A novel magnetic bifunctional hydrochar catalyst derived from palm leaf residue for biodiesel production: kinetic and thermodynamic studies DOI

Muhammad Aliyu,

Umer Rashid, Toshiki Tsubota

и другие.

Journal of Chemical Technology & Biotechnology, Год журнала: 2024, Номер unknown

Опубликована: Дек. 11, 2024

Abstract BACKGROUND Novel magnetic bifunctional hydrochar‐based catalysts were produced from activated hydrochar derived palm leaf residue (PLRAH) via a wet impregnation technique and used to perform one‐step waste cooking oil (WCO) transesterification produce biodiesel. The evaluated for their acid–base properties, crystallinity, functional groups, magnetism, textural thermal stability, chemical composition, morphology. RESULTS PLRAH‐Fe 2 O 3 /K catalyst performed well in testing, with large specific surface area of 111.08 m g −1 its high basicity value 7.34 mmol , as an acidity 12.67 significantly contributed the WCO transesterification. An optimum biodiesel yield 98.36% was obtained under following conditions: loading wt%, methanol‐to‐WCO molar ratio 12:1, reaction temperature 75 °C duration 4 h yields maintained at >80% after five cycles. complied physicochemical properties stated ASTM D6751. kinetic study also revealed that using approach had pseudo‐first order activation energy () 24.27 kJ mol . Furthermore, thermodynamic variables, including Gibbs free (∆ G o ), enthalpy H entropy S ) transesterification, found be 7.60 −21.78 J K, respectively. This suggests endothermic non‐spontaneous process. CONCLUSION synthesized demonstrated outstanding performance highlighting potential efficient production. © 2024 Society Chemical Industry (SCI).

Язык: Английский

Advances and challenges in humic acid production technologies from natural carbonaceous material wastes DOI
Ehsan Sarlaki, Mohammad Hossein Kianmehr, Nader Marzban

и другие.

Chemical Engineering Journal, Год журнала: 2024, Номер unknown, С. 155521 - 155521

Опубликована: Сен. 1, 2024

Язык: Английский

Процитировано

11

Biodiesel produced from transesterification of palm oil using NaOH-treated activated carbon and pyrolytic char of used tires as catalysts DOI

Khulanuttha Chana,

Bing‐Hung Chen, Duangkamol Na‐Ranong

и другие.

Process Safety and Environmental Protection, Год журнала: 2025, Номер 195, С. 106750 - 106750

Опубликована: Янв. 6, 2025

Язык: Английский

Процитировано

1

Highly efficient sustainable heterogeneous catalyst derived from onion peels (Allium sepa L.) for the ecological biodiesel production using non-edible feedstock DOI

Ichraq El yaakouby,

Miloudi Hlaı̈bi, Noureddine Kamil

и другие.

Energy Conversion and Management, Год журнала: 2024, Номер 315, С. 118801 - 118801

Опубликована: Июль 17, 2024

Язык: Английский

Процитировано

7

Valorization of Bambusa striata shavings into functional superparamagnetic material and its application in biodiesel production: Response surface optimization, kinetics, thermodynamics and economic assessment DOI
Arpita Das, Bidhan Kumbhakar, Pradip Pachfule

и другие.

Process Safety and Environmental Protection, Год журнала: 2024, Номер 189, С. 894 - 910

Опубликована: Июнь 26, 2024

Язык: Английский

Процитировано

6

NaAlO2/CuFe2O4 as a novel basic magnetic heterogeneous catalyst for effective biodiesel production: Synthesis, characterization, and optimization via RSM-FCCD modeling approach DOI

Hiarla Cristina Lima dos Santos,

Matheus Arrais Gonçalves,

Vicente da Silva Lima

и другие.

Process Safety and Environmental Protection, Год журнала: 2024, Номер 189, С. 228 - 245

Опубликована: Июнь 15, 2024

Язык: Английский

Процитировано

5

HYDROTHERMAL CARBONIZATION – A CRITICAL OVERVIEW OF ITS ENVIRONMENTAL AND ECONOMIC SUSTAINABILITY DOI
Matheus Cavali, Aline Perin Dresch,

Igor Marcon Belli

и другие.

