A facile method for in-situ detection of thiabendazole residues in fruit and vegetable peels using Surface-Enhanced Raman Spectroscopy DOI Creative Commons

María Luz Rizzato,

A. Picone, Rosana M. Romano

и другие.

Talanta Open, Год журнала: 2023, Номер 7, С. 100223 - 100223

Опубликована: Апрель 28, 2023

A flexible Surface-Enhanced Raman Spectroscopy (SERS) substrate based on silver nanoparticles encapsulated in an agar gel has been probed to detect the fungicide thiabendazole (TBZ) reaching a limit of detection (LOD) 30 ng/cm2. In addition, simple and sensitive strategy was employed for in-situ TBZ fruit vegetable peels. For that purpose, peels different fruits vegetables were intentionally contaminated with amount TBZ, analyte subsequently extracted within few seconds by gently rubbing surface SERS substrate. The lowest value detected eggplant green pepper 50 values achieved apple pear 0.20 μg/cm2 40 ng/cm2, respectively. On other hand, tomato strawberry 0.50 μg/cm2. variation sensitivity can be attributed differences properties above results show this further contaminants practical applications food safety inspection.

Язык: Английский

Quantum Dots‐Engineered Flexible Hydrogel as Plant‐Wearable Sensor for on‐Site Profiling Dynamic Pesticide Degradation DOI
Jianling Chen, Chenfei Wang,

Xinda Huang

и другие.

Advanced Functional Materials, Год журнала: 2025, Номер unknown

Опубликована: Янв. 20, 2025

Abstract Engineering wearable devices for in situ and on‐site monitoring of pesticide residues from plants a non‐destructive manner is great research value but remains huge challenge. In this study, plant‐wearable fluorescence sensor CdTe CDs@PVA@AG, designed constructed by embedding QDs polyvinyl alcohol (PVA) agarose (AG)‐co‐assembled double‐network hydrogel to transmit on‐the‐scene pesticides messages. Harnessing red emission stimuli‐responsive performance QDs, as well hydrogel's excellent flexibility, high adhesion, porous network, CDs@PVA@AG endowed with quantitative response thiram at ≈µ m level within 2 min through promoting silence conjunction the transformation images into primary colors digital signals. More interestingly, capable being tightly pasted onto various crops’ surfaces then not only explored appraise residue levels also profile dynamic degradation, manner. This work opens up new avenue engineer situ, on‐site, capturing information crops, favoring accurate health status rapid healthy development smart agriculture.

Язык: Английский

Процитировано

11

Design, Fabrication, and Applications of SERS Substrates for Food Safety Detection: Review DOI Creative Commons
Ding-Yan Lin, C. Yu, Chin-An Ku

и другие.

Micromachines, Год журнала: 2023, Номер 14(7), С. 1343 - 1343

Опубликована: Июнь 30, 2023

Sustainable and safe food is an important issue worldwide, it depends on cost-effective analysis tools with good sensitivity reality. However, traditional standard chemical methods of safety detection, such as high-performance liquid chromatography (HPLC), gas (GC), tandem mass spectrometry (MS), have the disadvantages high cost long testing time. Those prevented people from obtaining sufficient risk information to confirm their products. In addition, testing, bioassay method, often results in false positives or negatives due little rigor preprocessing samples. So far, currently relies enzyme-linked immunosorbent assay (ELISA), polymerase chain reaction (PCR), HPLC, GC, UV-visible spectrophotometry, MS, all which require significant time train qualified laboratory operators. These factors hindered development rapid monitoring systems, especially remote areas a relative lack resources. Surface-enhanced Raman spectroscopy (SERS) has emerged one choice for that can overcome these dilemmas over past decades. SERS offers advantages chromatographic its portability, non-destructive nature, lower implications. stands, supplemental tool analysis, reinforcing enhancing completeness coverage system. combines portability cheaper detection costs gain advantage analysis. encountered many challenges moving toward regulatory applications safety, quantitative accuracy, poor reproducibility, instability large molecule detection. As result, reality SERS, screening announcements still uncommon. this review article, we compiled current designs fabrications substrates unify requirements opportunities challenges. This expected improve interest sensing field facilitate future.

Язык: Английский

Процитировано

38

In situ self-cleaning PAN/Cu2O@Ag/Au@Ag flexible SERS sensor coupled with chemometrics for quantitative detection of thiram residues on apples DOI

Yuxia Zheng,

Limei Yin,

Heera Jayan

и другие.

Food Chemistry, Год журнала: 2025, Номер 473, С. 143032 - 143032

Опубликована: Янв. 22, 2025

Язык: Английский

Процитировано

1

Factors that Affect Quantification in Surface-Enhanced Raman Scattering DOI
Meikun Fan, Alexandre G. Brolo

ACS Nano, Год журнала: 2025, Номер unknown

Опубликована: Янв. 24, 2025

Surface-enhanced Raman scattering (SERS) is an analytical technique capable of detecting trace amounts specific species. The uniqueness vibrational signatures a major advantage SERS. This combination sensitivity and specificity has motivated researchers to develop diverse methodologies leveraging However, even 50 years after its first observation, SERS still perceived as unreliable for quantification. perception precluded the application in laboratories that rely on consistent quantification (for regulatory purposes, instance). In this review, we describe some aspects lead intensity variations how those challenges were addressed technique. goal identify sources intensities then demonstrate that, with these pitfalls, can be used when factors such nature substrate, experimental conditions, sample preparation, surface chemistry, data analysis are carefully considered tailored particular application.

