Ni-catalyzed cross-electrophile alkyl-alkyl coupling reactions
Science China Chemistry,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 3, 2025
Язык: Английский
Ni-Catalyzed Regioselective and Site-divergent Reductive Arylalkylations of Allylic Amines
Chemical Science,
Год журнала:
2025,
Номер
16(10), С. 4442 - 4449
Опубликована: Янв. 1, 2025
Catalytic
methods
by
switching
the
least
parameters
for
regioselective
and
site-divergent
transformations
to
construct
different
architectures
from
identical
readily
available
starting
materials
are
among
most
ideal
catalytic
protocols.
However,
associated
challenge
precisely
control
both
regioselectivity
site
diversity
renders
this
strategy
appealing
yet
challenging.
Herein,
Ni-catalyzed
cross-electrophile
1,2-
1,3-arylalkylations
of
N-acyl
allylic
amines
have
been
developed.
This
reductive
three-component
protocol
enables
1,2-arylalkylation
1,3-arylalkylation
with
aryl
halides
alkyl
excellent
chemo-,
regio-
site-selectivity,
representing
first
example
controlled
migratory
difunctionalization
alkenes
under
conditions.
A
wide
range
terminal
internal
unactivated
amines,
precursors
were
tolerated,
providing
straightforward
efficient
access
diverse
C(sp3)-rich
branched
aliphatic
materials.
Язык: Английский
Oct-B: A Derivative of L-BAIBA Significantly Alleviating High-Fat Diet-Induced Obesity in Mice
Biochemical and Biophysical Research Communications,
Год журнала:
2024,
Номер
734, С. 150739 - 150739
Опубликована: Сен. 25, 2024
Язык: Английский
Recent Advances in Nonprecious Metal Catalysis
Organic Process Research & Development,
Год журнала:
2024,
Номер
unknown
Опубликована: Дек. 7, 2024
As
the
field
of
nonprecious
metal
catalysis
continues
to
expand,
we
pursue
a
review
series
covering
selected
transformations
in
this
area
over
short
time
interval
highlight
practical
advancements.
We
seek
raise
awareness
both
current
art
and
need
continue
development
toward
broader
applications
earth-abundant
metals
chemical
pharmaceutical
industries.
Язык: Английский