Two-Dimensional Carbon Graphdiyne: Advances in Fundamental and Application Research

ACS Nano, Год журнала: 2023, Номер 17(15), С. 14309 - 14346

Опубликована: Июль 20, 2023

Graphdiyne (GDY), a rising star of carbon allotropes, features two-dimensional all-carbon network with the cohybridization sp and sp2 atoms represents trend research direction in development materials. The sp/sp2-hybridized structure GDY endows it numerous advantages advancements controlled growth, assembly, performance tuning, many studies have shown that has been key material for innovation fields catalysis, energy, photoelectric conversion, mode conversion transformation electronic devices, detectors, life sciences, etc. In past ten years, fundamental scientific issues related to understood, showing differences from traditional materials chemical physical properties mechanisms, attracting extensive attention scientists. gradually developed into one frontiers chemistry science, entered rapid period, producing large numbers applied achievements For exploration frontier concepts phenomena science research, there is great potential promote progress intelligent information, optoelectronics, sciences. this review, self-assembly method, aggregation structure, modification, doping are shown, theoretical calculation simulation also fully introduced. particular, applications its formed aggregates energy storage, photoelectronic, biomedicine, environmental separation

Язык: Английский

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Construction of CeO2/YMnO3 and CeO2/MgAl2O4/YMnO3 photocatalysts and adsorption of dyes and photocatalytic oxidation of antibiotics: Performance prediction, degradation pathway and mechanism insight

Applied Surface Science, Год журнала: 2022, Номер 608, С. 154977 - 154977

Опубликована: Окт. 7, 2022

Язык: Английский

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Recent advancements in the use of novel piezoelectric materials for piezocatalytic and piezo-photocatalytic applications

Applied Catalysis B Environment and Energy, Год журнала: 2023, Номер 341, С. 123335 - 123335

Опубликована: Сен. 28, 2023

Язык: Английский

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Enhanced Piezocatalytic Performance of BaTiO₃ Nanosheets with Highly Exposed {001} Facets

Advanced Functional Materials, Год журнала: 2022, Номер 32(35)

Опубликована: Июнь 23, 2022

Abstract Piezocatalysis has gradually come into the limelight due to its great potential for solving energy shortages and environmental pollution problems. However, limited piezocatalytic efficiency is a severe bottleneck practical applications. Here, well‐defined BaTiO 3 nanosheets with highly exposed {001} polar facets are successfully synthesized enhance activity. The [001] piezoelectric polarization can drive carriers migrate surface along out‐of‐plane direction. provides abundant active sites reaction. As result, superior degradation ratio of organic pollutants obtained high first‐order rate constant k 0.0835 min −1 , which 2.7 times higher than nanoparticles. Furthermore, display an outstanding H 2 production capability, 305 µmol g h –1 almost two that This work thus novel comprehensive strategy designing high‐performance piezocatalysts polarization, also insights optimization activity by regulating facet piezocatalysts.

Язык: Английский

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Piezo‐Augmented and Photocatalytic Nanozyme Integrated Microneedles for Antibacterial and Anti‐Inflammatory Combination Therapy

Advanced Functional Materials, Год журнала: 2022, Номер 33(10)

Опубликована: Дек. 23, 2022

Abstract Wound infection is arguably the most common, and potentially devastating, complication of wound healing process. The ideal treatment strategy has to eliminate bacteria, alleviate inflammation, promote skin formation. Herein, a multifunctional heterostructure designed consisting ultrasmall platinum–ruthenium nanoalloys porous graphitic carbon nitride C 3 N 5 nanosheets (denoted as PtRu/C ), which concurrently possesses piezoelectric enhanced oxidase ‐mimic nanozyme activity photocatalytic hydrogen gas production capacity. Moreover, these hybrid nanotherapeutics are integrated in natural hyaluronic acid microneedles, exhibit almost 100% broad‐spectrum antibacterial efficacy against multiple bacterial strains vitro vivo within 10 min ultrasound treatment, effectively inhibit inflammation reactions after 1 h visible light irradiation, promising for accelerating cutaneous infected mice. This study highlights competitive development all‐in‐one anti‐inflammatory therapies.

