Multifunctional NiO/Ti3+-TiO2 for concurrent Water Reduction and Glycerol Oxidation to Value added products by Sunlight driven photocatalysis DOI
Sivaraj Rajendran,

Simi Saju,

Sunesh S. Mani

и другие.

Journal of Materials Chemistry A, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 25, 2024

Self-doped Ti 3+ containing NiO/Ti –TiO 2 catalysts and their applications towards co-production of H VAPs from a glycerol water mixture by concurrent utilization electrons holes.

Язык: Английский

A review on recent advances in the design and structure-activity correlation of TiO2-based photocatalysts for solar hydrogen production DOI Creative Commons
Sunesh S. Mani, Sivaraj Rajendran, Thomas Mathew

и другие.

Energy Advances, Год журнала: 2024, Номер 3(7), С. 1472 - 1504

Опубликована: Янв. 1, 2024

The recent progress in visible light driven photocatalysis by describing the integration of TiO 2 with variety materials, and how it helps tailoring electronic, structural optical properties towards improved solar H production activity.

Язык: Английский

Процитировано

21
Design of Bi-functional mixed oxide electrodes for selective oxidative C–C cleavage of glycerol to formate and synchronized green hydrogen production DOI
Arindam Saha,

Vasantharadevi Murugiah,

Ravi Ranjan

и другие.

Sustainable Energy & Fuels, Год журнала: 2024, Номер 8(13), С. 2954 - 2968

Опубликована: Янв. 1, 2024

NiCoMn oxide nanoneedles with a cactus-like morphology are shown as bifunctional electrocatalysts that selectively oxidize glycerol to HCOOH and concurrently produce H 2 .

Язык: Английский

Процитировано

9
Aqueous Glycerol to Glyceric Acid and Green Hydrogen by Visible-Light-Driven Photocatalysis with Ni/Co(PO4)2-TiO2: Parallel Utilization of Holes and Electrons DOI

Thazhath R. Nivedhitha,

Himanshu Bajpai,

Jiffin Varghese Oommen

и другие.

ACS Sustainable Chemistry & Engineering, Год журнала: 2024, Номер unknown

Опубликована: Сен. 20, 2024

Язык: Английский

Процитировано

7
Oxidative and selective C–C cleavage of glycerol to glycolaldehyde with atom-like Cu on Cu-TiO2: Photocatalytic water reduction with concurrent glycerol oxidation in sunlight DOI
Himanshu Bajpai,

Thazhath R. Nivedhitha,

Elsa Dais

и другие.

Journal of Catalysis, Год журнала: 2024, Номер 437, С. 115644 - 115644

Опубликована: Июль 9, 2024

Язык: Английский

Процитировано

6
Electrocatalytic and Selective Oxidation of Glycerol to Formate on 2D 3d-Metal Phosphate Nanosheets and Carbon-Negative Hydrogen Generation DOI Creative Commons
Inderjeet Chauhan,

Pothoppurathu M. Vijay,

Ravi Ranjan

и другие.

ACS Materials Au, Год журнала: 2024, Номер 4(5), С. 500 - 511

Опубликована: Июнь 4, 2024

In the landscape of green hydrogen production, alkaline water electrolysis is a well-established, yet not-so-cost-effective, technique due to high overpotential requirement for oxygen evolution reaction (OER). A low-voltage approach proposed overcome not only OER challenge by favorably oxidizing abundant feedstock molecules with an earth-abundant catalyst but also reduce energy input required production. This alternative process generates carbon-negative H

Язык: Английский

Процитировано

4
Electrooxidation of Glycerol to Formic Acid: from Catalyst Design Strategies to Key Coupled Systems DOI Open Access
Chenyang Li,

Tasmia Azam,

Shengwei Li

и другие.

ChemSusChem, Год журнала: 2025, Номер unknown

Опубликована: Март 12, 2025

Abstract As a major by‐product of biodiesel production, glycerol offers significant economic potential when effectively utilized. The electrooxidation to formic acid in couped systems has attracted considerable attentions due its environmental friendliness, cost‐effectiveness, low energy consumption and production high‐value‐added chemicals. This concept presents the key strategies for catalyst design rational construction representative coupled towards efficient acid. Firstly, we overview from four aspects, including heteroatom doping, vacancy engineering, interface component construct highly active sites tune electronic properties electrocatalysts. Subsequently, discuss oxidation acid, highlight importance high‐value added Finally, conclude by outlining current challenges proposing future perspectives, arouse further research interest facilitate development.

Язык: Английский

Процитировано

0
Surface Nanostructuring of Copper Using Fluoride and Chloride DOI Creative Commons
Vicente Pascual‐Llorens, Albert Serrà, Pedro Mazaira

и другие.

ChemElectroChem, Год журнала: 2024, Номер unknown

Опубликована: Сен. 13, 2024

Abstract Copper is an active electrocatalyst for various energy conversion reactions, but its performance depends on the structure of surface sites. In this work, we propose a simple strategy to tailor both roughness and site's geometry copper. To modify copper, oxidize reduce copper polycrystalline electrode in 0.1 M solutions containing sodium fluoride chloride with different chloride/fluoride molar ratios: (0.1‐x) NaF+x NaCl. address anion effect changes geometry, recorded voltammetric fingerprints modified electrodes using lead underpotential deposition (UPD). The analysis suggested that while induces (n10) sites, promotes increase area growth low‐coordinated sites (110) or (111) geometry. Solutions anions induced motifs covered by nanometric clusters, as observed scanning electron microscopy, forming highly defect‐rich surface. Our work provides direct link between electrochemical response ex‐situ structural characterization, compares, detail, nanostructuring

Язык: Английский

Процитировано

1
Multifunctional NiO/Ti3+-TiO2 for concurrent Water Reduction and Glycerol Oxidation to Value added products by Sunlight driven photocatalysis DOI
Sivaraj Rajendran,

Simi Saju,

Sunesh S. Mani

и другие.

Journal of Materials Chemistry A, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 25, 2024

Self-doped Ti 3+ containing NiO/Ti –TiO 2 catalysts and their applications towards co-production of H VAPs from a glycerol water mixture by concurrent utilization electrons holes.

Язык: Английский

Процитировано

0