Nitrogen-Doped Carbon Supported Nanocobalt for the Synthesis of Functionalized Triazines Via Oxidative Cleavage of Biomass Derived Vicinal Diols as Carbon Synthons DOI
Feng Xie, Xiangyu Zhang, Haibo Liu

и другие.

SSRN Electronic Journal, Год журнала: 2022, Номер unknown

Опубликована: Янв. 1, 2022

The efficient conversion of renewable biomass resources into value-added nitrogen-containing chemicals has become the focus recent research. Herein, we report preparation nitrogen-doped carbon supported cobalt catalysts comprising a unique core−shell structure, and regulation their catalytic behavior in dehydrocyclization reaction. Abundant biomass-derived diols were employed as synthons to react with amidines, they furnished structurally diverse 1,3,5-triazines, class compounds found numerous natural biomedical products. synthetic protocol advantages broad substrate scope, good functional group tolerance, reusable metal catalyst, easily available reactants. method is convenient practical for syntheses versatile triazines advantageous biological physical properties.

Язык: Английский

The epoxy resin system: function and role of curing agents DOI
Tariq Aziz, Fazal Haq, Arshad Farid

и другие.

Carbon letters, Год журнала: 2023, Номер 34(1), С. 477 - 494

Опубликована: Сен. 1, 2023

Язык: Английский

Процитировано

51

Pd-Catalyzed Aryl C–H Amination with Diaziridinone DOI
Jianjun Wang,

Daguo Hu,

Xiao‐Feng Sun

и другие.

Organic Letters, Год журнала: 2023, Номер 25(12), С. 2006 - 2011

Опубликована: Март 16, 2023

This work describes an efficient Pd-catalyzed ortho-C-H amination of N-(quinolin-8-yl)benzamides with di-t-butyldiaziridinone, providing a variety anthranilic amides in good yields. The reaction likely involves the formation pallada(II)heterocycle via aryl C-H activation and subsequent di-t-butyldiaziridinone.

Язык: Английский

Процитировано

8

Nitrogen-doped carbon supported nanocobalt for the synthesis of functionalized triazines via oxidative cleavage of biomass derived vicinal diols as carbon synthons DOI
Xiangyu Zhang, Haibo Liu,

Xing Sheng

и другие.

Journal of Catalysis, Год журнала: 2022, Номер 408, С. 227 - 235

Опубликована: Март 19, 2022

Язык: Английский

Процитировано

12

Copper Catalyst-Supported Modified Magnetic Chitosan for the Synthesis of Novel 2-Arylthio-2,3-dihydroquinazolin-4(1H)-one Derivatives via Chan–Lam Coupling DOI Creative Commons

Nastaran Ghasemi,

Ali Yavari,

Saeed Bahadorikhalili

и другие.

Inorganics, Год журнала: 2022, Номер 10(12), С. 231 - 231

Опубликована: Ноя. 29, 2022

In this paper, magnetic chitosan is used as a support for the immobilization of copper catalyst (Cu@MChit). The fabricated successfully synthesized and characterized by several techniques. activity Cu@MChit evaluated in synthesis novel derivatives 3-alkyl-2-arylthio-2,3-dihydroquinazolin-4(1H)-ones. products are three simple steps via Chan–Lam coupling reaction. synthetic route based on reaction isatoic anhydride an amine, followed with carbon disulfide. Cu@MChit-catalyzed obtained intermediate phenylboronic acid leads to desired products. scope confirmed using various amine high isolated yields.

Язык: Английский

Процитировано

7

Layered Double Hydroxides as Reusable Catalysts for Cyclocondensation of Amidines and Aminoalcohols: Access to Multi-functionalized Oxazolines DOI

Shizhuo Lin,

Xing Sheng,

Xiangyu Zhang

и другие.