Язык: Английский

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Tailoring the Surface and Composition of Nanozymes for Enhanced Bacterial Binding and Antibacterial Activity

Small, Год журнала: 2023, Номер 19(42)

Опубликована: Июнь 15, 2023

With the advantages of diverse structures, tunable enzymatic activity, and high stability, nanozymes are widely used in medicine, chemistry, food, environment, other fields. As an alternative to traditional antibiotics, attract more attention from scientific researchers recent years. Developing nanozymes-based antibacterial materials opens up a new avenue for bacterial disinfection sterilization. In this review, classification their mechanisms discussed. The surface composition critical efficacy, which can be tailored enhance both binding activity. On one hand, modification enables targeting bacteria that improves performance including biochemical recognition, charge, topography. modulated achieve enhanced single nanozyme-mediated synergistic multiple nanozymes-mediated cascade catalytic applications. addition, current challenges future prospects tailoring applications This review provide insights into design treatments.

Язык: Английский

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Functional Graphdiyne for Emerging Applications: Recent Advances and Future Challenges

Advanced Functional Materials, Год журнала: 2023, Номер 34(4)

Опубликована: Окт. 20, 2023

Abstract Graphdiyne (GDY) is regarded as an exceptional candidate to meet the growing demand in many fields due its rich chemical bonds, highly π‐conjugated structure, uniformly distributed pores, large surface area, and high inhomogeneity of charge distribution. The extensive research efforts bring about a rapid expansion GDY with variety functionalities, which significantly enhance performance including photocatalysis, energy, biomedicine, etc. In this review, synthetic strategies (in situ ex approaches) that are designed rationally functionalize GDY, optimizing their nanostructures by surface/interface engineering dopants or functional groups (heteroatoms/small molecules/macromolecules), building up hierarchical GDY‐based heterostructures highlighted. Theoretical calculations on structural evolution electronic characteristics after functionalization briefly discussed. With elaborate rational structure engineering, applied emerging applications (e.g., hydrogen reaction, CO 2 reduction nitrogen energy storage conversion, nanophotonics, sensors, biomedical applications, etc.) comprehensively Finally, challenges prospects concerning future development nanoarchitectures also presented.

Язык: Английский

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Activity Regulating Strategies of Nanozymes for Biomedical Applications

Small, Год журнала: 2023, Номер 19(11)

Опубликована: Янв. 17, 2023

Abstract On accounts of the advantages inherent high stability, ease preparation and superior catalytic activities, nanozymes have attracted tremendous potential in diverse biomedical applications as alternatives to natural enzymes. Optimizing activity is significant for widening boosting into practical level. As research regulation strategies boosting, it essential timely review, summarize, analyze advances structure–activity relationships further inspiring ingenious this prosperous area. Herein, methods recent 5 years are systematically summarized, including size morphology, doping, vacancy, surface modification, hybridization, followed by a discussion latest consisting biosensing, antibacterial, tumor therapy. Finally, challenges opportunities rapidly developing field presented more infant yet promising

Язык: Английский

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Nanozymes: powerful catalytic materials for environmental pollutant detection and degradation

Environmental Science Nano, Год журнала: 2024, Номер 11(3), С. 766 - 796

Опубликована: Янв. 1, 2024

Here we made a critical review on nanozyme-involved detection and degradation of environmental pollutants, the research progress achieved in last five years was emphatically concluded.

Язык: Английский

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Construction of S-N-C bond for boosting bacteria-killing by synergistic effect of photocatalysis and nanozyme

Applied Catalysis B Environment and Energy, Год журнала: 2023, Номер 325, С. 122345 - 122345

Опубликована: Янв. 3, 2023

Язык: Английский

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