Journal of Cleaner Production, Год журнала: 2025, Номер unknown, С. 144838 - 144838

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

0

Advances in Hydrothermal Carbonization for Biomass Wastewater Valorization: Optimizing Nitrogen and Phosphorus Nutrient Management to Enhance Agricultural and Ecological Outcomes DOI Open Access
Guoqing Liu, Tao Zhang

Water, Год журнала: 2025, Номер 17(6), С. 800 - 800

Опубликована: Март 11, 2025

This study presents a novel approach that integrates hydrothermal carbonization (HTC) technology with circular economy principles to optimize the management of nitrogen and phosphorus in agricultural wastewater. Given increasing global resource scarcity continuous ecological degradation, valorization biomass wastewater has become critical pathway for promotion sustainable development. Biomass wastewater, which contains crop residues, forestry leftovers, food processing byproducts, long been regarded as useless waste. However, this abundant organic matter possesses significant renewable energy potential. The can significantly reduce environmental pollution. Through optimization HTC process parameters, we achieved an improvement quality yield carbonized products, facilitating efficient recycling utilization resources. research demonstrates transform into valuable biofertilizers, energy, feed, while simultaneously reducing reliance on fossil fuels, decreasing greenhouse gas emissions, mitigating impact activities. paper provides comprehensive exploration application ecosystems, highlighting its beneficial role management, efficiency, pollution reduction. findings suggest holds potential optimizing treatment, promoting recycling, advancing Furthermore, offers theoretical support practical guidance implementation is paramount importance fostering economic development achieving agriculture.

Язык: Английский

Процитировано

0

Waste Palm Leaves-Based Hydrochar Support Catalytic Esterification of Palm Fatty Acid Distillate DOI

Muhammad Aliyu,

Umer Rashid, Wan Azlina Wan Ab Karim Ghani

и другие.

BioEnergy Research, Год журнала: 2024, Номер 17(4), С. 2413 - 2428

Опубликована: Авг. 2, 2024

Язык: Английский

Процитировано

1

Synthesis, characterization, and performance evaluation of different sulfonated lignin-based carbon catalysts for upgrading waste vegetable oil to biodiesel DOI
Zayed Al-Hamamre, Mohammad Alnaief, Jehad Yamin

и другие.

Energy Conversion and Management, Год журнала: 2024, Номер 325, С. 119381 - 119381

Опубликована: Дек. 10, 2024

Язык: Английский

Процитировано

1

Preparation of sulfonated lignin-based carbon aerogel catalyst for biodiesel production from waste vegetable oil DOI
Zayed Al-Hamamre, Ibrahem Altarawneh, Mohammad Alnaief

и другие.

International Journal of Green Energy, Год журнала: 2024, Номер unknown, С. 1 - 18

Опубликована: Ноя. 17, 2024

Using effective green heterogeneous catalysts to produce biodiesel from inexpensive non-food oils is vital for reducing reliance on fossil fuels, meeting increasing global energy demands, and supporting carbon neutrality. This study explores the use of a sulfonated lignin-based aerogel catalyst production waste vegetable oil (WVO). The catalyst, prepared via sol–gel method followed by carbonization sulfonation exhibited specific surface area 78.16 m2/g -SO₃H group density 2.81 ± 0.14 mmol/g, which served as primary active sites. Under optimal conditions; 10 wt% loading, 45:1 methanol-to-WVO molar ratio, 65°C reaction temperature, 5-hr time, achieved maximum conversion 93.3% yield 88.51%. However, decline in performance was observed over repeated cycles, with dropping 51.68% fourth cycle, attributed leaching groups reduction 44.13 m2/g. decrease sulfonic 1.03 0.11 mmol SO₃H g− 1 indicated loss sites, highlighting need improve sites' stability catalyst's structural integrity. produced met ASTM D6751 EN 14,214 standards, demonstrating effectiveness sustainable production.

Язык: Английский

Процитировано

0