Process Safety and Environmental Protection,
Год журнала:
2024,
Номер
203, С. 583 - 594
Опубликована: Фев. 7, 2024
Heavy
metals
enter
our
environment
through
diverse
resources,
causing
harmful
effects
owing
to
their
inherent
toxicity
and
facile
migration
into
aqueous
medium,
becoming
an
environmental
challenge.
Among
technologies
able
remove
these
contaminants,
the
adsorption
process
emerges
as
a
promising
application
for
water
treatment.
Herein,
functionalized
silica
magnetic
nanoparticles
using
inorganic
organic
have
been
employed
adsorbents
hazards
from
wastewater
effectively.
Magnetic
silicate
core-shell
amino-functionalized
(Fe3O4@SiO2-AP)
nanocomposites
were
synthesised
acrylic
acid
(AA)
para-aminobenzoic
(PABA)
dual
copolymer
Cd
(II)
removal.
The
characterization
analysis
confirmed
formed
crystal
nanostructure
copolymers
chemically
introduced
in
nanoparticle.
results
on
achieved
impressive
qmax
of
32.50
mg/g
at
pH
8,
adsorbent
dosage
3
g/L,
concentration
100
ppm.
laboratory-scale
fixed-bed
column
showed
breakthrough
curves
are
flow
rate
independent,
achieving
metal
removal
99%
405
min,
influent
ion
ppm,
5
mL/min,
1
cm
bed
height.
Freundlich
model
was
most
suitable
fitting
equilibrium
data
(R2adj
=
0.981)
indicating
multi-layer
phenomenon
heterogeneous
surface
sites
nanocomposites.
pseudo-second-order
=0.999)
confirms
that
depends
active
occurs
by
chemical
sorption
mechanism.
reusability
adsorption-desorption
experiments
slightly
decreased
97.5%
86.7%
sixth
cycle
stability,
demonstrating
material
stability.
Nanoscale Advances,
Год журнала:
2024,
Номер
6(6), С. 1611 - 1642
Опубликована: Янв. 1, 2024
Iron
oxide
nanozymes
(IONzymes)
are
a
class
of
magnetic
nanoparticles
that
mimic
the
enzymatic
activity
natural
enzymes.
These
particles
have
received
significant
attention
in
recent
years
due
to
their
unique
properties,
such
as
high
stability,
tunable
responsiveness,
and
ability
act
biocatalysts
for
various
chemical
reactions.
In
this
review,
we
aim
provide
an
overview
production
methods
nanozymes,
including
chemical,
physical,
biological
synthesis.
The
structure
design
also
discussed
detail,
well
applications
fields
biomedicine
environmental
science.
results
studies
latest
advances
field
discussed.
This
review
provides
valuable
insights
into
current
state
highlights
potential
further
development
application
fields.
Advanced Healthcare Materials,
Год журнала:
2024,
Номер
unknown
Опубликована: Июнь 10, 2024
The
recent
decade
has
witnessed
a
remarkable
surge
in
the
field
of
nanoparticles,
from
their
synthesis,
characterization,
and
functionalization
to
diverse
applications.
At
nanoscale,
these
particles
exhibit
distinct
physicochemical
properties
compared
bulk
counterparts,
enabling
multitude
applications
spanning
energy,
catalysis,
environmental
remediation,
biomedicine,
beyond.
This
review
focuses
on
specific
nanoparticle
categories,
including
magnetic,
gold,
silver,
quantum
dots
(QDs),
as
well
hybrid
variants,
specifically
tailored
for
biomedical
A
comprehensive
comparison
prevalent
chemical,
physical,
biological
synthesis
methods
are
presented.
To
enhance
biocompatibility
colloidal
stability,
facilitate
surface
modification
cargo/agent
loading,
surfaces
coated
with
different
synthetic
polymers
very
recently,
cell
membrane
coatings.
utilization
polymer-
or
membrane-coated
nanoparticles
opens
wide
variety
such
magnetic
resonance
imaging
(MRI),
hyperthermia,
photothermia,
sample
enrichment,
bioassays,
drug
delivery,
etc.
With
this
review,
goal
is
provide
toolbox
insights
into
polymer
applications,
while
also
addressing
challenges
involved
translating
laboratory
benchtops
vitro
vivo
Furthermore,
perspectives
future
trends
developments
rapidly
evolving
domain
provided.
International Journal of Molecular Sciences,
Год журнала:
2024,
Номер
25(5), С. 2809 - 2809
Опубликована: Фев. 28, 2024
This
review
focuses
on
the
latest
advancements
in
magnetic
hydroxyapatite
(mHA)
nanoparticles
and
their
potential
applications
nanomedicine
regenerative
medicine.
mHA
have
gained
significant
interest
over
last
few
years
for
great
potential,
offering
advanced
multi-therapeutic
strategies
because
of
biocompatibility,
bioactivity,
unique
physicochemical
features,
enabling
on-demand
activation
control.
The
most
relevant
synthetic
methods
to
obtain
apatite-based
materials,
either
form
iron-doped
HA
showing
intrinsic
properties
or
composite/hybrid
compounds
between
superparamagnetic
metal
oxide
nanoparticles,
are
described
as
highlighting
structure–property
correlations.
Following
this,
this
discusses
application
various
nanomaterials
bone
regeneration
nanomedicine.
Finally,
novel
perspectives
investigated
with
respect
ability
improve
nanocarriers
homogeneous
structures
promote
multifunctional
biological
applications,
such
cell
stimulation
instruction,
antimicrobial
activity,
drug
release
triggering.
Process Safety and Environmental Protection,
Год журнала:
2024,
Номер
203, С. 583 - 594
Опубликована: Фев. 7, 2024
Heavy
metals
enter
our
environment
through
diverse
resources,
causing
harmful
effects
owing
to
their
inherent
toxicity
and
facile
migration
into
aqueous
medium,
becoming
an
environmental
challenge.
Among
technologies
able
remove
these
contaminants,
the
adsorption
process
emerges
as
a
promising
application
for
water
treatment.
Herein,
functionalized
silica
magnetic
nanoparticles
using
inorganic
organic
have
been
employed
adsorbents
hazards
from
wastewater
effectively.
Magnetic
silicate
core-shell
amino-functionalized
(Fe3O4@SiO2-AP)
nanocomposites
were
synthesised
acrylic
acid
(AA)
para-aminobenzoic
(PABA)
dual
copolymer
Cd
(II)
removal.
The
characterization
analysis
confirmed
formed
crystal
nanostructure
copolymers
chemically
introduced
in
nanoparticle.
results
on
achieved
impressive
qmax
of
32.50
mg/g
at
pH
8,
adsorbent
dosage
3
g/L,
concentration
100
ppm.
laboratory-scale
fixed-bed
column
showed
breakthrough
curves
are
flow
rate
independent,
achieving
metal
removal
99%
405
min,
influent
ion
ppm,
5
mL/min,
1
cm
bed
height.
Freundlich
model
was
most
suitable
fitting
equilibrium
data
(R2adj
=
0.981)
indicating
multi-layer
phenomenon
heterogeneous
surface
sites
nanocomposites.
pseudo-second-order
=0.999)
confirms
that
depends
active
occurs
by
chemical
sorption
mechanism.
reusability
adsorption-desorption
experiments
slightly
decreased
97.5%
86.7%
sixth
cycle
stability,
demonstrating
material
stability.
