Chinese Journal of Organic Chemistry, Год журнала: 2023, Номер 43(11), С. 3679 - 3679
Опубликована: Янв. 1, 2023
Язык: Английский
Chinese Journal of Organic Chemistry, Год журнала: 2023, Номер 43(11), С. 3679 - 3679
Опубликована: Янв. 1, 2023
Язык: Английский
Asian Journal of Organic Chemistry, Год журнала: 2024, Номер 13(5)
Опубликована: Фев. 16, 2024
Abstract Fused quinolines have gained substantial attention due to their significant biological and wide‐spectrum synthetic applications. This review supplies an encyclopedic document regarding the approaches developed for synthesis of fused‐cyclic based on ring volume size reported thus far. collected information will be valuable medicinal chemists obtain knowledge designing new in order access active compounds.
Язык: Английский
Процитировано
6Angewandte Chemie International Edition, Год журнала: 2023, Номер 62(30)
Опубликована: Май 23, 2023
Abstract A rhodium(III)‐catalyzed oxidative cyclization of chalcones with internal alkynes is reported, generating biologically important 3,3‐disubstituted 1‐indanones along reusable aromatic aldehydes. This transformation features unique (4+1) reaction mode, excellent regioselectivity in alkyne insertion, broad substrate scope, allows for the construction quaternary carbon centers, and scalable. Steric hindrance from ligand probably controls chemoselectivity this carbocyclization. Importantly, discovery enables a practical two‐step protocol switching overall acetophenones (3+2) to annulation.
Язык: Английский
Процитировано
9Organic Chemistry Frontiers, Год журнала: 2025, Номер unknown
Опубликована: Янв. 1, 2025
The synthesis of benzofuranone-based spiropyrans containing a thiophene, benzothiophene, or indole moiety, their diverse temperature-dependent photochromic properties, and DFT rationalization.
Язык: Английский
Процитировано
0Molecules, Год журнала: 2023, Номер 28(12), С. 4725 - 4725
Опубликована: Июнь 12, 2023
Sequential reactions of aminoalkynes represent a powerful tool to easily assembly biologically important polyfunctionalized nitrogen heterocyclic scaffolds. Metal catalysis often plays key role in terms selectivity, efficiency, atom economy, and green chemistry these sequential approaches. This review examines the existing literature on applications with carbonyls, which are emerging for their synthetic potential. Aspects concerning features starting reagents, catalytic systems, alternative reaction conditions, pathways possible intermediates provided.
Язык: Английский
Процитировано
5Опубликована: Май 17, 2023
Sequential reactions of aminoalkynes represent a powerful tool to easily assembly biologically important polyfunctionalized nitrogen heterocyclic scaffolds. Metal catalysis often plays key role in terms selectivity, efficiency, atom economy and green chemistry these sequential approaches. This review examines the existing literature on applications with carbonyls which are emerging for their synthetic potential. Aspect concerning features starting reagents, catalytic systems, alternative reaction conditions pathways as well possible intermediates provided.
Язык: Английский
Процитировано
4Chinese Journal of Chemistry, Год журнала: 2024, Номер 42(10), С. 1079 - 1083
Опубликована: Янв. 23, 2024
Comprehensive Summary A new family of dibenzoullazine derivatives was synthesized through 1,3‐dipolar cycloaddition polycyclic aromatic azomethine ylides with alkynylbenziodoxoles followed by oxidation. The benziodoxole moiety in the resulting products used as a versatile linchpin for synthesis structurally diverse functional dibenzoullazines that are difficult to access other synthetic methods.
Язык: Английский
Процитировано
1Advanced Synthesis & Catalysis, Год журнала: 2024, Номер 366(10), С. 2312 - 2323
Опубликована: Март 28, 2024
Abstract A range of densely functionalized ullazines have been synthesized by a one‐pot Rh(III)‐catalyzed twofold C−H activation/oxidative annulation N ‐arylpyrroles with alkynes. Electrophilic bromination at 5‐ or 5,7‐ positions the EWG‐substituted ullazine core offers an interesting single double entry for further extended functionalization. Mechanistic considerations suggest two complementary paths, EWG‐assisted and S E Ar, activations. All exhibit strong fluorescence emissions. Ullazines bearing thiophene triarylamine units show significant bathochromic shift in their emission spectra, attributed to more electronic circuits present.
Язык: Английский
Процитировано
1Chemical Science, Год журнала: 2023, Номер 14(40), С. 11203 - 11212
Опубликована: Янв. 1, 2023
An aza-dicyclopenta[ a , g ]naphthalene scaffold was discovered as controllable luminogenic structure, and precise balance of molecular motions unlocks the remarkable narrowband AIEgens.
Язык: Английский
Процитировано
1Tetrahedron, Год журнала: 2024, Номер 166, С. 134224 - 134224
Опубликована: Авг. 30, 2024
Язык: Английский
Процитировано
0Angewandte Chemie, Год журнала: 2023, Номер 135(30)
Опубликована: Май 23, 2023
Abstract A rhodium(III)‐catalyzed oxidative cyclization of chalcones with internal alkynes is reported, generating biologically important 3,3‐disubstituted 1‐indanones along reusable aromatic aldehydes. This transformation features unique (4+1) reaction mode, excellent regioselectivity in alkyne insertion, broad substrate scope, allows for the construction quaternary carbon centers, and scalable. Steric hindrance from ligand probably controls chemoselectivity this carbocyclization. Importantly, discovery enables a practical two‐step protocol switching overall acetophenones (3+2) to annulation.
Язык: Английский
Процитировано
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