Synthesis of Selenium-Decorated N-Oxide Isoquinolines: Arylseleninic Acids in Selenocyclization Reactions DOI Creative Commons
João M. Anghinoni, Sabrina S. Ferreira, Jean C. Kazmierczak

и другие.

The Journal of Organic Chemistry, Год журнала: 2024, Номер 89(16), С. 11272 - 11280

Опубликована: Авг. 1, 2024

Herein, we describe the use of benzeneseleninic acid derivatives (BSA) as a bench-stable and easy to handle selenium reagent access 4-(selanyl)isoquinoline-

Язык: Английский

Selenium-catalyzed selective reactions of carbonyl derivatives: state-of-the-art and future challenges DOI

Xinrui Xiao,

Cheng Guan, Jie Xu

и другие.

Green Chemistry, Год журнала: 2021, Номер 23(13), С. 4647 - 4655

Опубликована: Янв. 1, 2021

Organoselenium-catalyzed reactions of carbonyl derivatives can produce may useful compounds under mild and green conditions. This article aims to summarize the recent advances give a perspective from both chemistry safety viewpoint.

Язык: Английский

Процитировано

52

Photoinduced C(sp3)–H Chalcogenation of Amide Derivatives and Ethers via Ligand-to-Metal Charge-Transfer DOI
Ben Niu, Krishnakumar Sachidanandan, María Victoria Cooke

и другие.

Organic Letters, Год журнала: 2022, Номер 24(25), С. 4524 - 4529

Опубликована: Июнь 21, 2022

A photoinduced, iron(III) chloride-catalyzed C-H activation of

Язык: Английский

Процитировано

23

Highly selective radical isothiocyano-chalcogenization of alkenes with NH4SCN in water DOI
Chao Xu, Ze He,

Xiaokang Kang

и другие.

Green Chemistry, Год журнала: 2021, Номер 23(19), С. 7544 - 7548

Опубликована: Янв. 1, 2021

A sustainable, highly chemoselective, regioselective and cis -selective radical isothiocyano-chalcogenization of alkenes with NH 4 SCN in water is disclosed.

Язык: Английский

Процитировано

25

2‐Benzamide Tellurenyl Iodides: Synthesis and Their Catalytic Role in CO2 Mitigation DOI
Saket Jain, Monojit Batabyal, Raviraj Ananda Thorat

и другие.

Chemistry - A European Journal, Год журнала: 2023, Номер 29(49)

Опубликована: Июнь 20, 2023

Benzamide-derived organochalcogens (chalcogen=S, Se, and Te) have shown promising interest in biological synthetic chemistry. Ebselen molecule derived from benzamide moiety is the most studied organoselenium. However, its heavier congener organotellurium under-explored. Here, an efficient copper-catalyzed atom economical method has been developed to synthesize 2-phenyl-benzamide tellurenyl iodides by inserting a tellurium into carbon-iodine bond of 2-iodobenzamides one pot with 78-95 % yields. Further, Lewis acidic nature Te center basic nitrogen synthesized 2-Iodo-N-(quinolin-8-yl)benzamide enabled them as pre-catalyst for activation epoxide CO2 at 1 atm preparation cyclic carbonates TOF TON values 1447 h-1 4343, respectively, under solvent-free conditions. In addition, 2-iodo-N-(quinolin-8-yl)benzamide also used activating anilines form variety 1,3-diaryl ureas up 95 yield. The mechanistic investigation mitigation done 125 NMR HRMS studies. It seems that reaction proceeds via formation catalytically active Te-N heterocycle, ebtellur intermediate which isolated structurally characterized.

Язык: Английский

Процитировано

11

A base-free copper-assisted synthesis of C2-symmetric spirotelluranes and biaryls based on divergent stoichiometry of Na2Te DOI
Monojit Batabyal, Saket Jain, Aditya Upadhyay

и другие.

