A New Cd(II)-Based Coordination Polymer for Efficient Photocatalytic Removal of Organic Dyes

Molecules, Год журнала: 2023, Номер 28(19), С. 6848 - 6848

Опубликована: Сен. 28, 2023

Coordination polymers (CPs) are a diverse class of multi-dimensional compounds that show promise as photocatalysts for degrading dyes in polluted water. Herein, new 1D Cd(II)-based coordination polymer with the formula [Cd(bpyp)(nba)2] (1) (bpyp = 2,5-bis(pyrid-4-yl)pyridine and Hnba 4-nitrobenzoic acid) is synthesized characterized. In 1, two carboxyl groups different nba- ligands μ2-η1:η1 μ1-η1:η1 modes to connect CdII centers sit on either side chain along b direction. The produced CP 1 was utilized photocatalyst process photodegradation methyl blue (MB), orange (MO), rhodamine B (RhB), violet (MV) when exposed UV light. photocatalytic degradation activities were analyzed, results suggest it exhibits an extraordinary efficiency MB, MV, MO, RhB. RhB has 95.52% degradation, whereas MV 58.92% efficiency, MO 35.44%, MB 29.24%. photodecomposition catalyzed mostly by •O2- •OH-, shown research involving trapping radicals.

Язык: Английский

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Detection mechanism and the outlook of metal-organic frameworks for the detection of hazardous substances in milk

Food Chemistry, Год журнала: 2023, Номер 430, С. 136934 - 136934

Опубликована: Июль 27, 2023

Язык: Английский

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Metal–organic frameworks (MOFs) as apt luminescent probes for the detection of biochemical analytes

Journal of Materials Chemistry B, Год журнала: 2023, Номер 11(29), С. 6802 - 6822

Опубликована: Янв. 1, 2023

This article reviews the recent developments in use of MOF materials as probes and biosensing platforms for diverse chemicals (H 2 O , metal ions, H S, GSH, nucleic acids) biological cells.

Язык: Английский

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Current and promising applications of Hf(iv)-based MOFs in clinical cancer therapy

Journal of Materials Chemistry B, Год журнала: 2023, Номер 11(25), С. 5693 - 5714

Опубликована: Янв. 1, 2023

Cancer is one of the greatest challenges in medical science today as it poses a serious threat to human life. In view this, myriad therapeutic strategies are being developed for treatment cancer. Despite use various approaches, they still insufficient The rapid advancement nanotechnology currently offers exciting possibilities creation novel cancer therapy approaches. Metal organic frameworks (MOFs) emerging multifunctional nanomaterials that find prospective applications biomedical field owing their porosity, large specific surface area, and diversified structures. Amongst varied categories MOFs, Hf(IV)-based MOFs have been since 2012 finding new hence this class gaining immense attention amongst material biomaterial chemists. Most importantly, Hf(IV)-MOFs comprising high Z-Hf metal content may be capable offering options therapy, nonlinear optics, fluorescent sensors, photoresponsive devices. review, progress using radiotherapy, chemotherapy, immunotherapy, phototherapeutic techniques, or combination two more these techniques explored. This review also provides insight regarding current limitations future prospects therapy.

Язык: Английский

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Current status and prospects of MOFs in controlled delivery of Pt anticancer drugs

Dalton Transactions, Год журнала: 2023, Номер 52(19), С. 6226 - 6238

Опубликована: Янв. 1, 2023

This review focuses on the application of platinum as an anticancer drug and MOF materials loading species; prospect for its future development is also discussed.

Язык: Английский

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Current status and prospects of MIL-based MOF materials for biomedicine applications

RSC Medicinal Chemistry, Год журнала: 2023, Номер 14(10), С. 1914 - 1933

Опубликована: Янв. 1, 2023

This review focuses on drug delivery systems based MIL-100(Fe) and MIL-101(Fe) that have made significant progress in chemodynamic therapy, photothermal photodynamic combined therapy.

Язык: Английский

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Synthesized and characterization of a new Cd(II)-based coordination polymer: Sensing activity and photocatalytic activity against antibiotic

Polyhedron, Год журнала: 2023, Номер 241, С. 116468 - 116468

Опубликована: Июнь 1, 2023

Язык: Английский

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A new Ag‐based photocatalyst for efficient degradation of antibiotic nitrofurantoin

Applied Organometallic Chemistry, Год журнала: 2024, Номер 38(7)

Опубликована: Май 15, 2024

In this paper, a new 0D Ag(I)‐based coordination polymer [Ag 2 (dib)(H L) ]( 1 ) is proposed as photocatalyst for the photocatalytic degradation of nitrofurantoin (NFT) under ultraviolet irradiation. The catalytic was analyzed by various methods such PXRD, SEM, FT‐IR, TGA, UV–vis, DRS, and electrochemical tests. experimental result shows that an n ‐type semiconductor, which can effectively catalyze photodegradation NFT Under optimal reaction conditions, rate 97.95% within 60 min when concentration 30 ppm. experiment free radical capture O ˙ − main active substance photodecomposition, possible mechanism proposed. This research will lay foundation polymers in field antibiotic degradation.

Язык: Английский

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A new 3D Cd(II) metal organic framework (MOF) as an efficient photocatalyst for nitrofurantoin antibiotic degradation

Journal of Molecular Structure, Год журнала: 2024, Номер 1312, С. 138586 - 138586

Опубликована: Май 10, 2024

Язык: Английский

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Remediation of antibiotics using coordination polymers

Coordination Chemistry Reviews, Год журнала: 2024, Номер 519, С. 216120 - 216120

Опубликована: Авг. 9, 2024

Язык: Английский

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