Organic Letters, Год журнала: 2024, Номер unknown
Опубликована: Дек. 27, 2024
We herein report a photoredox N–S coupling reaction between dialkyl azodicarboxylates and thiols to access sulfenamide scaffolds. This proceeds under mild, green, operationally simple conditions, offering broad scope of sulfenamides with high yields excellent atom efficiency. Mechanistic investigations revealed this followed photoinitiated radical pathway in which iodide plays crucial role as both initiator single-electron reductant.
Язык: Английский