayed far beyond its original scope mixtures Lewis or Brønsted acids and bases. Instead, definition that grounded on thermodynamic principles distinguishes between encouraged, types precursors can be used prepare DESs reviewed. Landmark works surrounding sustainability, stability, toxicity, biodegradability these also discussed, revealing piling evidence numerous reported thus far, particularly those choline based, lack sufficient sustainability-related traits considered green solvents. Finally, emerging DES applications reviewed, emphasizing most remarkable feature: ability liquefy solid compound target property, allowing use as liquid solvent.
Язык: Английский
Процитировано
194
Pharmaceuticals, Год журнала: 2024, Номер 17(1), С. 124 - 124
Опубликована: Янв. 18, 2024
The extraction of bioactive compounds pharmaceutical interest from natural sources has been significantly explored in recent decades. However, the techniques used were not very efficient terms time and energy consumption; additionally, solvents for harmful environment. To improve environmental impact extractions at same increase yields, several new developed. Among most ones are ultrasound-assisted microwave-assisted extraction. These increased yield selectivity a smaller amount with decrease consumption. Nevertheless, high volume organic was still extraction, causing subsequent problem. Neoteric appeared as green alternatives to solvents. neoteric solvents, deep eutectic evidenced be one best due their intrinsic characteristics. considered because they made up such sugars, amino acids, carboxylic acids having low toxicity degradability. In addition, simple prepare, an atomic economy 100%, attractive physicochemical properties. Furthermore, huge number that can synthesize these make them useful since tailored selective towards specific component or class components. main aim this paper is give comprehensive review which describes properties, characteristics, production methods well its application extract interest. Additionally, overview more sustainable also given.
Язык: Английский
Процитировано
59
Energy & Environmental Science, Год журнала: 2023, Номер 17(3), С. 867 - 884
Опубликована: Дек. 26, 2023
This review highlights deep-eutectic solvents for green recycling of spent Li-ion battery cathodes towards future commercialization.
Язык: Английский
Процитировано
54
ChemSusChem, Год журнала: 2023, Номер 16(20)
Опубликована: Июль 18, 2023
Abstract In the spirit of circular economy and sustainable chemistry, use environmentally friendly chemical products in pharmacy has become a hot topic. recent years, organic solvents have been subject great range restriction policies due to their harmful effects on environment toxicity human health. parallel, deep eutectic (DESs) emerged as suitable greener with beneficial environmental impacts rich palette physicochemical advantages related low cost biocompatibility. Additionally, DESs can enable remarkable solubilizing effect for several active pharmaceutical ingredients (APIs), thus forming therapeutic (TheDESs). this work, special attention is paid DESs, presenting precise definition, classification, methods preparation, characterization. A description natural (NaDESs), i. e., present sources, also reported. Moreover, review article first one detail different approaches judiciously selecting constituents order minimize number experiments. The role biomedical sectors impact development successful therapies are discussed.
Язык: Английский
Процитировано
48
Food Chemistry, Год журнала: 2024, Номер 444, С. 138629 - 138629
Опубликована: Фев. 3, 2024
Язык: Английский
Процитировано
38
Carbohydrate Polymers, Год журнала: 2024, Номер 338, С. 122199 - 122199
Опубликована: Апрель 26, 2024
Язык: Английский
Процитировано
32
Advanced Functional Materials, Год журнала: 2025, Номер unknown
Опубликована: Янв. 2, 2025
Abstract The rapid expansion of the global economy has led to a surge in energy demand, resulting significant environmental pollution and scarcity due concomitant increase greenhouse gas emissions. advancement deep eutectic solvents (DESs) introduced viable substitute for traditional processing methods, boasting numerous intrinsic benefits, such as superior eco‐compatibility, outstanding thermal stability, desirable electrochemical properties. Consequently, DESs have garnered attention from research community, demonstrating broad spectrum prospective applications variety fields instance energy, biomass degradation, materials synthesis, biomedicine. This review aims offer comprehensive methodical overview DESs, encompassing their historical development, classification, preparation methodologies, fundamental physicochemical Furthermore, this explores synthesis various functional examines multifunctional roles. Crucially, economic viability is thoroughly examined, including an assessment cost‐effectiveness market potential. Finally, concludes by outlining future directions development challenges that remain.
Язык: Английский
Процитировано
8
Journal of Molecular Liquids, Год журнала: 2022, Номер 362, С. 119696 - 119696
Опубликована: Июнь 24, 2022
Язык: Английский
Процитировано
46
International Journal of Biological Macromolecules, Год журнала: 2023, Номер 243, С. 125219 - 125219
Опубликована: Июнь 5, 2023
Язык: Английский
Процитировано
35
Journal of Cleaner Production, Год журнала: 2023, Номер 434, С. 139914 - 139914
Опубликована: Дек. 1, 2023
Язык: Английский
Процитировано
27