Green Chemistry, Год журнала: 2022, Номер 24(5), С. 1809 - 1894
Опубликована: Янв. 1, 2022
A comprehensive and critical overview of the sustainable strategies for direct C–H bond arylation (hetero)arenes, based on use recoverable catalysts, solvents non-conventional energy sources, has been performed.
Язык: Английский
Frontiers in Bioengineering and Biotechnology, Год журнала: 2021, Номер 9
Опубликована: Март 9, 2021
Low molecular weight polycyclic aromatic hydrocarbons (PAHs) like naphthalene and substituted naphthalenes (methylnaphthalene, naphthoic acids, 1-naphthyl N -methylcarbamate, etc.) are used in various industries exhibit genotoxic, mutagenic, and/or carcinogenic effects on living organisms. These synthetic organic compounds (SOCs) or xenobiotics considered as priority pollutants that pose a critical environmental public health concern worldwide. The extent of anthropogenic activities emissions from coal gasification, petroleum refining, motor vehicle exhaust, agricultural applications determine the concentration, fate, transport these ubiquitous recalcitrant compounds. Besides physicochemical methods for cleanup/removal, green eco-friendly technology bioremediation, using microbes with ability to degrade SOCs completely convert non-toxic by-products, has been safe, cost-effective, promising alternative. Various bacterial species soil flora belonging Proteobacteria ( Pseudomonas , Pseudoxanthomonas Comamonas Burkholderia Novosphingobium ), Firmicutes Bacillus Paenibacillus Actinobacteria Rhodococcus Arthrobacter ) displayed SOCs. Metabolic studies, genomic metagenomics analyses have aided our understanding catabolic complexity diversity present simple life forms which can be further applied efficient biodegradation. prolonged persistence PAHs led evolution new degradative phenotypes through horizontal gene transfer genetic elements plasmids, transposons, phages, islands, integrative conjugative elements. Systems biology engineering either specific isolates mock community (consortia) might achieve complete, rapid, bioremediation synergistic actions. In this review, we highlight metabolic routes diversity, makeup cellular responses/adaptations by naphthalene-degrading bacteria. This will provide insights into ecological aspects field application strain optimization bioremediation.
Язык: Английский
Процитировано
119
Advanced Science, Год журнала: 2022, Номер 9(26)
Опубликована: Июль 19, 2022
Current interest toward ionic liquids (ILs) stems from some of their novel characteristics, like low vapor pressure, thermal stability, and nonflammability, integrated through high conductivity broad range electrochemical strength. Nowadays, represent a new category chemical-based compounds for developing superior multifunctional substances with potential in several fields. ILs can be used solvents such as salt electrolyte additional materials. By adding functional physiochemical variety IL-based electrolytes also energy storage purposes. It is hoped that the present review will supply guidance future research focused on polymer nanocomposites sensors, performance, biomedicine, environmental applications. Additionally, comprehensive overview about polymer-based composites' components, including classification types matrix available provided this review. More focus placed upon ILs-based polymeric multiple applications biosensors, energy-related materials, actuators, environmental, aviation aerospace industries. At last, existing challenges prospects field are discussed concluding remarks provided.
Язык: Английский
Процитировано
116
Case Studies in Chemical and Environmental Engineering, Год журнала: 2021, Номер 3, С. 100104 - 100104
Опубликована: Апрель 23, 2021
The widespread consumption of electronic devices has made spent batteries an ongoing economic and ecological concern with a compound annual growth rate up to 8% during 2018, expected reach between 18% 30% 2030. There is lack regulations for the proper storage management waste streams that enables their accumulation in open settings leakage hazardous substances into environment on landfill settings. In addition, recent trends battery manufacture dictate use emerging materials like ionic liquids electrolytes nanostructures cathodes enhance energetic properties lifespan. full impact novel compounds still uncertain could cause further hindrances recycling containment efforts. Currently, only handful countries are able recycle mass-produced lithium batteries, accounting 5% total more than 345,000 tons 2018. This mini review aims integrate currently reported contaminants present potential environmental impact, current strategies detection as evidence policy regulation.
Язык: Английский
Процитировано
113
International Journal of Molecular Sciences, Год журнала: 2022, Номер 23(2), С. 645 - 645
Опубликована: Янв. 7, 2022
Deep eutectic solvents (DESs) are one of the most rapidly evolving types solvents, appearing in a broad range applications, such as nanotechnology, electrochemistry, biomass transformation, pharmaceuticals, membrane technology, biocomposite development, modern 3D-printing, and many others. The their applicability continues to expand, which demands development new DESs with improved properties. To do so requires an understanding fundamental relationship between structure properties DESs. Computer simulation machine learning techniques provide fruitful approach they can predict reveal physical mechanisms readily be linked experiments. This review is devoted computational research describes technical features DES simulations corresponding perspectives on various applications. aim demonstrate current frontiers discuss future perspectives.
Язык: Английский
Процитировано
83
Green Chemistry, Год журнала: 2022, Номер 24(5), С. 1809 - 1894
Опубликована: Янв. 1, 2022
A comprehensive and critical overview of the sustainable strategies for direct C–H bond arylation (hetero)arenes, based on use recoverable catalysts, solvents non-conventional energy sources, has been performed.
Язык: Английский
Процитировано
72