Carbon nitride based materials: more than just a support for single-atom catalysis

Chemical Society Reviews, Год журнала: 2023, Номер 52(15), С. 4878 - 4932

Опубликована: Янв. 1, 2023

Recently, the missing link between homogeneous and heterogeneous catalysis has been found it was named single-atom (SAC). However, SAC field still faces important challenges, one of which is controlling bonding/coordination single atoms support in order to compensate for increase surface energy when particle size reduced due atomic dispersion. Excellent candidates meet this requirement are carbon nitride (CN)-based materials. Metal can be firmly trapped nitrogen-rich coordination sites CN materials, makes them a unique class hosts preparing catalysts (SACs). As most promising two-dimensional supports stabilize isolated metal atoms, materials have increasingly employed SACs. Herein, we will cover recent advances single-atoms supported by In review, characterization techniques challenges faced topic discussed, commonly synthetic methods delineated different Finally, catalytic performance SACs based on nitrides reviewed with special focus their photocatalytic applications. particular, prove as non-innocent support. The relationship two-way, where change electronic properties support, while features matrix tune activity reactions. highlight frontiers field, including analytical method development, truly controlled methods, allowing fine control loading multi-element synthesis, how understanding two-way exchange behind push next level.

Язык: Английский

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Graphitic carbon nitride (g-C₃N₄) based heterogeneous single atom catalysts: synthesis, characterisation and catalytic applications

Journal of Materials Chemistry A, Год журнала: 2023, Номер 11(16), С. 8599 - 8646

Опубликована: Янв. 1, 2023

The ease of anchoring single atoms on the g-C 3 N 4 matrix, through its abundant nitrogen sites, facilitates a variety atom catalysts for applications in multiple domains catalysis.

Язык: Английский

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Graphitic carbon nitride-based nanostructures as emergent catalysts for carbon monoxide (CO) oxidation

Green Chemistry, Год журнала: 2023, Номер 25(4), С. 1276 - 1310

Опубликована: Янв. 1, 2023

This is the first review that emphasizes engineering of carbon nitride-based catalysts for thermal, electrochemical, and photoelectrochemical CO oxidation reactions experimentally theoretically.

Язык: Английский

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Template-free synthesis of M/g-C3N4 (M = Cu, Mn, and Fe) porous one-dimensional nanostructures for green hydrogen production

Journal of Electroanalytical Chemistry, Год журнала: 2023, Номер 938, С. 117426 - 117426

Опубликована: Апрель 6, 2023

Язык: Английский

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Synergistically interactive MnFeM (M = Cu, Ti, and Co) sites doped porous g-C₃N₄ fiber-like nanostructures for an enhanced green hydrogen production

Green Chemistry, Год журнала: 2023, Номер 25(15), С. 6032 - 6040

Опубликована: Янв. 1, 2023

MnFeM (M = Cu, Ti, and Co) active sites doped porous g-C 3 N 4 nanofibers were developed for efficient electrochemical green H 2 production. MnFeCu/g-C NFs with higher synergism showed the best activity compared to others less synergism.

Язык: Английский

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Structure-activity relationship of tri-metallic Pt-based nanocatalysts for methanol oxidation reaction

Coordination Chemistry Reviews, Год журнала: 2023, Номер 493, С. 215280 - 215280

Опубликована: Июнь 20, 2023

Язык: Английский

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Atomic-level coordination structures meet graphitic carbon nitride (g-C3N4) for photocatalysis: Energy conversion and environmental remediation

Applied Catalysis B Environment and Energy, Год журнала: 2024, Номер unknown, С. 123683 - 123683

Опубликована: Янв. 1, 2024

Язык: Английский

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The synthesis and key features of 3D carbon nitrides (C3N4) used for CO2 photoreduction

Chemical Engineering Journal, Год журнала: 2024, Номер 486, С. 150213 - 150213

Опубликована: Март 6, 2024

Язык: Английский

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Recent advances in heteroatom-doped/hierarchically porous carbon materials: Synthesis, design and potential applications

Progress in Materials Science, Год журнала: 2024, Номер unknown, С. 101408 - 101408

Опубликована: Ноя. 1, 2024

Язык: Английский

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Analysis of fuel properties of hydrochar derived from food waste and biomass: Evaluating varied mixing techniques pre/post-hydrothermal carbonization

Journal of Cleaner Production, Год журнала: 2023, Номер 430, С. 139660 - 139660

Опубликована: Ноя. 10, 2023

Язык: Английский

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