A comprehensive review on the need for integrated strategies and process modifications for per- and polyfluoroalkyl substances (PFAS) removal: Current insights and future prospects

Case Studies in Chemical and Environmental Engineering, Год журнала: 2024, Номер 9, С. 100623 - 100623

Опубликована: Янв. 14, 2024

Alarming concern over the persistence and toxicity of per- polyfluoroalkyl substances (PFAS) in environment has created an imperative need for designing redesigning strategies their detection remediation. Conventional PFAS removal technologies that uses physical, chemical, or biological methods. Increase diversity quantity entering necessitated developing more advanced integrated removal. Despite advances reported this domain, there exist a huge research gap to be mentored tackle problems associated with mitigation combined wide variety environment. The possibility combine other emerging contaminants poses additional threat existing treatment methods thereby stressing continuous monitoring updating processes. This review work aims at understanding structure, entry, fate different types Further in-depth discussion regarding levels is elaborated review. process description recent remediation techniques along significance, limitations integration discussed detail. detailed outlook on advantages insight into recently developed outlined

Язык: Английский

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Overview of Per- and Polyfluoroalkyl Substances (PFAS), Their Applications, Sources, and Potential Impacts on Human Health

Pollutants, Год журнала: 2024, Номер 4(1), С. 136 - 152

Опубликована: Март 6, 2024

Per- and polyfluoroalkyl substances (PFAS) belong to a group of synthetic compounds that have recently raised concerns about human health environmental quality due their great prevalence, degradation resistance, potential toxicity. This review focuses on the applications PFAS effects health. Specific emphasis has been laid (i) application/use PFAS, (ii) sources distribution in diverse compartments, (iii) impact Significant humans are associated with exposure i.e., immunotoxicity, thyroid kidney disorders, cancer, etc. Conclusions obtained from studies demonstrate inadequate evidence should not be used justify delaying risk reduction steps for alternatives. can determined different matrices using both traditional analytical approaches, liquid chromatography coupled mass spectrometry (LC-MS/MS) semi-quantitative passive sampling, advanced methods colorimetric, spectrofluorimetric, electrochemical detection. Traditional costly broadly available, while emerging, cost-effective less sensitive unable meet regulatory limits. There is still significant number performed fully comprehend real contamination by PFAS.

Язык: Английский

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All-cause, cardiovascular disease and cancer mortality in the population of a large Italian area contaminated by perfluoroalkyl and polyfluoroalkyl substances (1980–2018)

Environmental Health, Год журнала: 2024, Номер 23(1)

Опубликована: Апрель 16, 2024

Abstract Background Per- and polyfluoroalkyl substances (PFAS) are associated with many adverse health conditions. Among the main effects is carcinogenicity in humans, which deserves to be further clarified. An evident association has been reported for kidney cancer testicular cancer. In 2013, a large episode of surface, ground drinking water contamination PFAS was uncovered three provinces Veneto Region (northern Italy) involving 30 municipalities population about 150,000. We report on temporal evolution all-cause mortality selected cause-specific by calendar period birth cohort local between 1980 2018. Methods The Italian National Institute Health pre-processed made available anonymous data from Statistics death certificate archives residents Vicenza, Padua Verona (males, n = 29,629; females, 29,518) who died Calendar analysis done calculating standardised ratios using total same as reference. performed 20–84 years cumulative ratios. Exposure defined being resident one Red area , where aqueduct supplying fed contaminated groundwater. Results During 34 1985 (assumed beginning date contamination) 2018 (last year availability data), we observed 51,621 deaths vs. 47,731 expected (age- sex-SMR: 108; 90% CI: 107–109). found evidence raised cardiovascular disease (in particular, heart diseases ischemic disease) malignant neoplastic diseases, including Conclusions For first time, an exposure formally demonstrated. regarding consistent previously data.

