Organics, Год журнала: 2024, Номер 5(3), С. 163 - 204
Опубликована: Июль 2, 2024
This review deals with the functionalization of double bonds carried out in presence a chiral catalyst exploiting intramolecular attack to haliranium ions by nucleophilic nitrogen amides or carbamates prepared from achiral aminoalkenes, and C–N formation leads highly enantioenriched nonaromatic heterocycles. A range protocols are reported, emphasizing synthesis many natural biologically active products pharmacological interest according this methodology.
Язык: Английский