Russian Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 60(11), P. 2086 - 2107
Published: Nov. 1, 2024
Language: Английский
Organic Letters, Journal Year: 2024, Volume and Issue: 26(15), P. 2939 - 2944
Published: April 11, 2024
A selective three-component 1,2-sulfonyl etherification of aryl 1,3-dienes enabled by copper catalysis to afford biologically interesting alkenyl 1,2-sulfone ether derivatives through C–S and C–O bond formation is described. The protocol proceeds with the sulfonyl chloride alcohols under simple, mild, base-free conditions, providing a straightforward route sulfonylated allyl compounds broad functional group tolerance excellent chemo- regioselectivity. Mechanistic studies indicate that alkene difunctionalization includes key copper-mediated single-electron transfer process.
Language: Английский
Citations
12
Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(32)
Published: May 24, 2024
Abstract Radical‐involved multicomponent difunctionalization of 1,3‐dienes has recently emerged as a promising strategy for rapid synthesis valuable allylic compounds in one‐pot operation. However, the expansion radical scope and enantiocontrol remain two major challenges. Herein, we describe an unprecedented photoinduced copper‐catalyzed highly enantioselective three‐component 1,2‐azidooxygenation with readily available azidobenziodazolone reagent carboxylic acids. This mild protocol exhibits broad substrate scope, high functional group tolerance, exceptional control over chemo‐, regio‐ enantioselectivity, providing practical access to diverse azidated chiral esters. Mechanistic studies imply that copper complex is implicated bifunctional catalyst both photoredox catalyzed azidyl generation C−O cross‐coupling.
Language: Английский
Citations
11
Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 528, P. 216428 - 216428
Published: Jan. 4, 2025
Language: Английский
Citations
1
Organic Letters, Journal Year: 2024, Volume and Issue: 26(39), P. 8400 - 8404
Published: Sept. 25, 2024
We describe herein a novel stereoselective
Language: Английский
Citations
2
Asian Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: unknown
Published: Oct. 27, 2024
Abstract With Ag/g‐C 3 N 4 semiconductor as the heterogeneous photocatalyst, visible light promoted synthesis of unsymmetric diaryl chalcogenides could be achieved under additive‐free and mild conditions. A series were generated in good to excellent yields with high functional group tolerance. The photocatalyst is easily recovered from reaction mixture reused at least 5 times, opening way for larger‐scale industrial applications this type photocatalytic bond‐forming reactions.
Language: Английский
Citations
1
Angewandte Chemie, Journal Year: 2024, Volume and Issue: 136(32)
Published: May 24, 2024
Abstract Radical‐involved multicomponent difunctionalization of 1,3‐dienes has recently emerged as a promising strategy for rapid synthesis valuable allylic compounds in one‐pot operation. However, the expansion radical scope and enantiocontrol remain two major challenges. Herein, we describe an unprecedented photoinduced copper‐catalyzed highly enantioselective three‐component 1,2‐azidooxygenation with readily available azidobenziodazolone reagent carboxylic acids. This mild protocol exhibits broad substrate scope, high functional group tolerance, exceptional control over chemo‐, regio‐ enantioselectivity, providing practical access to diverse azidated chiral esters. Mechanistic studies imply that copper complex is implicated bifunctional catalyst both photoredox catalyzed azidyl generation C−O cross‐coupling.
Language: Английский
Citations
0
Tetrahedron, Journal Year: 2024, Volume and Issue: unknown, P. 134257 - 134257
Published: Sept. 1, 2024
Language: Английский
Citations
0
Organic & Biomolecular Chemistry, Journal Year: 2024, Volume and Issue: unknown
Published: Jan. 1, 2024
A three-component radical alkyl-acylation of [1.1.1]propellane to access a diverse array 1,3-disubstituted BCP ketone derivatives.
Language: Английский
Citations
0
The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 28, 2024
An amine-promoted three-component radical selenofunctionalization reaction of alkenes with TBHP and diselenide is disclosed. The conditions are mild suitable for a wide range substrates (29 examples), all give the corresponding hydroxyselenenylation products in moderate to excellent yields. In addition, preliminary studies on mechanism reveal that current method might proceed via pathway. serves as both initiator source hydroxyl group.
Language: Английский
Citations
0
Russian Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 60(11), P. 2086 - 2107
Published: Nov. 1, 2024
Language: Английский
Citations
0