Journal of Hazardous Materials, Год журнала: 2022, Номер 439, С. 129532 - 129532
Опубликована: Июль 4, 2022
Язык: Английский
Journal of Hazardous Materials, Год журнала: 2022, Номер 439, С. 129532 - 129532
Опубликована: Июль 4, 2022
Язык: Английский
Environmental Research, Год журнала: 2023, Номер 231, С. 116185 - 116185
Опубликована: Май 17, 2023
Язык: Английский
Процитировано
59Water Research, Год журнала: 2020, Номер 190, С. 116759 - 116759
Опубликована: Дек. 17, 2020
Язык: Английский
Процитировано
126Water Research, Год журнала: 2021, Номер 194, С. 116933 - 116933
Опубликована: Фев. 15, 2021
Язык: Английский
Процитировано
83Water Research, Год журнала: 2019, Номер 169, С. 115201 - 115201
Опубликована: Окт. 18, 2019
Dissolved organic matter (DOM) in groundwater is fundamentally important with respect to biogeochemical reactions, global carbon cycling, heavy metal transport, water treatability and potability. One source of DOM from the transport vadose zone by rainfall recharge. Changes precipitation patterns associated natural climate variability change are expected alter load character released these areas, which ultimately impacts on quality treatability. In order investigate potential changes after recharge, we sampled shallow a coastal peat-rich sand aquifer New South Wales, Australia, during an extended period low (average daily rate < 1.6 mm day−1 over 8 months prior sampling), two events (84 98 respectively). We assess composition correcting for dilution novel combination advanced analytical techniques: liquid chromatography detection (LC-OCD) negative-ion electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS). also chemistry pre- post-rainfall. Post-rainfall, show that dilution-corrected amount highly aromatic molecular formulae (i.e. those categorised into groups polyphenolics condensed aromatics) were 1.7 2.0 times higher respectively than pre-rainfall samples. attribute this flushing peat-derived buried material groundwater. identify periods can lead hydrophilic/HOC ratios (median = 4.9, n 14). Redundancy analysis (RDA) was used compare HOC fraction FT-ICR MS compound groups. has more samples, less similar post-rainfall This suggests decline water-borne hydrophobics observed could be preferential adsorption hydrophobic DOM, making samples treatable potable supply. Post-rainfall observe significant increases arsenic (leading concentrations greater 3 World Health Organisation drinking limit 10 μg / L). Increases due may therefore peatland areas ways impact bioavailability, increase concentrations, reducing ease treatment human consumption. To best our knowledge, first study chemical sedimentary rich environment through multiple techniques.
Язык: Английский
Процитировано
82Environmental Science & Technology, Год журнала: 2021, Номер 55(22), С. 15090 - 15099
Опубликована: Сен. 15, 2021
Microbially derived extracellular polymeric substances (EPSs) occupy a large portion of dissolved organic matter (DOM) in surface waters, but the understanding photochemical behaviors EPS is still very limited. In this study, characteristics from different microbial sources (Shewanella oneidensis, Escherichia coli, and sewage sludge flocs) were investigated terms production reactive species (RS), such as triplet intermediates (3EPS*), hydroxyl radicals (•OH), singlet oxygen (1O2). The steady-state concentrations •OH, 3EPS*, 1O2 varied ranges 2.55–8.73 × 10–17, 3.01–4.56 10–15, 2.08–2.66 10–13 M, respectively, which within range reported for DOM other sources. RS among isolates due to diversity their composition. A strong degradation protein-like components was identified by excitation emission matrix fluorescence with parallel factor analysis, relatively, humic-like remained stable. Fourier-transform ion cyclotron resonance mass spectrometry further revealed that aliphatic resistant irradiation, while portions lower H/C ratios higher O/C more susceptible photolysis, leading phototransformation saturation aromaticity. With EPS, could effectively promote antibiotic tetracycline. findings study provide new insights into photoinduced self-evolution interrelated fate contaminants aquatic environment.
Язык: Английский
Процитировано
77Journal of Environmental Management, Год журнала: 2021, Номер 294, С. 113041 - 113041
Опубликована: Июнь 11, 2021
Язык: Английский
Процитировано
60Chemosphere, Год журнала: 2022, Номер 299, С. 134377 - 134377
Опубликована: Март 29, 2022
Язык: Английский
Процитировано
48Water Research, Год журнала: 2023, Номер 238, С. 120006 - 120006
Опубликована: Апрель 26, 2023
Язык: Английский
Процитировано
31Water Research, Год журнала: 2023, Номер 243, С. 120414 - 120414
Опубликована: Июль 25, 2023
Язык: Английский
Процитировано
29npj Biodiversity, Год журнала: 2024, Номер 3(1)
Опубликована: Фев. 7, 2024
Rivers are an important component of the global carbon cycle and contribute to atmospheric exchange disproportionately their total surface area. Largely, this is because rivers efficiently mobilize, transport metabolize terrigenous organic matter (OM). Notably, our knowledge about magnitude globally relevant fluxes strongly contrasts with lack understanding underlying processes that transform OM. Ultimately, OM processing en route oceans results from a diverse assemblage consumers interacting equally pool resources in spatially complex network heterogeneous riverine habitats. To understand interaction between OM, we must therefore account for spatial configuration, connectivity, landscape context at scales ranging local ecosystems entire networks. Building such explicit framework fluvial across may also help us better predict poorly understood anthropogenic impacts on cycling, instance human-induced fragmentation changes flow regimes, including intermittence. Moreover, current unprecedented human-driven loss biodiversity. This least partly due mechanisms operating scales, as interference migration habitat homogenization, comes largely unknown functional consequences. We advocate here comprehensive networks connecting two aware but disparate lines research (i) metacommunities biodiversity, (ii) biogeochemistry contribution cycle. argue agenda focusing regional scale-that is, river network-to enable deeper mechanistic naturally arising biodiversity-ecosystem functioning coupling major driver biogeochemically fluxes.
Язык: Английский
Процитировано
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