Chemistry Letters, Год журнала: 2024, Номер 53(10)
Опубликована: Окт. 1, 2024
Abstract Vinyl sulfides are important structural motifs that allow various organic compounds. Herein, we report the facile synthesis of vinyl through photoredox-catalyzed coupling reaction alkenyl halides with benzenethiols. The can proceed without use transition metal catalysts.
Язык: Английский
Green Chemistry, Год журнала: 2024, Номер 26(7), С. 4199 - 4208
Опубликована: Янв. 1, 2024
A new photoelectrocatalytic mode permits the synthesis of polycyclic pyrimidin-4-ones through dehydrogenative cyclization malonates with unactivated alkenes.
Язык: Английский
Процитировано
15
Advanced Synthesis & Catalysis, Год журнала: 2024, Номер 366(10), С. 2352 - 2362
Опубликована: Апрель 5, 2024
Abstract While the emergence of electrophotochemistry provides opportunities, such a chemistry at this stage suffers from limited reaction types and high photocatalyst loadings. A self‐catalyzed electrophotosynthesis as well one with low loading is presented. These external‐oxidant‐free cyclizations are enabling applicable to range activated alkenes, affording diverse array thiocyanato heterocycles including 4‐pyrrolin‐2‐ones, isoquinoline‐1,3‐diones, indolo[2,1‐ ]isoquinolin‐6(5 H )‐ones, benzoimidazo[2,1‐ )‐ones indolin‐2‐ones, protocols amenable late‐stage diversification complex molecular architectures gram‐scale syntheses. Sunlight could serve light source, be conducted in an all‐solar‐driven mode using commercially available photovoltaic panel produce electricity.
Язык: Английский
Процитировано
9
The Journal of Organic Chemistry, Год журнала: 2024, Номер 89(15), С. 10660 - 10677
Опубликована: Июль 18, 2024
Two general protocols for the regioselective electrochemically enabled sulfonylation cyclization of
Язык: Английский
Процитировано
8
Chemistry - A European Journal, Год журнала: 2024, Номер 30(36)
Опубликована: Апрель 23, 2024
Three hybrid electrochemical protocols, which involve the energy transfer, direct photolysis and N-hydroxyphthalimide catalyst, respectively, are presented for selenylation/cyclization of fragile substrates 3-aza-1,5-dienes with diorganyl diselenides to afford 3-selenomethyl-4-pyrrolin-2-ones. The two electrophotocatalytic reactions indirect electrolysis one both regioselective external-oxidant- transition-metal-free, associated a broad substrate scope high Se-economy, all three methods amenable gram-scale syntheses, late-stage functionalizations, sunlight-induced experiments all-solar-driven syntheses.
Язык: Английский
Процитировано
6
Chinese Journal of Chemistry, Год журнала: 2024, Номер unknown
Опубликована: Дек. 2, 2024
Comprehensive Summary Herein, we report a rare example of three‐component net‐oxidative sulfonylation SO 2 surrogate with an oxidatively activated radical precursor under mild and metal‐ external‐oxidant‐free conditions. The mildness sustainability the reaction are enabled by photoelectrocatalysis, 3‐aza‐1,5‐dienes, organotrifluoroborates 1,4‐diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct (DABSO) undergo sulfonylative cyclization to afford sulfono 4‐pyrrolin‐2‐ones in atom‐economical manner broad substrate scope good functional‐group tolerance. protocol is amenable late‐stage diversification complex molecular architectures as well gram‐scale synthesis. Sunlight could be used light source, conducted all‐solar mode using commercially available photovoltaic panel generate electricity situ . Mechanistic studies reveal that generated (DABCO), which was generally innocent previous reactions, functions electron shuttle between photocatalytic cycle reactants.
Язык: Английский
Процитировано
2
Chemistry Letters, Год журнала: 2024, Номер 53(10)
Опубликована: Окт. 1, 2024
Abstract Vinyl sulfides are important structural motifs that allow various organic compounds. Herein, we report the facile synthesis of vinyl through photoredox-catalyzed coupling reaction alkenyl halides with benzenethiols. The can proceed without use transition metal catalysts.
Язык: Английский
Процитировано
0