Titanium Self‐Intercalation in Titanium Diselenide Devices: Insights from In Situ Transmission Electron Microscopy
Advanced Materials,
Год журнала:
2025,
Номер
unknown
Опубликована: Март 4, 2025
Abstract
Metallic
transition
metal
dichalcogenides
(MTMDCs)
are
of
significant
attention
for
various
electronic
applications
due
to
their
anisotropic
conductivity,
high
electron
mobility,
superconductivity,
and
charge‐density‐waves
(CDW).
Understanding
the
correlations
between
properties
structural
transformations
is
crucial.
In
this
study,
a
bias‐induced
transformation
in
vertical
CDW‐based
1T‐TiSe
2
devices,
transitioning
from
1T
metallic
phase
distorted
d
subsequently
an
orthorhombic
Ti
9
Se
conducting
phase,
reported.
Using
ex‐situ
in‐situ
biasing
transmission
microscopy,
dynamic
changes,
while
energy
loss
spectroscopy
analysis
revealed
valence
state
modifications
within
Ti‐rich
layer
after
biasing,
observed.
addition,
effect
varying
thickness
on
maximum
current
value
investigated.
These
observations
reveal
that
increased
requires
higher
voltage
induce
transitions.
insights
contribute
understanding
dynamics
,
highlighting
its
potential
as
promising
material
future
device
applications.
Язык: Английский
Mechanistic Insights into Sulfur Vacancy Engineering in Sns₂ Reram and the Role of Mos₂/Sns₂ Heterostructures
Опубликована: Янв. 1, 2025
Язык: Английский
Oxygen plasma induced improvement of contact resistance and mobility of tellurium field-effect transistor
Applied Physics Letters,
Год журнала:
2025,
Номер
126(19)
Опубликована: Май 12, 2025
Two-dimensional
tellurium
(Te)
has
been
intensely
studied
in
recent
years
due
to
its
outstanding
electrical
properties
and
excellent
air
stability.
Simple
effective
contact
engineering
is
highly
desirable
further
improve
device
performance.
In
this
work,
we
demonstrate
a
simple
strategy
largely
the
metal–Te
quality
by
forming
an
ultrathin
oxide
layer
region
via
O2
plasma
treatment.
The
surface
doped
underlying
Te
layers
degenerately
charge
transfer,
establishing
Ohmic
between
Pd
electrode
with
negative
Schottky
barrier
under
flatband
condition.
This
enables
field-effect
transistor
achieve
electronic
performance,
including
record-low
resistance
of
∼0.16
kΩ·μm
high
mobility
∼1015
cm2V−1s−1
(∼3002
cm2V−1s−1)
at
room
temperature
(low
temperature).
simplicity
CMOS
compatibility
treatment
make
it
promising
candidate
for
applications
Te-based
large-scale
integrated
circuits.
Язык: Английский