Highly efficient photoenzymatic CO2 reduction dominated by 2D/2D MXene/C3N5 heterostructured artificial photosynthesis platform

Journal of Colloid and Interface Science, Год журнала: 2024, Номер 678, С. 1121 - 1131

Опубликована: Авг. 22, 2024

Язык: Английский

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Nonporous and porous silica-polyethylene composite membrane attached FDH for carbon dioxide conversion to formate and its application in a photo-enzyme coupled system

Separation and Purification Technology, Год журнала: 2025, Номер unknown, С. 131656 - 131656

Опубликована: Янв. 1, 2025

Язык: Английский

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Rh-functionalized Imino-pyridine Covalent Organic Framework Assembled on Ti₃C₂T_x (MXene) for Efficient NADH Regeneration and Photoenzymatic CO₂ Reduction

ACS Sustainable Chemistry & Engineering, Год журнала: 2025, Номер unknown

Опубликована: Март 4, 2025

Nicotinamide adenine dinucleotide (NADH) regeneration is crucial for sustainable enzymatic CO2 reduction. In this study, Ti3C2Tx (MXene) and [Cp*Rh(bpy)(H2O)]2+ (labeled as [Cp*Rh]) were sequentially assembled onto imino-pyridine structured covalent organic frameworks (TD-COF) to construct Rh@TDM photocatalysts with dual cocatalyst. The photoelectrochemical tests temperature-dependent photoluminescence spectra suggest that the synergistic effect of incorporation [Cp*Rh] immobilization enables a reduction in exciton binding energy promotes carrier transfer. Consequently, optimized [email protected] photocatalyst achieves 95.0% NADH yield, significantly higher than TD-COF free (32.7%). Additionally, modification strategy applied also enhances selectivity 1,4-NADH. Therefore, turnover frequency 1,4-NADH 1.06 h–1, which 7.1 times (0.15 h–1). Subsequently, photoenzymatic cascade catalytic system, obtained remarkable formate generation rate 2137.7 μmol g–1 h–1. This work not only provides novel example using COF containing an structure immobilize but reveals synergetic MXene facilitates These findings offer new insights opportunities design application artificial systems

Язык: Английский

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Protein aggregates facilitated by polar aprotic solvents as carriers for enzyme immobilization

International Journal of Biological Macromolecules, Год журнала: 2025, Номер 307, С. 142164 - 142164

Опубликована: Март 15, 2025

Язык: Английский

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Highly efficient photoenzymatic CO2 reduction via integrated structural design of porphyrin covalent organic framework on Ti3C2T (MXene)

Separation and Purification Technology, Год журнала: 2025, Номер unknown, С. 132943 - 132943

Опубликована: Апрель 1, 2025

Язык: Английский

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In situ NADH regeneration coupled to enzymatic CO2 reduction: from fundamental concepts to recent advances

Journal of environmental chemical engineering, Год журнала: 2025, Номер unknown, С. 116657 - 116657

Опубликована: Апрель 1, 2025

Язык: Английский

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Constructing Cu2+ active sites on pyrazole-decorated UiO-66-NH2 with high activity for photocatalytic CO2 reduction to HCOO−

Materials Today Chemistry, Год журнала: 2025, Номер 46, С. 102712 - 102712

Опубликована: Апрель 19, 2025

Язык: Английский

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Designing biomimetic catalytic systems for CO₂ reduction to formate using NAD(P)H

Inorganic Chemistry Frontiers, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

This review article focuses on current achievements and identifies future research directions by designing biomimetic catalytic systems for CO 2 reduction to formate using NAD(P)H.

Язык: Английский

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Role of dynamic gravity in marinized multiphase packed bed applications

Current Opinion in Chemical Engineering, Год журнала: 2025, Номер 49, С. 101143 - 101143

Опубликована: Май 14, 2025

Язык: Английский

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Electroassisted Cofactor Regeneration with Co-Immobilized FDH-GlyDH on Mesoporous Silica for Enhanced CO2 Conversion

Microporous and Mesoporous Materials, Год журнала: 2025, Номер unknown, С. 113706 - 113706

Опубликована: Май 1, 2025

Язык: Английский

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