Introduction of the year 2023 DOI Creative Commons

M. A. Quindt,

Taegeun Jo, Luca Nicchio

et al.

Royal Society of Chemistry eBooks, Journal Year: 2024, Volume and Issue: unknown, P. 1 - 31

Published: Dec. 18, 2024

In the introduction chapter we introduce volume and its three sections, namely critical reviews, highlights on recent “hot” topics SPR lectures in photochemistry. Furthermore, includes most significant editorial releases photochemistry 2023, by presenting awards, handbooks, special issues reviews.

Language: Английский

Photocatalytic Oxidative C(sp3)-H/N–H Cross-Dehydrogenative Coupling of Tertiary Anilines with Amides/Imides: Synthesis of N-Mannich Bases DOI

Qiaerbati Adelibieke,

Bulunuer Yusan,

Xiong Wang

et al.

The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 30, 2025

A photocatalytic method for the synthesis of N-Mannich bases has been developed through C(sp3)-H/N-H cross-dehydrogenative coupling N,N-dimethylanilines with amides/imides. This process utilizes 2,4,6-triphenylpyrylium tetrafluoroborate (TPT) as photocatalyst and is conducted at ambient temperature atmospheric air. Various aromatic, heteroaromatic aliphatic (cyclic) amides, well imides were successfully employed, yielding moderate to good results. Preliminary mechanistic isotope-labeling studies indicate that reaction likely proceeds via a single electron transfer pathway involves an α-aminoalkyl radical intermediate.

Language: Английский

Citations

0
Acidity of Saturated (Hetero)cyclic α-Fluoro Carboxylic Acids and Lipophilicity of Their Amide Derivatives DOI

Oleksii Pidvyshennyi,

Kostiantyn P. Melnykov, Oleksandr S. Liashuk

et al.

Journal of Fluorine Chemistry, Journal Year: 2024, Volume and Issue: 278, P. 110316 - 110316

Published: July 9, 2024

Language: Английский

Citations

1
TMSN3 Initiated Electrochemical Mono-Dealkylation of Tertiary Amides DOI

Anjun Ding,

Meixia Liu,

Yunxiang Jiang

et al.

The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 13, 2024

N-Dealkylation of amides is a general process in living organisms and organic synthetic chemistry, but an efficient chemical approach for this transformation has not been explored. Herein, we report electrochemical method the monodealkylation wide range tertiary amides, including benzamides, alkyl lactams, sulfonamides. The reaction proceeds smoothly under mild conditions using TMSN3 as initiator limited to deethylation or demethylation. This protocol enables large synthesis, providing valuable tool chemistry.

Language: Английский

Citations

0
Introduction of the year 2023 DOI Creative Commons

M. A. Quindt,

Taegeun Jo, Luca Nicchio

et al.

Royal Society of Chemistry eBooks, Journal Year: 2024, Volume and Issue: unknown, P. 1 - 31

Published: Dec. 18, 2024

In the introduction chapter we introduce volume and its three sections, namely critical reviews, highlights on recent “hot” topics SPR lectures in photochemistry. Furthermore, includes most significant editorial releases photochemistry 2023, by presenting awards, handbooks, special issues reviews.

Language: Английский

Citations

0