Ru(III)-PhI(OAc)2─A Combination for Generation of Isocyanate Intermediate from Benzimidate through a Rearrangement: Synthesis of Unsymmetrical Urea, Carbamate, and Chiral Analogues DOI

Shobhon Aich,

Maitreyi Saha,

Debasish Ghosh

и другие.

Organic Letters, Год журнала: 2024, Номер unknown

Опубликована: Дек. 4, 2024

Ru(III)-PhI(OAc)2, an unprecedented combination, is a highly efficient reagent system for the in situ generation of valuable isocyanate intermediate from benzimidate synthons through rearrangement. It unlocks powerful platform forming diverse C–N bonds, enabling one-pot synthesis expansive array unsymmetrical ureas, carbamates, and their chiral analogues toward complex molecular structures with high selectivity excellent yields. This new strategy not only exemplifies efficiency but also serves as versatile tool construction architectures, enhancing scope impact modern synthetic chemistry.

Язык: Английский

Tandem Thermo–electrochemical Strategy for Upcycling Waste Poly(ethylene terephthalate) into Value-Added Aniline Derivatives DOI

Shengwen Zhong,

Liangbo L. Shen,

Jiakun Xue

и другие.

ACS Sustainable Chemistry & Engineering, Год журнала: 2025, Номер unknown

Опубликована: Май 15, 2025

Язык: Английский

Процитировано

0

Manfred T. Reetz – A Pioneer in Chemical Synthesis DOI
Zhoutong Sun, Frank Hollmann

Molecular Catalysis, Год журнала: 2024, Номер 565, С. 114374 - 114374

Опубликована: Июль 8, 2024

Язык: Английский

Процитировано

0

Cubr2-Catalyzed Intramolecular Oxidative C-N Bond Formation for Synthesis of Isatins and Anticancer Drug Semaxanib Under Continuous-Flow Conditions DOI

SHARADA PRASANNA SWAIN,

C. G. Arya,

V. Ravichandiran

и другие.

Опубликована: Янв. 1, 2024

Язык: Английский

Процитировано

0

Ru(III)-PhI(OAc)2─A Combination for Generation of Isocyanate Intermediate from Benzimidate through a Rearrangement: Synthesis of Unsymmetrical Urea, Carbamate, and Chiral Analogues DOI

Shobhon Aich,

Maitreyi Saha,

Debasish Ghosh

и другие.

Organic Letters, Год журнала: 2024, Номер unknown

Опубликована: Дек. 4, 2024

Ru(III)-PhI(OAc)2, an unprecedented combination, is a highly efficient reagent system for the in situ generation of valuable isocyanate intermediate from benzimidate synthons through rearrangement. It unlocks powerful platform forming diverse C–N bonds, enabling one-pot synthesis expansive array unsymmetrical ureas, carbamates, and their chiral analogues toward complex molecular structures with high selectivity excellent yields. This new strategy not only exemplifies efficiency but also serves as versatile tool construction architectures, enhancing scope impact modern synthetic chemistry.

Язык: Английский

Процитировано

0