The Journal of Organic Chemistry, Год журнала: 2021, Номер 87(2), С. 1366 - 1376

Опубликована: Дек. 29, 2021

An efficient catalytic protocol based on reusable MgAl-layered double hydroxides has been developed for the synthesis of multi-functionalized oxazolines via cyclocondensation amidines and aminoalcohols. The method a broad substrate scope excellent functional group tolerance uses catalyst. catalyst can be conveniently recycled by filtration reused at least five times without obvious deactivation. Additionally, selective ortho C–H silylation was performed using Ru(II) as triethyl silane silylating reagent, which proved to convenient practical versatile organosilyl-functionalized with advantageous biological physical properties.

Язык: Английский

Процитировано

6

A Simple and Efficient [(n-Bu3Sn)2MO4]nCatalyzed Synthesis of Quinazolinones and Dihydroquinazolinones DOI

Simhachalam Gorle,

Vaikunta Rao Lakinani,

Chiranjeevi Yakkanti

и другие.

Polycyclic aromatic compounds, Год журнала: 2021, Номер 42(9), С. 6583 - 6591

Опубликована: Окт. 7, 2021

A novel unprecedented approach for the synthesis of various quinazolinones and dihydroquinazolinones has been using [(n-Bu3Sn)2MO4]n as a catalyst. The reaction screened in solvents gram scale experiment also demonstrated under given conditions. Further, substrate scope recyclability catalyst have studied.

Язык: Английский

Процитировано

3

One-Pot Three-Component Synthesis of 3,4-Dihydroquinazoline Derivatives DOI Open Access

Long Zhao,

Mao-Lin Yang,

Hao Chen

и другие.

Chinese Journal of Organic Chemistry, Год журнала: 2022, Номер 42(11), С. 3740 - 3740

Опубликована: Янв. 1, 2022

A new one-pot synthesis of 3,4-dihydroquinazolines by diethyl azodicarboxylate (DEAD)-promoted oxidative Ugi/ aza-Wittig reaction was developed.The reactions iminophosphoranes 5, N-aryl-1,2,3,4-tetrahydroisoquinolines 6 and acids 7 produced 3-(tetrahydroisoquinolin-1-formyl) substituted 8 in moderate to good yields the presence DEAD tandem Ugi/aza-Wittig reaction.

Язык: Английский

Процитировано

1

Selective Synthesis of 2-(1,2,3-Triazoyl) Quinazolinones through Copper-Catalyzed Multicomponent Reaction DOI Open Access
Manoela Sacramento,

Luís Pedro A. Piúma,

José Edmilson R. Nascimento

и другие.

Catalysts, Год журнала: 2021, Номер 11(10), С. 1170 - 1170

Опубликована: Сен. 27, 2021

We describe here our results from the copper-catalyzed three component reaction of 2-azidobenzaldehyde, anthranilamide and terminal alkynes, using Et3N as base, DMSO solvent. Depending on temperature amount used in reactions, 1,2,3-triazolyl-quinazolinones or 1,2,3-triazolyl-dihydroquinazolinone could be obtained. When reactions were performed at 100 °C 2 equivalents Et3N, was formed 82% yield, whereas carried out 120 1 equivalent provided moderate-to-good yields.

Язык: Английский

Процитировано

1

Nitrogen-Doped Carbon Supported Nanocobalt for the Synthesis of Functionalized Triazines Via Oxidative Cleavage of Biomass Derived Vicinal Diols as Carbon Synthons DOI
Feng Xie, Xiangyu Zhang, Haibo Liu

и другие.

SSRN Electronic Journal, Год журнала: 2022, Номер unknown

Опубликована: Янв. 1, 2022

The efficient conversion of renewable biomass resources into value-added nitrogen-containing chemicals has become the focus recent research. Herein, we report preparation nitrogen-doped carbon supported cobalt catalysts comprising a unique core−shell structure, and regulation their catalytic behavior in dehydrocyclization reaction. Abundant biomass-derived diols were employed as synthons to react with amidines, they furnished structurally diverse 1,3,5-triazines, class compounds found numerous natural biomedical products. synthetic protocol advantages broad substrate scope, good functional group tolerance, reusable metal catalyst, easily available reactants. method is convenient practical for syntheses versatile triazines advantageous biological physical properties.

Язык: Английский

Процитировано

0