Applied Organometallic Chemistry,
Год журнала:
2024,
Номер
39(1)
Опубликована: Окт. 9, 2024
ABSTRACT
A
new
Schiff
base
ligand,
HNMPC
,
was
prepared
and
reacted
with
some
metal
ions,
including
Cu(II),
Ni(II),
Co(II),
Mn(II),
VO(IV).
The
infrared,
electronic,
mass,
electron
spin
resonance,
nuclear
magnetic
thermal
elemental
analysis,
molar
conductance,
susceptibility
measurements
were
used
to
characterize
the
complexes.
ligand
acts
as
a
monoanionic
tridentate
ONO
donor
in
all
complexes,
coordinating
sites
are
C=O
pyridone
C=N,
phenolate
anion.
All
complexes
exhibit
octahedral
configurations,
results
showed
that
ion:ligand
ratio
1:2.
molecular
structural
parameters
of
its
determined
based
on
DFT
level
implemented
Gaussian
09
program
B3LYP/GENECP
method
at
6‐311G(d,p)
basis
set
for
C,
H,
N,
O
atoms
SDD
(Stuttgart/Dresden)
atoms.
theoretical
data
correlated
experimental
results.
Gram‐positive
bacteria,
Gram‐negative
yeast,
fungi
test
current
compounds'
antimicrobial
activity.
Investigating
antitumor
activity
against
HepG2
cell
lines
encouraging
IC
50
values
par
those
cisplatin
.
In
order
determine
affinity
binding
pattern
synthesized
compounds
toward
VEGFR‐2
active
site,
docking
studies
conducted,
data.
Based
obtained
results,
future
work
aimed
synthesize
category
bases
their
derived
from
aminopyridine
derivative
diverse
aldehydes
ketones.
Chinese Journal of Chemistry,
Год журнала:
2024,
Номер
42(19), С. 2346 - 2350
Опубликована: Май 27, 2024
Comprehensive
Summary
Catalytic
and
green
strategies
for
the
synthesis
of
privileged
scaffolds
are
synthetically
appealing.
We
now
report
a
radical‐polar
crossover
(RPC)‐enabled
three‐component
cyclization
bromodifluoroalkyls
with
enaminones
6‐aminouraciles
via
visible‐light‐induced
domino
cyclization.
The
reaction
exhibited
broad
substrate
scope
(>
40
examples)
including
complex
molecules,
which
highlighted
utility
this
strategy
construction
library
bioactive
analogs.
International Journal of Environmental & Analytical Chemistry,
Год журнала:
2024,
Номер
unknown, С. 1 - 29
Опубликована: Авг. 5, 2024
Mercury,
known
for
its
severe
health
and
environmental
impacts
even
in
trace
amounts,
necessitates
effective
removal
from
water
systems.
This
research
focuses
on
preparation
of
a
novel
adsorbent
3,9−bis((4−amino−5−hydroxy−1
H−pyrazol−3−yl)amino)−2,4,8,10−tetraoxa−3,9−diphosphaspiro[5.5]
undecane
3,
9−dioxide
(PADP)
Hg(II)
ions
adsorption.
To
validate
functionalization
steps
elucidate
PADP's
physical
chemical
properties,
comprehensive
array
assays,
including
FTIR,
surface
area,
BET,
TGA,
13CNMR,
Mass
spectra,
31PNMR
and1HNMR
were
employed.
The
study
systematically
examined
several
factors
controlling
mercury
sorption,
temperature,
dosage,
pH,
interaction
time,
concentration
using
the
batch
technique.
Optimal
sorption
effectiveness
was
achieved
at
pH
5,
with
an
time
50
min,
80
mg
dose,
ambient
temperature.
newly
devised
exhibited
impressive
adsorption
capacity
(qe)
357
per
Litre,
empirical
data
fitting
Langmuir
Dubinin−Radushkevich
isotherm
models.
kinetics
followed
second-order
Elovich
Thermodynamic
aspects,
ΔGº,
ΔSº,
ΔHº,
also
investigated,
providing
appreciated
perceptions
into
energetic
dynamics
process.
Thermodynamics
has
shown
that
is
both
endothermic
spontaneous.
Additionally,
occurrence
other
explored,
highlighting
selectivity
modified
Pyrazole
–
Phosphoramidate
removal.
PADP
demonstrates
superior
performance
removing
wastewater
effluents,
outshining
range
natural
synthetic
adsorbents
previously
used
this
purpose.
superiority
evident
when
comparing
(qo)
against
those
adsorbents,
showcasing
exceptional
efficacy
purifying
contamination.
Chinese Journal of Chemistry,
Год журнала:
2024,
Номер
42(12), С. 1394 - 1398
Опубликована: Фев. 23, 2024
Comprehensive
Summary
The
development
of
switchable
solvent‐free
multicomponent
reactions
to
build
high‐value‐added
products
is
an
important
demand
for
organic
synthesis.
Herein,
we
detailed
the
successful
implementation
a
strategy
construction
diverse
4‐fluoroalkyl‐1,4‐dihydropyrimidines
and
4‐fluoroalkyl‐pyrimidines
via
solvent/additive‐free
[3
+
2
1]
annulation,
starting
from
readily
available
enamines,
trifluoroacetaldehyde
hydrate
or
1‐ethoxy‐2,2‐difluoroethanol
amidines
hydrochloride.
This
reaction
conforms
concept
green
synthesis,
provides
new
avenue
access
valuable
fluorinated
heterocycles.
RSC Advances,
Год журнала:
2024,
Номер
14(30), С. 21608 - 21622
Опубликована: Янв. 1, 2024
This
research
developed
a
new
nanocatalyst
by
incorporating
nanocopper
iodide
onto
the
surface
of
layered
double
hydroxides
modified.
enables
green
synthesis
tetrahydrobenzo[
Polymers for Advanced Technologies,
Год журнала:
2024,
Номер
35(10)
Опубликована: Окт. 1, 2024
ABSTRACT
This
work
presents
a
fluorescence
sensor
based
on
nitrogen‐doped
carbon
dots
(N‐CDs)
utilized
for
sequential
detection
of
Hg
2+
and
TNT.
The
N‐CDs
were
produced
by
simple
efficient
hydrothermal
process
involving
the
combination
black
bean
extract
with
citric
acid
(CA)
ethylenediamine
(EDA).
resulting
exhibit
steady
blue
significant
quantum
yield
12%.
We
conducted
thorough
investigation
into
mechanism
which
NCDs
is
reduced
in
presence
.
Our
analyses,
included
Stern–Volmer
quenching
tests,
confirmed
development
stable
complex
between
When
NCDs‐Hg
was
exposed
to
TNT,
selectively
restored.
“on–off–on”
sensing
capacity
allows
monitoring
both
demonstrating
good
sensitivity
selectivity.
has
low
limit
(LOD)
3.1
46
nM
ions
TNT
linear
range
0–40
0–30
μM,
respectively.
study
emphasizes
potential
application
detecting
heavy
metals
explosives
at
same
time.
It
highlights
their
usefulness
sophisticated
environmental
technologies
that
are
suitable
important
applications.
RSC Advances,
Год журнала:
2024,
Номер
14(24), С. 17245 - 17260
Опубликована: Янв. 1, 2024
A
simple
synthetic
method
was
performed
to
design
a
novel
series
of
polycyclic
systems
consisting
carbazole–thiazolidinone–chromone
hybrids
4a–e
and
carbazole–thiazolidinone–pyrazole
5a–e
in
excellent
yields.
