Structural, computational, fluorescent properties and antibacterial properties insights into perfect self-assembly of a novel ring-shaped dinuclear copper(Ⅱ) complex based on a bis(salamo)-type ligand

Journal of Molecular Structure, Год журнала: 2025, Номер unknown, С. 141535 - 141535

Опубликована: Янв. 1, 2025

Язык: Английский

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Cd-Ln (Ln = Pr, Sm, Yb and Nd) heteronuclear complexes based on the linear chain ether Schiff base: Structural regulation and fluorescence properties

Journal of Molecular Structure, Год журнала: 2024, Номер 1318, С. 139445 - 139445

Опубликована: Июль 24, 2024

Язык: Английский

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An experimental and theoretical study of coinage bond interaction in a copper(II)/potassium(I) Schiff base complex

Inorganica Chimica Acta, Год журнала: 2024, Номер 573, С. 122323 - 122323

Опубликована: Авг. 23, 2024

Язык: Английский

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Hydrogen evolution reaction on silver(I) complex modified electrode materials as electrocatalysts

Journal of Coordination Chemistry, Год журнала: 2024, Номер 77(17-19), С. 2044 - 2058

Опубликована: Окт. 1, 2024

Two new silver(I) complexes, [Ag2(BDC)(Et-BBA)2] (1) and {[Ag3(BTC)(Et-BBA)3]·(C2H5OH)6·(H2O)3}2 (2) (Et-BBA = N,N-bis[(1-ethyl-1H-benzo[d]imidazol-2-yl)methyl]aniline, H2BDC 1,4-benzendicarboxylic acid, H3BTC 1,3,5-benzenetricarboxylic acid), were prepared structurally characterized. Complex 1 is binuclear, whereas 2 forms a trinuclear structure. The carbon paste composite electrodes (CPCEs 2) from graphite powder used as molecular electrocatalysts to investigate their catalytic hydrogen evolution reaction (HER) performance by variable temperature linear sweep voltammetry (VT-LSV) electrochemical impedance spectroscopy (EIS). results indicated that the overpotentials η10293K of CPCEs in 0.5 M H2SO4 electrolyte undergo significant positive shift (–915 mV for CPCE 1, −600 with respect sCPCE (–966 mV). Tafel slope, activation energy EIS further verify modified could effectively catalyze HER behavior. Based on identified structures, mechanisms toward hypothesized. active intermediate (triangular bipyramidal configuration) formed upon addition more reactive, which may be reason higher activity than 1.

Язык: Английский

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Chalcone-ensembled 1,2,3-triazole via Click Chemistry: Selective ‘Turn-On’ detection of Cu(II) ions via Photoinduced Electron Transfer in real water samples and computational analysis

Journal of Molecular Structure, Год журнала: 2024, Номер unknown, С. 140921 - 140921

Опубликована: Ноя. 1, 2024

Язык: Английский

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