Russian Journal of Organic Chemistry, Год журнала: 2024, Номер 60(11), С. 2086 - 2107
Опубликована: Ноя. 1, 2024
Язык: Английский
Organic Letters, Год журнала: 2024, Номер 26(15), С. 2939 - 2944
Опубликована: Апрель 11, 2024
A selective three-component 1,2-sulfonyl etherification of aryl 1,3-dienes enabled by copper catalysis to afford biologically interesting alkenyl 1,2-sulfone ether derivatives through C–S and C–O bond formation is described. The protocol proceeds with the sulfonyl chloride alcohols under simple, mild, base-free conditions, providing a straightforward route sulfonylated allyl compounds broad functional group tolerance excellent chemo- regioselectivity. Mechanistic studies indicate that alkene difunctionalization includes key copper-mediated single-electron transfer process.
Язык: Английский
Процитировано
12
Angewandte Chemie International Edition, Год журнала: 2024, Номер 63(32)
Опубликована: Май 24, 2024
Abstract Radical‐involved multicomponent difunctionalization of 1,3‐dienes has recently emerged as a promising strategy for rapid synthesis valuable allylic compounds in one‐pot operation. However, the expansion radical scope and enantiocontrol remain two major challenges. Herein, we describe an unprecedented photoinduced copper‐catalyzed highly enantioselective three‐component 1,2‐azidooxygenation with readily available azidobenziodazolone reagent carboxylic acids. This mild protocol exhibits broad substrate scope, high functional group tolerance, exceptional control over chemo‐, regio‐ enantioselectivity, providing practical access to diverse azidated chiral esters. Mechanistic studies imply that copper complex is implicated bifunctional catalyst both photoredox catalyzed azidyl generation C−O cross‐coupling.
Язык: Английский
Процитировано
11
Coordination Chemistry Reviews, Год журнала: 2025, Номер 528, С. 216428 - 216428
Опубликована: Янв. 4, 2025
Язык: Английский
Процитировано
1
Organic Letters, Год журнала: 2024, Номер 26(39), С. 8400 - 8404
Опубликована: Сен. 25, 2024
We describe herein a novel stereoselective
Язык: Английский
Процитировано
2
Asian Journal of Organic Chemistry, Год журнала: 2024, Номер unknown
Опубликована: Окт. 27, 2024
Abstract With Ag/g‐C 3 N 4 semiconductor as the heterogeneous photocatalyst, visible light promoted synthesis of unsymmetric diaryl chalcogenides could be achieved under additive‐free and mild conditions. A series were generated in good to excellent yields with high functional group tolerance. The photocatalyst is easily recovered from reaction mixture reused at least 5 times, opening way for larger‐scale industrial applications this type photocatalytic bond‐forming reactions.
Язык: Английский
Процитировано
1
Angewandte Chemie, Год журнала: 2024, Номер 136(32)
Опубликована: Май 24, 2024
Abstract Radical‐involved multicomponent difunctionalization of 1,3‐dienes has recently emerged as a promising strategy for rapid synthesis valuable allylic compounds in one‐pot operation. However, the expansion radical scope and enantiocontrol remain two major challenges. Herein, we describe an unprecedented photoinduced copper‐catalyzed highly enantioselective three‐component 1,2‐azidooxygenation with readily available azidobenziodazolone reagent carboxylic acids. This mild protocol exhibits broad substrate scope, high functional group tolerance, exceptional control over chemo‐, regio‐ enantioselectivity, providing practical access to diverse azidated chiral esters. Mechanistic studies imply that copper complex is implicated bifunctional catalyst both photoredox catalyzed azidyl generation C−O cross‐coupling.
Язык: Английский
Процитировано
0
Tetrahedron, Год журнала: 2024, Номер unknown, С. 134257 - 134257
Опубликована: Сен. 1, 2024
Язык: Английский
Процитировано
0
Organic & Biomolecular Chemistry, Год журнала: 2024, Номер unknown
Опубликована: Янв. 1, 2024
A three-component radical alkyl-acylation of [1.1.1]propellane to access a diverse array 1,3-disubstituted BCP ketone derivatives.
Язык: Английский
Процитировано
0
The Journal of Organic Chemistry, Год журнала: 2024, Номер unknown
Опубликована: Дек. 28, 2024
An amine-promoted three-component radical selenofunctionalization reaction of alkenes with TBHP and diselenide is disclosed. The conditions are mild suitable for a wide range substrates (29 examples), all give the corresponding hydroxyselenenylation products in moderate to excellent yields. In addition, preliminary studies on mechanism reveal that current method might proceed via pathway. serves as both initiator source hydroxyl group.
Язык: Английский
Процитировано
0
Russian Journal of Organic Chemistry, Год журнала: 2024, Номер 60(11), С. 2086 - 2107
Опубликована: Ноя. 1, 2024
Язык: Английский
Процитировано
0