Ru(III)-PhI(OAc)2─A Combination for Generation of Isocyanate Intermediate from Benzimidate through a Rearrangement: Synthesis of Unsymmetrical Urea, Carbamate, and Chiral Analogues DOI

Shobhon Aich,

Maitreyi Saha,

Debasish Ghosh

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 4, 2024

Ru(III)-PhI(OAc)2, an unprecedented combination, is a highly efficient reagent system for the in situ generation of valuable isocyanate intermediate from benzimidate synthons through rearrangement. It unlocks powerful platform forming diverse C–N bonds, enabling one-pot synthesis expansive array unsymmetrical ureas, carbamates, and their chiral analogues toward complex molecular structures with high selectivity excellent yields. This new strategy not only exemplifies efficiency but also serves as versatile tool construction architectures, enhancing scope impact modern synthetic chemistry.

Language: Английский

Tandem Thermo–electrochemical Strategy for Upcycling Waste Poly(ethylene terephthalate) into Value-Added Aniline Derivatives DOI

Shengwen Zhong,

Liangbo L. Shen,

Jiakun Xue

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2025, Volume and Issue: unknown

Published: May 15, 2025

Language: Английский

Citations

0
Manfred T. Reetz – A Pioneer in Chemical Synthesis DOI
Zhoutong Sun, Frank Hollmann

Molecular Catalysis, Journal Year: 2024, Volume and Issue: 565, P. 114374 - 114374

Published: July 8, 2024

Language: Английский

Citations

0
Cubr2-Catalyzed Intramolecular Oxidative C-N Bond Formation for Synthesis of Isatins and Anticancer Drug Semaxanib Under Continuous-Flow Conditions DOI

SHARADA PRASANNA SWAIN,

C. G. Arya,

V. Ravichandiran

et al.

Published: Jan. 1, 2024

Language: Английский

Citations

0
Ru(III)-PhI(OAc)2─A Combination for Generation of Isocyanate Intermediate from Benzimidate through a Rearrangement: Synthesis of Unsymmetrical Urea, Carbamate, and Chiral Analogues DOI

Shobhon Aich,

Maitreyi Saha,

Debasish Ghosh

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 4, 2024

Ru(III)-PhI(OAc)2, an unprecedented combination, is a highly efficient reagent system for the in situ generation of valuable isocyanate intermediate from benzimidate synthons through rearrangement. It unlocks powerful platform forming diverse C–N bonds, enabling one-pot synthesis expansive array unsymmetrical ureas, carbamates, and their chiral analogues toward complex molecular structures with high selectivity excellent yields. This new strategy not only exemplifies efficiency but also serves as versatile tool construction architectures, enhancing scope impact modern synthetic chemistry.

Language: Английский

Citations

0