Chemical Communications, Год журнала: 2022, Номер 58(50), С. 7050 - 7053

Опубликована: Янв. 1, 2022

A one pot Cu(I)-assisted synthetic methodology has been developed for the preparation of biologically important C2-symmetric spirodiaza, benzyloxy and benzoxytelluranes from 2-bromo-N-aryl benzamides, benzyl alcohols, benzoic acids by using tellurium dianion (Te2-) under base-free conditions. Furthermore, C-C coupled biaryl 1,1'-diamides have prepared an excess Na2Te same reaction The synthesized spirodiazatelluranes served as a potent catalyst reduction H2O2 nitro-Michael reactions.

Язык: Английский

Процитировано

16

Copper-Catalyzed and 1,3-Sulfonyl Migration Enabled Installation of Azaindoles in the Periphery of Aryl Rings: Synthesis of Sulfonylated Pyrrolo[2,3-b]quinolines and Investigation of Antimalarial Potency DOI
Shivani Choudhary,

Gayyur,

Siddhant

и другие.

The Journal of Organic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Апрель 24, 2025

Herein, an atom efficient and one-pot protocol, offering a series of sulfonylated pyrrolo[2,3-b]quinolines via C-N, C-C, C-S bond formation, has been developed with inexpensive copper catalyst. Notably, the reaction proceeds double-annulation followed by 1,3-sulfonyl migration sequence. Moreover, method is applicable to broad range 2-carbonylanilines. Furthermore, synthetic applications scale-up highlight utility potential this protocol. In addition, antimalarial property showed parasite inhibition without cytotoxic effects in mammalian cells.

Язык: Английский

Процитировано

0

Electrochemical Synthesis of 4‐Selenylated Oxazolones via Oxyselenylation of Ynamides DOI Open Access
Jinhui Cai,

Kaili Cen,

Weishuang Li

и другие.

Advanced Synthesis & Catalysis, Год журнала: 2024, Номер unknown

Опубликована: Окт. 19, 2024

Abstract Electrosynthesis of selenylated‐oxazolone derivatives via cascade selenylation/cyclization ynamides was disclosed. A series diaryl diselenides, dialkyl and heteroaryl‐substituted tolerated in this protocol delivered 4‐selenyloxazolones 28–83% yields. The scale‐up reaction the oxidation performed to showcase practicability method. Furthermore, mechanistic experiments indicated that a cationic pathway instead radical probably involved.

Язык: Английский

Процитировано

2

Methylselenized Glucose: Improvement of the Stability of Glucose-Supported Selenium via the End-Capping Strategy DOI
Qiyuan Wang,

Peizi Li,

Tao Li

и другие.

Industrial & Engineering Chemistry Research, Год журнала: 2021, Номер 60(24), С. 8659 - 8663

Опубликована: Июнь 10, 2021

In this work, the end-capping strategy was adopted in selenized material production for first time. Methylselenized glucose, as a new-generation glucose product, designed and synthesized under NaBH4-free conditions, avoiding generation of hydrogen gas. comparison with reported works, new method significantly reduced cost enhanced safety. The produced methylselenized an even more stable low-valent Se it hardly oxidized by air, resulting elevated efficiency serving practical fertilizer Se-enriched crop planting.

Язык: Английский

Процитировано

14

FeCl3-catalyzed three-component aryl-selenylation of alkenes DOI
Chao Xu, Ze He, Hongqin Yang

и другие.

Tetrahedron, Год журнала: 2021, Номер 91, С. 132239 - 132239

Опубликована: Май 27, 2021

Язык: Английский

Процитировано

11

Chalcogenation/pyrrolo(pyrido)annulation of 2-(3-butenyl)quinazolin-4(3H)-ones by arylsulfenyl(selenyl) chlorides DOI
А. И. Васькевич, Nataliia O. Savinchuk, Ruslan I. Vaskevych

и другие.

Tetrahedron, Год журнала: 2022, Номер 111, С. 132722 - 132722

Опубликована: Март 14, 2022

Язык: Английский

Процитировано

8