The influential IPr: 25 years after its discovery

Chemical Science, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

25 Years after the discovery of most influential NHC ligand, we revisit and highlight studies involving IPr that have shaped field NHC-transition metal catalysis.

Язык: Английский

IPr^# Complexes─Highly-Hindered, Sterically-Bulky Cu(I) and Ag(I) N-Heterocyclic Carbenes: Synthesis, Characterization, and Reactivity

Organometallics, Год журнала: 2024, Номер 43(19), С. 2305 - 2313

Опубликована: Сен. 21, 2024

Metal-N-heterocyclic carbene (M-NHC) complexes are well-known as an important class of organometallic compounds widely used in transition-metal catalysis. Taking into account that the steric hindrance around metal center is one major effects M-NHC catalysis, development new, sterically hindered ongoing interest this field research. Herein, we report synthesis and characterization exceedingly hindered, well-defined, air- moisture-stable Cu(I) Ag(I) complexes, [Cu(NHC)Cl] [Ag(NHC)Cl], recently discovered IPr

Язык: Английский

Hydroxyapatite-supported CuO nanoparticles: an efficient catalyst for the propargylamines synthesis with antimicrobial properties

Research on Chemical Intermediates, Год журнала: 2025, Номер unknown

Опубликована: Апрель 4, 2025

Язык: Английский