Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: unknown, P. 140921 - 140921
Published: Nov. 1, 2024
Language: Английский
Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: unknown, P. 140921 - 140921
Published: Nov. 1, 2024
Language: Английский
Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 141535 - 141535
Published: Jan. 1, 2025
Language: Английский
Citations
0Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: 1318, P. 139445 - 139445
Published: July 24, 2024
Language: Английский
Citations
3Inorganica Chimica Acta, Journal Year: 2024, Volume and Issue: 573, P. 122323 - 122323
Published: Aug. 23, 2024
Language: Английский
Citations
3Journal of Coordination Chemistry, Journal Year: 2024, Volume and Issue: 77(17-19), P. 2044 - 2058
Published: Oct. 1, 2024
Two new silver(I) complexes, [Ag2(BDC)(Et-BBA)2] (1) and {[Ag3(BTC)(Et-BBA)3]·(C2H5OH)6·(H2O)3}2 (2) (Et-BBA = N,N-bis[(1-ethyl-1H-benzo[d]imidazol-2-yl)methyl]aniline, H2BDC 1,4-benzendicarboxylic acid, H3BTC 1,3,5-benzenetricarboxylic acid), were prepared structurally characterized. Complex 1 is binuclear, whereas 2 forms a trinuclear structure. The carbon paste composite electrodes (CPCEs 2) from graphite powder used as molecular electrocatalysts to investigate their catalytic hydrogen evolution reaction (HER) performance by variable temperature linear sweep voltammetry (VT-LSV) electrochemical impedance spectroscopy (EIS). results indicated that the overpotentials η10293K of CPCEs in 0.5 M H2SO4 electrolyte undergo significant positive shift (–915 mV for CPCE 1, −600 with respect sCPCE (–966 mV). Tafel slope, activation energy EIS further verify modified could effectively catalyze HER behavior. Based on identified structures, mechanisms toward hypothesized. active intermediate (triangular bipyramidal configuration) formed upon addition more reactive, which may be reason higher activity than 1.
Language: Английский
Citations
0Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: unknown, P. 140921 - 140921
Published: Nov. 1, 2024
Language: Английский
Citations
0