Macromolecular Rapid Communications,
Год журнала:
2024,
Номер
unknown
Опубликована: Сен. 30, 2024
Abstract
Hydrophobic
antifouling
polymers
capable
of
self‐healing
performance
are
highly
desirable
for
industrial
applications.
However,
the
construction
self‐healing,
hydrophobic
is
challenging
considering
their
complex
fouling
environments,
which
humid
in
aqueous
environment.
In
this
work,
a
polymer
containing
Fe
3+
‐catechol
coordination
applicable
to
synthesized.
The
fluoroalkyl
segments
formed
unique
domains
dispersed
polydimethylsiloxane
matrix.
as‐synthesized
can
completely
restore
tensile
strength,
and
efficiency
above
90%
both
artificial
seawater
pure
water
because
dynamic
interactions.
exhibited
properties
against
common
marine
bacteria.
colony
adhesion
processes
damaged
coating
bacteria
characterized
by
laser
confocal
microscopy.
This
strategy
may
be
useful
development
future
polymeric
materials.
Abstract
The
1H‐benzo[f]indole
(Bd[f]),
a
carbazole
(Cz)
isomer
is
first
reported
as
the
source
of
Cz‐based
phosphors
in
2020.
In
this
work,
novel
isomers,
1H‐benzo[g]indole
(Bd[g])
based
derivatives,
are
synthesized
by
one‐step
solvent‐free
mechanical
ball
milling
reaction,
establishing
facile,
efficient,
and
environmentally
friendly
method
for
synthesis
new
Cz
phosphorescent
derivatives
with
high
yields
compared
to
previously
multi‐step
solvent‐based
thermochemical
routes
Bd[f]
low
yields.
Six
Bd[g]
different
substituents,
namely
OCH
3
–Bd,
In–Bd,
Bn–Bd,
F–Bd,
Cl–Bd,
Br–Bd,
synthesized,
which
exhibit
distinctly
single‐crystal
structures
properties.
After
irradiation
365
nm
UV
light,
derivatives‐doped
poly
(methyl
methacrylate)
(PMMA)
films
photoactivated
green
room‐temperature
phosphorescence
ultra‐long
lifetimes
up
1.65
s.
Interestingly,
stable
seawater
along
good
bactericidal
properties,
also
provide
candidates
indole‐based
marine
antifoulants.
This
study
demonstrates
that
an
efficient
benzoindole
heterocycles.
Bd[g],
members
family,
building
units
construct
molecules
besides
Bd[f].
Macromolecular Rapid Communications,
Год журнала:
2024,
Номер
unknown
Опубликована: Сен. 30, 2024
Abstract
Hydrophobic
antifouling
polymers
capable
of
self‐healing
performance
are
highly
desirable
for
industrial
applications.
However,
the
construction
self‐healing,
hydrophobic
is
challenging
considering
their
complex
fouling
environments,
which
humid
in
aqueous
environment.
In
this
work,
a
polymer
containing
Fe
3+
‐catechol
coordination
applicable
to
synthesized.
The
fluoroalkyl
segments
formed
unique
domains
dispersed
polydimethylsiloxane
matrix.
as‐synthesized
can
completely
restore
tensile
strength,
and
efficiency
above
90%
both
artificial
seawater
pure
water
because
dynamic
interactions.
exhibited
properties
against
common
marine
bacteria.
colony
adhesion
processes
damaged
coating
bacteria
characterized
by
laser
confocal
microscopy.
This
strategy
may
be
useful
development
future
polymeric
materials.