Язык: Английский

Процитировано

1

ZnO@Ag-Functionalized Paper-Based Microarray Chip for SERS Detection of Bacteria and Antibacterial and Photocatalytic Inactivation DOI

Afang Zhu,

Shujat Ali, Zhen Wang

и другие.

Analytical Chemistry, Год журнала: 2023, Номер 95(50), С. 18415 - 18425

Опубликована: Дек. 7, 2023

Bacterial infections caused by pathogenic microorganisms have become a serious, widespread health concern. Thus, it is essential and required to develop multifunctional platform that can rapidly accurately determine bacteria effectively inhibit or inactivate pathogens. Herein, microarray SERS chip was successfully synthesized using novel metal/semiconductor composites (ZnO@Ag)-ZnO nanoflowers (ZnO NFs) decorated with Ag nanoparticles (Ag NPs) arrayed on paper-based as supporting substrate for in situ monitoring photocatalytic inactivation of bacteria. Typical Gram-positive Staphylococcus aureus Gram-negative Escherichia coli Vibrio parahemolyticus were selected models. Partial least-squares discriminant analysis (PLS-DA) performed minimize the dimensionality spectra data sets cost-effective identification model. The classification accuracy 100, 97.2, 100% S. aureus, E. coli, V. parahemolyticus, respectively. antimicrobial activity ZnO@Ag proved microbroth dilution method, minimum inhibitory concentrations (MICs) 40, 50, 55 μg/mL, Meanwhile, demonstrated remarkable performance under natural sunlight bacteria, rates 97.03 97.56%, As result, not only detected high sensitivity but also confirmed antibacterial sterilization properties. Consequently, offers highly prospective strategies foodborne diseases

Язык: Английский

Процитировано

22

Cellulose Nanofiber Films with Gold Nanoparticles Electrostatically Adsorbed for Facile Surface-Enhanced Raman Scattering Detection DOI

Dewen Xu,

Wei Su,

Yinlong Luo

и другие.

ACS Applied Materials & Interfaces, Год журнала: 2024, Номер unknown

Опубликована: Апрель 24, 2024

Cellulose nanofiber (CNF) holds great promise in applications such as surface-enhanced Raman scattering (SERS), catalysis, esthesia, and detection. This study aimed to build novel CNF-based SERS substrates through a facile synthetic method. Citrate-reduced gold nanoparticles (AuNPs) were adsorbed on the cationized CNF surface due electrostatic interactions, uniform AuNPs@(2,3-epoxypropyl trimethylammonium chloride)EPTMAC@CNF flexible prepared by simple vacuum-assisted filtration The probe molecule methylene blue was chosen assess performance of substrate with sensitivity up 10-9 M, superior signal reproducibility (relative standard deviation (RSD) = 4.67%), storage stability (more than 30 days). Tensile strength tests indicated that films had good mechanical properties. In addition, can easily capture visually identify microplastics water. These results demonstrate potential application flexible, self-assembled AuNPs@EPTMAC@CNF for prompt sensitive detection trace substances.

Язык: Английский

Процитировано

7

Recent advances in ratiometric surface-enhanced Raman spectroscopy sensing strategies DOI
Yan Wu, Jing Liu,

Rong Xu

и другие.

Microchemical Journal, Год журнала: 2024, Номер 199, С. 110127 - 110127

Опубликована: Фев. 7, 2024

Язык: Английский

Процитировано

6

One-Pot Interference-Based Colorimetric Detection of Melamine in Raw Milk via Green Tea-Modified Silver Nanostructures DOI Creative Commons
Upama Das, Rajib Biswas, Nirmal Mazumder

и другие.

ACS Omega, Год журнала: 2024, Номер unknown

Опубликована: Май 9, 2024

Detection of melamine has proven to be a challenge, requiring the use complex analytical techniques. This study introduces an innovative, straightforward one-pot technique for qualitative assessment milk adulterant melamine. Originally, silver nanoparticles (AgNPs) were synthesized by utilizing green tea extract, which acted as both reducing and sensing element. The AgNPs characterized using UV–vis spectroscopy, X-ray diffraction, zeta potential, transmission electron microscopy, field emission scanning Fourier transform infrared spectroscopy. Melamine, rich in –NH2 groups, interacts with biopolyphenols extract through hydrogen bonding. interaction inhibits formation nanoparticles, resulting noticeable colorimetric response. data obtained confirmed standard spectrophotometer validated high-performance liquid chromatography technique. limit detection achieved this scheme was quite low, falling below permissible levels recommended government bodies, e.g., Food Safety Standards Authority India (FSSAI).

Язык: Английский

Процитировано

6

Constructing graphene oxide/Au nanoparticle cellulose membranes for SERS detection of mixed pesticide residues in edible chrysanthemum DOI
Zhilei Zhao,

Mingshuo Cao,

Dizhe Wei

и другие.

The Analyst, Год журнала: 2024, Номер 149(4), С. 1151 - 1159

Опубликована: Янв. 1, 2024

A GO/Au NP cellulose substrate was constructed through layer-by-layer assembly of graphene oxide and Au nanoparticles on a mixed membrane. Surface-enhanced Raman spectroscopy detection 3 pesticides in chrysanthemum demonstrated.

Язык: Английский

Процитировано

5

Optimization of cotton SERS substrates based on different weave structures for surface trace detection DOI

Xiongwei Zhan,

Shuo Zhang,

Peibo Du

и другие.

Optical Materials, Год журнала: 2024, Номер 150, С. 115338 - 115338

Опубликована: Апрель 1, 2024

Язык: Английский

Процитировано

5