Energetic Materials Frontiers,
Год журнала:
2023,
Номер
4(2), С. 57 - 62
Опубликована: Май 18, 2023
Two
new
tetrazole
ligands
were
designed
and
synthesized
using
simple
methods
in
this
study,
namely
1H-tetrazole-5-carbohydrazide
(HCHT,
1)
2-amino-5-(1H-tetrazol-5-yl)-1,3,4-oxadiazole
(HAOT,
2).
Their
solvent-free
potassium
salts
[K(CHT)]n
(3)
[K(AOT)]n
(4)
are
two-dimensional
energetic
metal-organic
frameworks
(EMOFs),
their
structures
characterized
nuclear
magnetic
resonance
(NMR),
infrared
spectroscopy
(IR),
mass
spectrometry
(MS),
elemental
analysis
(EA),
single-crystal
X-ray
diffraction
(SXRD).
Both
compounds
3
4
exhibit
high
decomposition
temperatures
(Td)
of
314
°C
310
°C,
respectively
highly
insensitive
to
impact
friction
stimuli
(IS
>
40
J,
FS
360
N).
The
detonation
velocity
pressure
calculated
at
9141
m
s−1
29.0
GPa,
respectively,
those
determined
8423
24.5
respectively.
Furthermore,
intermolecular
interactions
analyzed
2D
fingerprint
plots
with
associated
Hirshfeld
surfaces.
In
manner,
two
thermally
stable
EMOFs
developed
based
on
ligands.
The Chemical Record,
Год журнала:
2024,
Номер
unknown
Опубликована: Ноя. 14, 2024
Abstract
This
review
provides
a
comprehensive
overview
of
research
on
1,2,4‐triazoles
conducted
over
the
last
fifteen
years.
1,2,4‐Triazoles
are
highly
significant
in
pharmaceutical
industry,
with
numerous
compounds
from
this
class
used
clinically
as
antifungal,
antiviral,
antibacterial,
anti‐inflammatory,
and
antitubercular
agents.
Beyond
their
relevance,
also
explores
role
material
science
agriculture.
In
science,
gaining
prominence,
particularly
development
energetic
materials
(EMs),
due
to
exceptional
properties
such
thermal
stability,
coordination
ability,
performance
comparable
well‐known
explosives.
Their
applications
extend
polymers,
corrosion
inhibitors,
metal‐organic
frameworks
(MOFs),
they
play
functional
for
sensors,
catalysis,
energy
storage.
Additionally,
addresses
general
aspects
synthetic
methodologies
functionalization
construction
1,2,4‐triazole
ring.
Synthetic
methods
discussed
include
metalation
synthesis,
cyclization
hydrazine
derivatives,
multicomponent
reactions,
amides
amidines,
microwave‐assisted
synthesis.
Given
significance
triazole
scaffold,
its
synthesis
has
garnered
considerable
attention
wide‐ranging
across
various
industrial
sectors.
Inorganic Chemistry Frontiers,
Год журнала:
2021,
Номер
8(22), С. 4864 - 4877
Опубликована: Янв. 1, 2021
Oxidized
MXene-supported
MCo
2
O
4
(oxidized
MXene/MCo
,
M
=
Mn,
Zn,
Cu
and
Co)
nanocomposites
with
an
excellent
catalytic
performance
for
AP
decomposition
were
successfully
synthesized
through
a
facile
hydrothermal
assisted
calcination
method.
Inorganic Chemistry,
Год журнала:
2022,
Номер
61(41), С. 16493 - 16500
Опубликована: Окт. 4, 2022
N-nitration
of
2,6-diamino-3,5-dinitropyrazine
(ANPZ)
leads
to
a
sensitive
energetic
compound
N,N'-(3,5-dinitropyrazine-2,6-diyl)dinitramide.
This
nitro(nitroamino)
was
stabilized
by
synthesizing
salts,
dipotassium
(3,5-dinitropyrazine-2,6-diyl)bis(nitroamide)
(3)
and
diammonium
(4).
Compounds
3
4
are
fully
characterized
single-crystal
X-ray
diffraction.
Compound
exhibits
three-dimensional
metal-organic
framework
(3D
EMOF)
structure
an
outstanding
overall
performance
combining
high
experimental
density
(2.10
g
cm-3),
good
thermal
stability
(Td(onset)
=
220
°C),
calculated
detonation
(D
8300
m
s-1,
P
29.9
GPa).
has
acceptable
(155
moderate
(1.73
8624
30.8
The
sensitivities
compounds
toward
impact
friction
were
determined
following
standard
methods
(BAM).
character
using
red-hot
needle
heated
plate
tests.
results
highlight
3D
EMOF
based
on
six-membered
heterocycle
as
potential
material.
Materials Advances,
Год журнала:
2023,
Номер
4(10), С. 2332 - 2339
Опубликована: Янв. 1, 2023
The
excellent
catalytic
activity
of
Co-NPs@NC
is
attributed
to
the
well-dispersed
Co
NPs,
intrinsic
adsorption
capacity
for
NH
3
,
and
synergistically
enhanced
effect
NC,
which
favor
thermal
decomposition
AP.
The Journal of Organic Chemistry,
Год журнала:
2024,
Номер
89(9), С. 5966 - 5976
Опубликована: Апрель 23, 2024
Polycyclic
energetic
materials
make
up
a
distinctive
class
of
conjugated
structures
that
consist
two
or
more
rings.
In
this
work,
1,3-bis(3,5-dinitro-1
