Exploring Fe3+ Cation Exchange Dynamics in Fluorescent MIL-53(Al) MOF: Solid-state Photoluminescence and Structural Insights DOI Creative Commons
Tanzeel Ul Rehman, S. Agnello,

F. M. Gelardi

et al.

Materials Chemistry and Physics, Journal Year: 2024, Volume and Issue: 332, P. 130237 - 130237

Published: Dec. 7, 2024

Language: Английский

Metal-Organic frameworks (MOFs) for Oxo-Anion removal in wastewater Treatment: Advancements and applications DOI
M. Shahnawaz Khan, Sidi Zhu, Shing Bor Chen

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 500, P. 157396 - 157396

Published: Nov. 1, 2024

Language: Английский

Citations

10
Exploring the Structural Features and Adsorption Potential of a Newly Synthesized Cobalt(II) Coordination Polymer towards Perilous Organic Dye Contaminants in Water DOI
Sumra Dilshad, Arif Ali,

Shama Firduas

et al.

Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 141895 - 141895

Published: Feb. 1, 2025

Language: Английский

Citations

0
Synthesis and Characterization of a V‐Shaped Heteroleptic Hg(II) Complex with Enhanced Conductivity DOI
Sourav Datta, Nargis Khatun, Pravat Ghorai

et al.

ChemistrySelect, Journal Year: 2025, Volume and Issue: 10(11)

Published: March 1, 2025

Abstract In this article, we report the synthesis of first example V‐shaped unique structure complex {[Hg(nvp) 2 (NCS)(Cl)][Hg(nvp) (NCS) ]} ( 1 ; 4‐nvp = 4‐(1‐naphthylvinyl)pyridine and SCN − thiocyanate) containing two heteroleptic monometallic Hg(II) based units. The undergoes a variety conventional unconventional supramolecular interactions, such as hydrogen bonding, chalcogen⋯π, halogen⋯π, π⋯π chalcogen⋯halogen interactions to generate higher dimensional architecture. These assemblies, along with presence d 10 metal ion promote large charge transportation make material behave semiconductor well Schottky diode. shows high conductivity (1.73 × −3 S/m), maintaining 1.54 ideality factor. This allows quick response times low noise, enhancing signal clarity efficiency in electronic devices, making it ideal for high‐speed photodetectors. semiconducting behavior is also realized by density functional theory (DFT) computed band gap study.

Language: Английский

Citations

0
A new 3D Pb(II)-based MOF as highly sensitive selective fluorescent probe for naked-eye detection of furazolidone DOI

Gang Li,

Miao Yao,

C.C. Liu

et al.

Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: unknown, P. 140053 - 140053

Published: Sept. 1, 2024

Language: Английский

Citations

2
Luminescent Metal–Organic Framework with Outstanding “Turn-On” Hg2+ Sensing Ability First Constructed by an AIE Ligand DOI
Jinfang Zhang, Xingyu Tao,

Yinlong Yue

et al.

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 64(1), P. 335 - 343

Published: Dec. 31, 2024

Hg

Language: Английский

Citations

2
A new Zn(II)-based 3D MOF with pcu-like topology: Potent photocatalyst for nitrofurazone antibiotic degradation DOI
Jian Zhang, Tingting Zhao, Aparna Kushwaha

et al.

Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: 1320, P. 139672 - 139672

Published: Aug. 15, 2024

Language: Английский

Citations

1
A tetrahedral zinc(II) coordination polymer: Synthesis, characterisation, and application in ascorbic Acid fluorescence sensing DOI

Yuehua He,

Mithun Kumar Ghosh, Ren‐Min Ma

et al.

Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: 1322, P. 140530 - 140530

Published: Nov. 3, 2024

Language: Английский

Citations

1
Breathing Transition and Effective Iodine Adsorption in a Temperature-Responsive Zn-Based Flexible Metal–Organic Framework DOI
Samrah Kamal, Mohd Khalid, M. Shahnawaz Khan

et al.

Langmuir, Journal Year: 2024, Volume and Issue: 41(1), P. 1182 - 1193

Published: Dec. 30, 2024

A porous and flexible Zn-MOF was synthesized under solvothermal conditions by using the ligand 2,5-furandicarboxylic acid (2,5-FDA). This demonstrates a temperature-triggered breathing effect. At low temperature (100 K), we obtained high-symmetry MOF denoted as SM-A with unit cell volume of 1958 Å3, characterized triangular narrow pore (np) channels. Upon increasing from 100 K to 298 K, lower symmetry referred SM-B obtained, featuring rhombic large (lp) channels, along an expanded 7823 Å3. temperature-induced phase transition involves distortion channels change in dimensionality framework 3D (SM-A) 2D (SM-B). The behavior were thoroughly justified help single-crystal X-ray diffraction differential scanning calorimetry. Additionally, BET analysis revealed surface area 85.504 m2/g, mesopores 3.05 nm. Leveraging large-pore at room employed adsorbent for removal hazardous iodine both vapor solution phases. discovery such dynamic MOFs holds potential may pave way novel strategies advanced applications.

Language: Английский

Citations

1
Removal of crocein orange G from water solutions by trimetallic nanoparticles [Co/Cu/M (M=Ni, Zn)] prepared by chemical reduction method DOI Creative Commons

Sultan Alam,

Absar Ul Haq, Muhammad Ilyas

et al.

Desalination and Water Treatment, Journal Year: 2024, Volume and Issue: 320, P. 100686 - 100686

Published: Aug. 5, 2024

Co-Cu-Ni and Co-Cu-Zn trimetallic nanoparticles (NPs) were prepared by chemical reduction method which then used as adsorbent to remove Crocein Orange G dye from solution. The elemental composition of the fabricated NPs was determined EDX analysis, surface morphology assessed SEM, its crystalline nature confirmed XRD analysis. functional groups on FT-IR optimum dosage found be 0.01 g. Langmuir model well linear pseudo 2nd order kinetics models best explained obtained data. maximum adsorption capabilities around 497.618 mg/g 683.093 mg/g, respectively for NPs. process exothermic, evidenced positive ΔH° values. negative values ΔG° at corresponding temperatures support spontaneous processes. entropy changes (ΔS°) suggested that there is more disorderness interface between solid solution during adsorption. have effectively adsorbed G, may considered an attractive option in wastewater treatment environmental remediation applications due diversity metal ions offering differential forces pollutant.

Language: Английский

Citations

0
A Cd (II)‐based Metal–Organic Framework as Switch‐Off Fluorescence Sensors for Antibiotic Detection DOI

Zhi‐Chao Yin,

M. K. Ray,

C.C. Liu

et al.

Applied Organometallic Chemistry, Journal Year: 2024, Volume and Issue: 39(1)

Published: Oct. 3, 2024

ABSTRACT Detecting antibiotic residues is crucial for monitoring their excessive use in healthcare and agricultural practices. Herein, a new 3D metal–organic framework (MOF) containing {[Cd (bpyp)(sdba)]·DMF·2H 2 O} n ( 1 ) (bpyp = 2,5‐bis (pyrid‐4‐yl)pyridine H sdba 4,4′‐sulfonyldibenzoic acid) has been designed synthesized. MOF displays sensitive detection tetracycline (TCY) with limit of below 7.67 × 10 −6 M an aqueous solution. The mechanism involves competitive absorption between antibiotics, supported by UV–vis spectroscopy fluorescence lifetime measurements. exhibits visible response to TCY under 254 nm UV lamp. applied the quantitative lake water recovery based on sensing platform was 92.26–107.54% RSD (%) less than 4.38%, indicating outstanding reliability.

Language: Английский

Citations

0