Organic & Biomolecular Chemistry, Год журнала: 2024, Номер 22(36), С. 7327 - 7331
Опубликована: Янв. 1, 2024
A simple and efficient method to access 4-selenyl-isocoumarin derivatives through visible-light-promoted selenylation/cyclization of o -(1-alkynyl) benzoates has been developed.
Язык: Английский
Asian Journal of Organic Chemistry, Год журнала: 2024, Номер 13(5)
Опубликована: Фев. 16, 2024
Abstract Fused quinolines have gained substantial attention due to their significant biological and wide‐spectrum synthetic applications. This review supplies an encyclopedic document regarding the approaches developed for synthesis of fused‐cyclic based on ring volume size reported thus far. collected information will be valuable medicinal chemists obtain knowledge designing new in order access active compounds.
Язык: Английский
Процитировано
6
The Journal of Organic Chemistry, Год журнала: 2024, Номер 89(6), С. 4176 - 4184
Опубликована: Март 4, 2024
A simple and efficient visible-light-promoted selenylation/cyclization of o-alkynyl benzylazides/o-propargyl arylazides have been realized for the practical synthesis seleno-substituted isoquinolines quinolines. This strategy provides valuable isoquinoline quinoline derivatives via construction one C(sp2)–Se bond C–N within process.
Язык: Английский
Процитировано
4
RSC Advances, Год журнала: 2023, Номер 13(11), С. 7432 - 7435
Опубликована: Янв. 1, 2023
A series of enantioenriched γ-hydroxybutyric acid derivatives were obtained via asymmetric ring-opening reactions D–A cyclopropanes with 1,3-cyclodiones.
Язык: Английский
Процитировано
4
New Journal of Chemistry, Год журнала: 2024, Номер 48(21), С. 9480 - 9485
Опубликована: Янв. 1, 2024
A one-pot strategy has been developed for the synthesis of 3-selenylated pyrazolo[1,5- a ]pyrimidines from amino pyrazoles, chalcones/enaminones, and diselenides through I 2 -catalyzed tandem cascade annulations/C–H selenylation.
Язык: Английский
Процитировано
1
ACS Omega, Год журнала: 2023, Номер 8(39), С. 35809 - 35821
Опубликована: Сен. 20, 2023
Herein, we demonstrated a silver/K2S2O8-mediated highly regio- and diastereoselective 6/5-exo trig radical cascade cyclization of alkyne-tethered cyclohexadienones with sulfonyl hydrazides or sodium sulfinates subsequent selenation to access 6,6-dihydrochromenone 6,5-fused tetrahydro benzofuranone derivatives. This reaction protocol features high functional group compatibility has wide substrate scope providing variety dihydrochromenones derivatives in good excellent yields. The proceeds via the attack alkyne over activated Michael acceptor. TEMPO quenching experiment implies presence intermediate. Further synthetic versatility 6,6- 5,6-fused is also showcased.
Язык: Английский
Процитировано
3
Synthesis, Год журнала: 2024, Номер 56(16), С. 2529 - 2536
Опубликована: Июнь 12, 2024
Abstract A variety of 2-substituted 3-selanyl-chromenones are readily prepared through a cascade selanylation/cyclization alkynyl aryl ketones with sulfonoselenoates. This transformation is performed under metal-free conditions and does not require an additional oxidant. It also has the advantage broad functional group tolerance scalability.
Язык: Английский
Процитировано
0
Organic & Biomolecular Chemistry, Год журнала: 2024, Номер 22(36), С. 7327 - 7331
Опубликована: Янв. 1, 2024
A simple and efficient method to access 4-selenyl-isocoumarin derivatives through visible-light-promoted selenylation/cyclization of o -(1-alkynyl) benzoates has been developed.
Язык: Английский
Процитировано
0