Язык: Английский

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Estimated scale of costs to remove PFAS from the environment at current emission rates

The Science of The Total Environment, Год журнала: 2024, Номер 918, С. 170647 - 170647

Опубликована: Фев. 6, 2024

Язык: Английский

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PFAS Contamination in Europe: Generating Knowledge and Mapping Known and Likely Contamination with “Expert-Reviewed” Journalism

Environmental Science & Technology, Год журнала: 2024, Номер 58(15), С. 6616 - 6627

Опубликована: Апрель 3, 2024

While the extent of environmental contamination by per- and polyfluoroalkyl substances (PFAS) has mobilized considerable efforts around globe in recent years, publicly available data on PFAS Europe were very limited. In an unprecedented experiment "expert-reviewed journalism" involving 29 journalists seven scientific advisers, a cross-border collaborative project, "Forever Pollution Project" (FPP), drew both methods investigative journalism techniques such as open-source intelligence (OSINT) freedom information (FOI) requests to map across Europe, making public that previously had existed "unseen science". The FPP identified 22,934 known sites, including 20 manufacturing facilities, 21,426 "presumptive sites", 13,745 sites presumably contaminated with fluorinated aqueous film-forming foam (AFFF) discharge, 2911 industrial 4752 related PFAS-containing waste. Additionally, 231 "known users", new category for intermediate level evidence use considered likely be sources. However, true remains significantly underestimated due lack comprehensive geolocation, sampling, data. This model knowledge production dissemination offers lessons researchers, policymakers, about cross-field collaborations transparency.

Язык: Английский

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Magnetic surfactant-modified clay for enhanced adsorption of mixtures of per- and polyfluoroalkyl substances (PFAS) in snowmelt: Improving practical applicability and efficiency

Journal of Hazardous Materials, Год журнала: 2024, Номер 471, С. 134390 - 134390

Опубликована: Апрель 24, 2024

Язык: Английский

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Surface Modification of Graphene Oxide for Fast Removal of Per- and Polyfluoroalkyl Substances (PFAS) Mixtures from River Water

ACS ES&T Water, Год журнала: 2024, Номер 4(7), С. 2968 - 2980

Опубликована: Июнь 11, 2024

Per- and polyfluoroalkyl substances (PFAS) make up a diverse group of industrially derived organic chemicals that are significant concern due to their detrimental effects on human health ecosystems. Although other technologies available for removing PFAS, adsorption remains viable effective method. Accordingly, the current study reported novel type graphene oxide (GO)-based adsorbent tested removal performance toward PFAS from water. Among eight adsorbents tested, GO modified by cationic surfactant, cetyltrimethylammonium chloride (CTAC), GO-CTAC was found be best, showing an almost 100% all 11 tested. The kinetics were best described pseudo-second-order model, indicating rapid adsorption. isotherm data well supported Toth suggesting onto involved complex interactions. Detailed characterization using scanning electron microscopy-energy dispersive X-ray spectroscopy, Fourier transform infrared, thermogravimetric analysis, diffraction, photoelectron spectroscopy confirmed proposed mechanisms, including electrostatic hydrophobic Interestingly, not influenced solution pH, ionic strength, or natural matter. Furthermore, efficiency at in river water demonstrated could suitable capturing real surface

Язык: Английский

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Ecological risk of per- and polyfluorinated alkyl substances in the phytoremediation process: a case study for ecologically keystone species across two generations

The Science of The Total Environment, Год журнала: 2024, Номер 951, С. 174962 - 174962

Опубликована: Июль 26, 2024

Язык: Английский

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Evaluating the efficiency of modified hydrophobic PVDF membrane for the removal of PFOA substances from water by direct contact membrane distillation

Desalination, Год журнала: 2024, Номер 579, С. 117509 - 117509

Опубликована: Март 8, 2024

Язык: Английский

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Changing the structure of PFOA and PFOS: a chemical industry strategy or a solution to avoid thyroid-disrupting effects?

Journal of Endocrinological Investigation, Год журнала: 2024, Номер 47(8), С. 1863 - 1879

Опубликована: Март 24, 2024

Abstract Background The family of perfluoroalkyl and polyfluoroalkyl substances (PFAS) raised concern for their proven bioaccumulation persistence in the environment animals as well hazardous health effects. As a result, new congeners PFAS have rapidly replaced so-called “old long-chain PFAS” (mainly PFOA PFOS), currently out-of-law banned by most countries. These compounds derive from original structure PFAS”, cutting or making little conformational changes to structure, thus obtaining molecules with similar industrial applications. were designed obtain "safer" compounds. Indeed, old-long-chain reported exert thyroid disruptive effects vitro, vivo humans. However, shreds evidence accumulated so far indicate that “restyling” old leads production compounds, not only functionally previous ones but also potentially free adverse bioaccumulation. Studies aimed at characterizing new-PFAS on function some these showed Purpose present review is providing an overview recent data regarding novel alternatives function. Results conclusions An extensive current legislation obtained vitro studies evaluating exposure PFOS alternatives, mixture will be provided.

Язык: Английский

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