Copper-catalyzed sulfonylation of alkenes with CH3SSO3Na

BMC Chemistry, Год журнала: 2025, Номер 19(1)

Опубликована: Фев. 22, 2025

A successful methodology for the copper-catalyzed dehydrogenated methylsulfonylation of alkenes utilizing CH3SSO3Na in conjunction with hypervalent iodine reagents was successfully established. This method offers a practical avenue to obtain allyl methyl sulfones and alkenyl by forming C-S bonds. Using C-H bond oxidation sulfonylation strategy Bunte salts, we synthesized total twenty two compounds, including four examples deuterium-substituted molecules, demonstrated one example scale-up reaction.

Язык: Английский

Reactions of alkynes with C–S bond formation: recent developments

Organic & Biomolecular Chemistry, Год журнала: 2024, Номер 22(32), С. 6443 - 6484

Опубликована: Янв. 1, 2024

Alkynes are important in organic synthesis. This review mainly focuses on the recent advances (2013–2023) alkynes with C–S bond formation, based more than 30 kinds of sulfur reagents.

Язык: Английский

Synthetic developments on the preparation of thioethers via photocatalysis

New Journal of Chemistry, Год журнала: 2024, Номер 49(3), С. 651 - 668

Опубликована: Дек. 10, 2024

Sulfide is a widely occurring natural product and pharmaceutically active compound. This review highlights the photochemically mediated thioether synthesis reactions, with emphasis on catalytic mechanism.

Язык: Английский