Column‐to‐Beam Structure House Inspired MXene‐Based Integrated Membrane with Stable Interlayer Spacing for Water Purification

Advanced Functional Materials, Год журнала: 2022, Номер 32(22)

Опубликована: Фев. 23, 2022

Abstract Ti 3 C 2 T x (MXene) displays prominent properties in water purification due to its rich surface chemistry and physicochemical property. However, the separation property is severely restrained because of intercalation‐induced swelling. Inspired by column‐to‐beam structure house, an advanced MXene‐based membrane developed with a stable interlayer spacing for purification. Laminar nanosheets numerous nanochannels are set as “beam” part, boron nitride (BN) thought “brick” part integrated membrane. Moreover, form interactions BN through covalent cross‐linking supramolecular hydrogen bonding. Furthermore polydopamine polyethylenimine assume roles “column” this interaction. Therefore, shows outstanding anti‐swelling 14.7 ± 0.13 Å after 600 h immersion water, which superior that most previously reported works. In addition, hydrophilic functional groups charges endow itself exceptional anti‐fouling ability. This work may offer promising manner construct materials precise

Язык: Английский

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Integrated Self‐Powered Sensors Based on 2D Material Devices

Advanced Functional Materials, Год журнала: 2022, Номер 32(41)

Опубликована: Авг. 3, 2022

With the development of Internet Things, there is an increasing need for clean energy and large‐scale sensory systems. Triboelectric/piezoelectric nanogenerators (TENGs/PENGs), have attracted considerable attention as a new type power generation terminal, which can harvest surrounding convert it into electrical energy. To improve output performance (NGs) diversify related applications, 2D materials with high carrier mobility excellent piezoelectric properties be directly used or integrated different types self‐powered sensors. In this review, authors first introduce optoelectronic materials, followed by triboelectric series in TENGs. The categories sensors based on are then summarized according to their structures compositions. We also discuss detail recent applications from five aspects. Finally, challenges outlooks research field featured. Given continuous they considered significant potential biomedicine, environmental detection, human motion monitoring, harvesting, smart wearable devices.

Язык: Английский

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Selective Ion Transport in Two‐Dimensional Lamellar Nanochannel Membranes

Angewandte Chemie International Edition, Год журнала: 2023, Номер 62(19)

Опубликована: Янв. 31, 2023

Precise and ultrafast ion sieving is highly desirable for many applications in environment-, energy-, resource-related fields. The development of a permselective lamellar membrane constructed from parallel stacked two-dimensional (2D) nanosheets opened new avenue the next-generation separation technology because unprecedented diversity designable interior nanochannels. In this Review, we first discuss construction homo- heterolaminar nanoarchitectures starting materials to emerging preparation strategies. We then explore property-performance relationships, with particular emphasis on effects physical structural features, chemical properties, external environment stimuli transport behavior under nanoconfinement. also present existing potential 2D membranes desalination, recovery, energy conversion. Finally, challenges outline research directions promising field.

Язык: Английский

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Carbon-doped boron nitride nanosheets: A high-efficient electrocatalyst for ambient nitrogen reduction

Applied Catalysis B Environment and Energy, Год журнала: 2022, Номер 315, С. 121574 - 121574

Опубликована: Май 30, 2022

Язык: Английский

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Green preparation of high-yield and large-size hydrophilic boron nitride nanosheets by tannic acid-assisted aqueous ball milling for thermal management

Composites Part A Applied Science and Manufacturing, Год журнала: 2022, Номер 164, С. 107266 - 107266

Опубликована: Окт. 17, 2022

Язык: Английский

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Self-Modifying Nanointerface Driving Ultrahigh Bidirectional Thermal Conductivity Boron Nitride-Based Composite Flexible Films

Nano-Micro Letters, Год журнала: 2022, Номер 15(1)

Опубликована: Ноя. 28, 2022

While boron nitride (BN) is widely recognized as the most promising thermally conductive filler for rapidly developing high-power electronic devices due to its excellent thermal conductivity and dielectric properties, a great challenge poor vertical when embedded in composites owing interfacial interaction causing severe phonon scattering. Here, we report novel surface modification strategy called "self-modified nanointerface" using BN nanocrystals (BNNCs) efficiently link interface between polymer matrix. Combining with ice-press assembly method, an only 25 wt% BN-embedded composite film can not possess in-plane of 20.3 W m-1 K-1 but also, more importantly, achieve through-plane high 21.3 K-1, which than twice reported maximum ideal spectrum matching BNNCs fillers, strong self-modified fillers matrix, well ladder-structured skeleton. The has been verified by theoretical calculations heat dissipation CPU. This study provides innovative design principle tailor interfaces opens up new path develop high-performance composites.

Язык: Английский

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A novel phase change composite with ultrahigh through-plane thermal conductivity and adjustable flexibility

Chemical Engineering Journal, Год журнала: 2023, Номер 463, С. 142402 - 142402

Опубликована: Март 13, 2023

Язык: Английский

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A review of boron nitride-based photocatalysts for carbon dioxide reduction

Journal of Materials Chemistry A, Год журнала: 2023, Номер 11(23), С. 11925 - 11963

Опубликована: Янв. 1, 2023

The conversion of carbon dioxide (CO 2 ) into valuable chemicals by photoreduction is an effective strategy for tackling the global warming conundrum.

Язык: Английский

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Simultaneously enhanced thermal conductivity and dielectric properties of borosilicate glass-based LTCC with AlN and h-BN additions

Journal of the European Ceramic Society, Год журнала: 2023, Номер 43(11), С. 4814 - 4825

Опубликована: Апрель 9, 2023

Язык: Английский

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Tumor Eradication by Boron Neutron Capture Therapy with ¹⁰B‐enriched Hexagonal Boron Nitride Nanoparticles Grafted with Poly(Glycerol)

Advanced Materials, Год журнала: 2023, Номер 35(35)

Опубликована: Май 27, 2023

Abstract Boron neutron capture therapy (BNCT) has emerged as a treatment modality with high precision and efficacy of intractable tumors. At the core effective tumor BNCT are 10 B carriers facile preparation well advantageous pharmacokinetic therapeutic profiles. Herein, design sub‐10 nm B‐enriched hexagonal boron nitride nanoparticles grafted poly(glycerol) (h‐ BN‐PG), their application to cancer by reported. By virtue small particle size outstanding stealth property, h‐ BN‐PG accumulate efficiently in murine CT26 colon tumors intratumor concentration 8.8%ID g −1 or 102.1 µg at 12 h post‐injection. Moreover, penetrate into inside parenchyma then taken up cells. comprising single bolus injection subsequent one‐time irradiation results significant shrinkage subcutaneous BN‐PG‐mediated not only causes direct DNA damage cells, but also triggers pronounced inflammatory immune response tissues, which contributes long‐lasting suppression after irradiation. Thus, promising agents eradicate through highly efficient accumulation.

Язык: Английский

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