In
the
field
of
energy
storage
technology,
organic
electrodes,
separators,
and
electrolytes
have
unique
advantages
over
inorganic
materials,
such
as
low
cost,
environmental
friendliness,
a
wide
range
applications.
Due
to
organics
light
elements,
abundant
reserves,
recyclability,
they
become
favorable
candidate
materials
for
solving
problems
caused
by
fossil
crisis.
recent
years,
high-performance
branch
covalent
frameworks,
triazine
structures
(CTFs)
attracted
great
interest
due
their
applications
in
electrochemical
storage.
CTFs
gradually
excellent
metal-ion
batteries
large
specific
surface
area,
nitrogen
richness,
customizable
structural
features,
electron
donor-acceptor/conductive
parts.
However,
relatively
poor
conductivity
ring
main
structure
harsh
polycondensation
conditions
limit
its
commercial
application.
To
overcome
these
challenges,
many
effective
strategies
emerged
terms
optimization,
functional
construction,
triazine-based
composites.
This
review
summarizes
detail
synthesis
methods
cathodes,
electrolytes,
separators
past
decade.
It
is
found
that
CTFs,
large-scale
performance
regulation
reached
bottleneck.
hoped
systematic
summary
this
will
provide
strategic
screening
prospects
further
expansion
research
next-generation
batteries.
ACS Applied Polymer Materials,
Год журнала:
2024,
Номер
6(13), С. 7809 - 7818
Опубликована: Июнь 29, 2024
Investigating
the
relationship
between
substituent
groups
of
nanoporous
organic
polymers
and
adsorption
capacities
for
SO2,
NH3,
CO2,
I2
is
a
significant
challenge.
In
this
study,
four
polyaminal
networks
(NPANs)
with
methyl
or
phenyl
were
prepared,
they
demonstrated
high
I2.
The
NPANs,
which
referred
to
as
NPAN-1,
NPAN-2,
NPAN-3,
NPAN-4,
fabricated
via
one-pot
polycondensation
method
by
using
inexpensive
p-phthalaldehyde
(p-PDA)
m-phthalaldehyde
(m-PDA)
6-methyl-1,3,5-triazine-2,4-diamine
(MTDA)
2,4-diamino-6-phenyl-1,3,5-triazine
(DAPT).
NPANs
had
dense
aminal-rich
structure
stable
nanoporosity,
contributed
their
SO2/CO2
selectivities.
Notably,
SO2
capacities,
NH3
CO2
NPAN-1
electron-donating
groups,
higher
than
those
NPAN-2
electron-withdrawing
groups.
This
result
indicated
that
introduction
into
an
NPAN
enhanced
electron
density
nitrogen
atoms
in
network,
leading
increases
study
offers
important
insights
design
synthesis
adjustable
properties
tackle
environmental
industrial
challenges.
Inorganic Chemistry,
Год журнала:
2024,
Номер
63(29), С. 13367 - 13379
Опубликована: Июль 9, 2024
The
extensive
growth
of
nuclear
power
plants
has
a
severe
detrimental
effect
on
human
health
and
the
surroundings
due
to
uncontrolled
unfiltered
release
radioactive
wastes
into
environment.
One
such
waste
is
In
the
field
of
energy
storage
technology,
organic
electrodes,
separators,
and
electrolytes
have
unique
advantages
over
inorganic
materials,
such
as
low
cost,
environmental
friendliness,
a
wide
range
applications.
Due
to
organics
light
elements,
abundant
reserves,
recyclability,
they
become
favorable
candidate
materials
for
solving
problems
caused
by
fossil
crisis.
recent
years,
high-performance
branch
covalent
frameworks,
triazine
structures
(CTFs)
attracted
great
interest
due
their
applications
in
electrochemical
storage.
CTFs
gradually
excellent
metal-ion
batteries
large
specific
surface
area,
nitrogen
richness,
customizable
structural
features,
electron
donor-acceptor/conductive
parts.
However,
relatively
poor
conductivity
ring
main
structure
harsh
polycondensation
conditions
limit
its
commercial
application.
To
overcome
these
challenges,
many
effective
strategies
emerged
terms
optimization,
functional
construction,
triazine-based
composites.
This
review
summarizes
detail
synthesis
methods
cathodes,
electrolytes,
separators
past
decade.
It
is
found
that
CTFs,
large-scale
performance
regulation
reached
bottleneck.
hoped
systematic
summary
this
will
provide
strategic
screening
prospects
further
expansion
research
next-generation
batteries.
