Introduction of the year 2023 DOI Creative Commons

M. A. Quindt,

Taegeun Jo, Luca Nicchio

и другие.

Royal Society of Chemistry eBooks, Год журнала: 2024, Номер unknown, С. 1 - 31

Опубликована: Дек. 18, 2024

In the introduction chapter we introduce volume and its three sections, namely critical reviews, highlights on recent “hot” topics SPR lectures in photochemistry. Furthermore, includes most significant editorial releases photochemistry 2023, by presenting awards, handbooks, special issues reviews.

Язык: Английский

Photocatalytic Oxidative C(sp3)-H/N–H Cross-Dehydrogenative Coupling of Tertiary Anilines with Amides/Imides: Synthesis of N-Mannich Bases DOI

Qiaerbati Adelibieke,

Bulunuer Yusan,

Xiong Wang

и другие.

The Journal of Organic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Апрель 30, 2025

A photocatalytic method for the synthesis of N-Mannich bases has been developed through C(sp3)-H/N-H cross-dehydrogenative coupling N,N-dimethylanilines with amides/imides. This process utilizes 2,4,6-triphenylpyrylium tetrafluoroborate (TPT) as photocatalyst and is conducted at ambient temperature atmospheric air. Various aromatic, heteroaromatic aliphatic (cyclic) amides, well imides were successfully employed, yielding moderate to good results. Preliminary mechanistic isotope-labeling studies indicate that reaction likely proceeds via a single electron transfer pathway involves an α-aminoalkyl radical intermediate.

Язык: Английский

Процитировано

0
Acidity of Saturated (Hetero)cyclic α-Fluoro Carboxylic Acids and Lipophilicity of Their Amide Derivatives DOI

Oleksii Pidvyshennyi,

Kostiantyn P. Melnykov, Oleksandr S. Liashuk

и другие.

Journal of Fluorine Chemistry, Год журнала: 2024, Номер 278, С. 110316 - 110316

Опубликована: Июль 9, 2024

Язык: Английский

Процитировано

1
TMSN3 Initiated Electrochemical Mono-Dealkylation of Tertiary Amides DOI

Anjun Ding,

Meixia Liu,

Yunxiang Jiang

и другие.

The Journal of Organic Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Дек. 13, 2024

N-Dealkylation of amides is a general process in living organisms and organic synthetic chemistry, but an efficient chemical approach for this transformation has not been explored. Herein, we report electrochemical method the monodealkylation wide range tertiary amides, including benzamides, alkyl lactams, sulfonamides. The reaction proceeds smoothly under mild conditions using TMSN3 as initiator limited to deethylation or demethylation. This protocol enables large synthesis, providing valuable tool chemistry.

Язык: Английский

Процитировано

0
Introduction of the year 2023 DOI Creative Commons

M. A. Quindt,

Taegeun Jo, Luca Nicchio

и другие.

Royal Society of Chemistry eBooks, Год журнала: 2024, Номер unknown, С. 1 - 31

Опубликована: Дек. 18, 2024

In the introduction chapter we introduce volume and its three sections, namely critical reviews, highlights on recent “hot” topics SPR lectures in photochemistry. Furthermore, includes most significant editorial releases photochemistry 2023, by presenting awards, handbooks, special issues reviews.

Язык: Английский

Процитировано

0