
Materials Chemistry and Physics, Год журнала: 2024, Номер 332, С. 130237 - 130237
Опубликована: Дек. 7, 2024
Язык: Английский
Materials Chemistry and Physics, Год журнала: 2024, Номер 332, С. 130237 - 130237
Опубликована: Дек. 7, 2024
Язык: Английский
Chemical Engineering Journal, Год журнала: 2024, Номер 500, С. 157396 - 157396
Опубликована: Ноя. 1, 2024
Язык: Английский
Процитировано
10Journal of Molecular Structure, Год журнала: 2025, Номер unknown, С. 141895 - 141895
Опубликована: Фев. 1, 2025
Язык: Английский
Процитировано
0ChemistrySelect, Год журнала: 2025, Номер 10(11)
Опубликована: Март 1, 2025
Abstract In this article, we report the synthesis of first example V‐shaped unique structure complex {[Hg(nvp) 2 (NCS)(Cl)][Hg(nvp) (NCS) ]} ( 1 ; 4‐nvp = 4‐(1‐naphthylvinyl)pyridine and SCN − thiocyanate) containing two heteroleptic monometallic Hg(II) based units. The undergoes a variety conventional unconventional supramolecular interactions, such as hydrogen bonding, chalcogen⋯π, halogen⋯π, π⋯π chalcogen⋯halogen interactions to generate higher dimensional architecture. These assemblies, along with presence d 10 metal ion promote large charge transportation make material behave semiconductor well Schottky diode. shows high conductivity (1.73 × −3 S/m), maintaining 1.54 ideality factor. This allows quick response times low noise, enhancing signal clarity efficiency in electronic devices, making it ideal for high‐speed photodetectors. semiconducting behavior is also realized by density functional theory (DFT) computed band gap study.
Язык: Английский
Процитировано
0Journal of Molecular Structure, Год журнала: 2024, Номер unknown, С. 140053 - 140053
Опубликована: Сен. 1, 2024
Язык: Английский
Процитировано
2Inorganic Chemistry, Год журнала: 2024, Номер 64(1), С. 335 - 343
Опубликована: Дек. 31, 2024
Hg
Язык: Английский
Процитировано
2Journal of Molecular Structure, Год журнала: 2024, Номер 1320, С. 139672 - 139672
Опубликована: Авг. 15, 2024
Язык: Английский
Процитировано
1Journal of Molecular Structure, Год журнала: 2024, Номер 1322, С. 140530 - 140530
Опубликована: Ноя. 3, 2024
Язык: Английский
Процитировано
1Langmuir, Год журнала: 2024, Номер 41(1), С. 1182 - 1193
Опубликована: Дек. 30, 2024
A porous and flexible Zn-MOF was synthesized under solvothermal conditions by using the ligand 2,5-furandicarboxylic acid (2,5-FDA). This demonstrates a temperature-triggered breathing effect. At low temperature (100 K), we obtained high-symmetry MOF denoted as SM-A with unit cell volume of 1958 Å3, characterized triangular narrow pore (np) channels. Upon increasing from 100 K to 298 K, lower symmetry referred SM-B obtained, featuring rhombic large (lp) channels, along an expanded 7823 Å3. temperature-induced phase transition involves distortion channels change in dimensionality framework 3D (SM-A) 2D (SM-B). The behavior were thoroughly justified help single-crystal X-ray diffraction differential scanning calorimetry. Additionally, BET analysis revealed surface area 85.504 m2/g, mesopores 3.05 nm. Leveraging large-pore at room employed adsorbent for removal hazardous iodine both vapor solution phases. discovery such dynamic MOFs holds potential may pave way novel strategies advanced applications.
Язык: Английский
Процитировано
1Desalination and Water Treatment, Год журнала: 2024, Номер 320, С. 100686 - 100686
Опубликована: Авг. 5, 2024
Co-Cu-Ni and Co-Cu-Zn trimetallic nanoparticles (NPs) were prepared by chemical reduction method which then used as adsorbent to remove Crocein Orange G dye from solution. The elemental composition of the fabricated NPs was determined EDX analysis, surface morphology assessed SEM, its crystalline nature confirmed XRD analysis. functional groups on FT-IR optimum dosage found be 0.01 g. Langmuir model well linear pseudo 2nd order kinetics models best explained obtained data. maximum adsorption capabilities around 497.618 mg/g 683.093 mg/g, respectively for NPs. process exothermic, evidenced positive ΔH° values. negative values ΔG° at corresponding temperatures support spontaneous processes. entropy changes (ΔS°) suggested that there is more disorderness interface between solid solution during adsorption. have effectively adsorbed G, may considered an attractive option in wastewater treatment environmental remediation applications due diversity metal ions offering differential forces pollutant.
Язык: Английский
Процитировано
0Applied Organometallic Chemistry, Год журнала: 2024, Номер 39(1)
Опубликована: Окт. 3, 2024
ABSTRACT Detecting antibiotic residues is crucial for monitoring their excessive use in healthcare and agricultural practices. Herein, a new 3D metal–organic framework (MOF) containing {[Cd (bpyp)(sdba)]·DMF·2H 2 O} n ( 1 ) (bpyp = 2,5‐bis (pyrid‐4‐yl)pyridine H sdba 4,4′‐sulfonyldibenzoic acid) has been designed synthesized. MOF displays sensitive detection tetracycline (TCY) with limit of below 7.67 × 10 −6 M an aqueous solution. The mechanism involves competitive absorption between antibiotics, supported by UV–vis spectroscopy fluorescence lifetime measurements. exhibits visible response to TCY under 254 nm UV lamp. applied the quantitative lake water recovery based on sensing platform was 92.26–107.54% RSD (%) less than 4.38%, indicating outstanding reliability.
Язык: Английский
Процитировано
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