EDA Complex-Enabled Annulation to Access CF2-Containing Tetralones and Quinazolinones Using Persulfates as Electron Donors
The Journal of Organic Chemistry,
Год журнала:
2024,
Номер
89(15), С. 10614 - 10623
Опубликована: Июль 25, 2024
A
photocatalyst-free
and
EDA
complex-enabled
radical
cascade
cyclization
reaction
of
inactive
alkenes
with
bromodifluoroacetamides
was
reported
for
the
divergent
synthesis
fluorine-containing
tetralones
quinazolinones.
In
this
transformation,
persulfates
as
electron
donors
difluoro
bromamide
acceptors
generate
complex.
This
is
a
promising
photochemical
method
advantages
such
mild
conditions,
simple
operation,
being
metal-free,
excellent
functional
group
tolerance.
Язык: Английский
Recent advances in radical cascade reaction for constructing nitrogen heterocycles using azides as radical acceptors
Organic & Biomolecular Chemistry,
Год журнала:
2024,
Номер
22(27), С. 5511 - 5523
Опубликована: Янв. 1, 2024
The
research
advances
in
radical
tandem
cyclization
for
constructing
nitrogen
heterocycles
which
azide
functions
as
a
acceptor
are
reviewed.
Язык: Английский
Photoinduced Metal‐Free Decarboxylative Fluoroalkylation of Alkenes for the Synthesis of N‐Arylbutanamides and Oxindoles
Chemistry - A European Journal,
Год журнала:
2024,
Номер
30(68)
Опубликована: Авг. 28, 2024
The
visible
light-induced
decarboxylative
cascade
reaction
of
fluoroalkyl
carboxylic
acids
has
been
achieved
for
the
efficient
synthesis
fluorinated
compounds.
However,
most
transformations
rely
on
noble
iridium
metal
complex.
Herein,
a
metal-free
realized.
This
protocol
features
simple
operation,
transition
free,
and
good
functional
group
tolerance.
Язык: Английский
Synthesis of succinyldiamides containing all-quaternary carbon center by photo-induced amidation/smiles rearrangement of alkenes
Organic & Biomolecular Chemistry,
Год журнала:
2024,
Номер
unknown
Опубликована: Дек. 23, 2024
A
novel,
mild,
and
environmentally
friendly
method
was
developed
for
the
synthesis
of
quaternary-carbon-containing
succinyldiamides.
This
found
to
be
compatible
with
many
substrates.
Язык: Английский