Novel approach for preparation of the energy-safety balanced cocrystals of attractive nitramines via coagglomeration DOI Creative Commons
Veerabhadragouda B. Patil, Svatopluk Zeman

FirePhysChem, Год журнала: 2024, Номер 4(4), С. 283 - 294

Опубликована: Март 6, 2024

Co-agglomeration unique crystal engineering approach; in which the co-precipitated micro-particles of nitramines with other energetic materials co-agglomerated by slurry method; to modify properties attractive like CL20, HMX, BCHMX, and RDX etc. The interesting structural modifications newly prepared crystals (CACs) one are discussed here. There notable variations morphologies packing crystals, including key relatively high density, melting point, impact sensitivity, detonation properties. These CACs overwhelming majority showing co-crystals. Apart from these aspects, co-agglomeration provides a huge opportunity tune performance existing is easy scale-up for industrial level. preliminary results also suggest that chemical factors involved preparation have tremendous improvements than conventional crystallization. With technological optimization this method can be employable scale production.

Язык: Английский

Decreasing the hygroscopicity of ammonium dinitramide (ADN) through cocrystallization DOI Creative Commons
Shen Qiao, Hongzhen Li, Zongwei Yang

и другие.

Energetic Materials Frontiers, Год журнала: 2022, Номер 3(2), С. 84 - 89

Опубликована: Апрель 5, 2022

To decrease the hygroscopicity of ADN—a energetic oxidizer, this study developed a new cocrystal composed ADN and 18C6 (18-crown-6) at 1:1 ​M ratio through cocrystallization using solvent evaporation method. The structure ADN/18C6 cocrystal, which has been confirmed single X-ray diffraction (SXRD), indicates that formation is attributed to strong intermolecular hydrogen bond interactions between ammonium ions crown ether cycles. melting point 151.5 ​°C, significantly higher than those its respective components: 93.6 ​°C 43.2 18C6. Notably, nearly non-hygroscopic compared with ADN. cocrystal's rate 0.9% when exposed air relative humidity (RH) 60% temperature 30 for 12 ​h. By comparison, ADN's 18% under same conditions. In addition, impact sensitivity 18 ​J, substantially lower raw (2.5 ​J). These results show offers an effective way reduce

Язык: Английский

Процитировано

19
Continuous, safe and large-scale preparation of insensitive high-energy TATB/HMX composite particles by microfluidic self-assembly technology DOI
Song Zhang,

Le‐Wu Zhan,

Guang-kai Zhu

и другие.

Chemical Engineering Science, Год журнала: 2022, Номер 264, С. 118160 - 118160

Опубликована: Окт. 5, 2022

Язык: Английский

Процитировано

19
Theoretical investigations on stability, sensitivity, energetic performance, and mechanical properties of CL-20/TNAD cocrystal explosive by molecular dynamics method DOI

Guiyun Hang,

Jintao Wang, Tao Wang

и другие.

Journal of Molecular Modeling, Год журнала: 2022, Номер 28(3)

Опубликована: Фев. 12, 2022

Язык: Английский

Процитировано

17
Comparative Studies of Synthesis, Performance, and Applications of Recently Developed CL-20 Based Co-crystals DOI

Qamar‐un‐Nisa Tariq,

Maher‐un‐Nisa Tariq,

Wen‐Shuai Dong

и другие.

Crystal Growth & Design, Год журнала: 2023, Номер 23(9), С. 6974 - 6987

Опубликована: Авг. 19, 2023

Owing to promising characteristics including a high heat of formation (100 kcal·mol–1), density (2.04 g·cm–3), and powerful explosive nature (14–20% more potent than 1,3,5,7-tetranitro-1,3,5,7-tetrazocane (HMX)), the hollow cage-type molecular structure polycyclic nitramine 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (HNIW/CL-20) has recently attained significant attention from scientists. Its sensitivity toward mechanical stimuli raises safety concerns. The safety–power contradiction high-energy explosives can be alleviated certain extent via co-crystallization method. It is possible modify properties energetic materials such as melting decomposition point, density, detonation (detonation velocity pressure), sensitivities (friction impact) by forming new chemical composition new/existing molecules through noncovalent interactions (π–π stacking, hydrogen bonds, van der Waals forces). Energetic co-crystals have been developed various approaches solvent evaporation, solvent/nonsolvent, grinding, slurry, resonant acoustic mixing, etc. This Review highlights an interesting overview HNIW/CL-20 based co-crystals, their synthetic methods, intermolecular interactions, physicochemical properties. Moreover, applications, existing problems, challenges for future work on CL-20-based are also discussed.

Язык: Английский

Процитировано

10
Novel approach for preparation of the energy-safety balanced cocrystals of attractive nitramines via coagglomeration DOI Creative Commons
Veerabhadragouda B. Patil, Svatopluk Zeman

FirePhysChem, Год журнала: 2024, Номер 4(4), С. 283 - 294

Опубликована: Март 6, 2024

Co-agglomeration unique crystal engineering approach; in which the co-precipitated micro-particles of nitramines with other energetic materials co-agglomerated by slurry method; to modify properties attractive like CL20, HMX, BCHMX, and RDX etc. The interesting structural modifications newly prepared crystals (CACs) one are discussed here. There notable variations morphologies packing crystals, including key relatively high density, melting point, impact sensitivity, detonation properties. These CACs overwhelming majority showing co-crystals. Apart from these aspects, co-agglomeration provides a huge opportunity tune performance existing is easy scale-up for industrial level. preliminary results also suggest that chemical factors involved preparation have tremendous improvements than conventional crystallization. With technological optimization this method can be employable scale production.

Язык: Английский

Процитировано

4