Palladium-Catalyzed Asymmetric [3+2] Cycloaddition Reaction of Vinyl Cyclopropane with Electron-Deficient Dienes

Synlett, Год журнала: 2024, Номер unknown

Опубликована: Март 18, 2024

Abstract Palladium-catalyzed asymmetric [3+2] cycloaddition reaction of vinyl cyclopropane and electron-deficient dienes was realized. The proceeded regioselectively on the distant C=C double bond dienes, mainly controlled by steric hindrance 5-substituent dienes. Chiral multi-substituted cyclopentanes bearing three functional groups (monosubstituted alkene, conjugated ester, cyano) continuous stereocenters were obtained in moderate to high yields, diastereoselectivities, enantioselectivities.

Язык: Английский

Dicarbofunctionalization via C–C Bonds Cleavage

Elsevier eBooks, Год журнала: 2024, Номер unknown

Опубликована: Янв. 1, 2024

Язык: Английский

Selected Diastereoselective Transition Metal-Catalyzed Cyclizations

Elsevier eBooks, Год журнала: 2023, Номер unknown, С. 335 - 356

Опубликована: Дек. 19, 2023

Язык: Английский