Facile synthesis of alkylphosphonates from 4-alkyl-1,4-dihydropyridines via photoinduced formal deformylative phosphonylation

Organic Chemistry Frontiers, Год журнала: 2024, Номер 11(16), С. 4502 - 4507

Опубликована: Янв. 1, 2024

A photoinduced formal deformylative phosphonylation utilizing easily available aldehydes was established, providing a practical synthetic route to alkylphosphonates from aliphatic aldehydes.

Язык: Английский

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Selective Synthesis of Mono- and Bis-Phosphorylated (Dihydro)pyrans via TMSCl-Mediated Cascade Phosphorylation Cycloisomerization of Enynones

Organic Letters, Год журнала: 2024, Номер unknown

Опубликована: Сен. 26, 2024

A chlorotrimethylsilane (TMSCl)-mediated cascade phosphorylation and cycloisomerization of enynones with diphenylphosphine oxides is presented. This methodology enables the highly selective synthesis monophosphorylated 2

Язык: Английский

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Nucleophilic Ring Opening of Donor–Acceptor Cyclopropanes through Umpolung Reactivity of Organochlorophosphines: Phosphine Oxide-Functionalized Boron-Pendanted Compounds

Organic Letters, Год журнала: 2024, Номер unknown

Опубликована: Сен. 27, 2024

We present a novel set of frustrated Lewis pair (FLP) systems that exhibit remarkable ability to promote the ring opening donor-acceptor cyclopropanes (DACs). This FLP-promoted protocol offers umpolung reactivity R

Язык: Английский

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Progress in the P(III)→P(V) Rearrangement Reaction of Phosphine Chlorides and Hydroxyl Containing Compounds

Chinese Journal of Organic Chemistry, Год журнала: 2024, Номер 44(12), С. 3639 - 3639

Опубликована: Янв. 1, 2024

Язык: Английский

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