The influential IPr: 25 years after its discovery

Chemical Science, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

25 Years after the discovery of most influential NHC ligand, we revisit and highlight studies involving IPr that have shaped field NHC-transition metal catalysis.

Language: Английский

IPr^# Complexes─Highly-Hindered, Sterically-Bulky Cu(I) and Ag(I) N-Heterocyclic Carbenes: Synthesis, Characterization, and Reactivity

Organometallics, Journal Year: 2024, Volume and Issue: 43(19), P. 2305 - 2313

Published: Sept. 21, 2024

Metal-N-heterocyclic carbene (M-NHC) complexes are well-known as an important class of organometallic compounds widely used in transition-metal catalysis. Taking into account that the steric hindrance around metal center is one major effects M-NHC catalysis, development new, sterically hindered ongoing interest this field research. Herein, we report synthesis and characterization exceedingly hindered, well-defined, air- moisture-stable Cu(I) Ag(I) complexes, [Cu(NHC)Cl] [Ag(NHC)Cl], recently discovered IPr

Language: Английский

Hydroxyapatite-supported CuO nanoparticles: an efficient catalyst for the propargylamines synthesis with antimicrobial properties

Research on Chemical Intermediates, Journal Year: 2025, Volume and Issue: unknown

Published: April 4, 2025

Language: Английский