A review on recent advances in the design and structure-activity correlation of TiO2-based photocatalysts for solar hydrogen production
Energy Advances,
Journal Year:
2024,
Volume and Issue:
3(7), P. 1472 - 1504
Published: Jan. 1, 2024
The
recent
progress
in
visible
light
driven
photocatalysis
by
describing
the
integration
of
TiO
2
with
variety
materials,
and
how
it
helps
tailoring
electronic,
structural
optical
properties
towards
improved
solar
H
production
activity.
Language: Английский
Design of Bi-functional mixed oxide electrodes for selective oxidative C–C cleavage of glycerol to formate and synchronized green hydrogen production
Arindam Saha,
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Vasantharadevi Murugiah,
No information about this author
Ravi Ranjan
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et al.
Sustainable Energy & Fuels,
Journal Year:
2024,
Volume and Issue:
8(13), P. 2954 - 2968
Published: Jan. 1, 2024
NiCoMn
oxide
nanoneedles
with
a
cactus-like
morphology
are
shown
as
bifunctional
electrocatalysts
that
selectively
oxidize
glycerol
to
HCOOH
and
concurrently
produce
H
2
.
Language: Английский
Oxidative and selective C–C cleavage of glycerol to glycolaldehyde with atom-like Cu on Cu-TiO2: Photocatalytic water reduction with concurrent glycerol oxidation in sunlight
Himanshu Bajpai,
No information about this author
Thazhath R. Nivedhitha,
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Elsa Dais
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et al.
Journal of Catalysis,
Journal Year:
2024,
Volume and Issue:
437, P. 115644 - 115644
Published: July 9, 2024
Language: Английский
Aqueous Glycerol to Glyceric Acid and Green Hydrogen by Visible-Light-Driven Photocatalysis with Ni/Co(PO4)2-TiO2: Parallel Utilization of Holes and Electrons
Thazhath R. Nivedhitha,
No information about this author
Himanshu Bajpai,
No information about this author
Jiffin Varghese Oommen
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et al.
ACS Sustainable Chemistry & Engineering,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Sept. 20, 2024
Language: Английский
Electrocatalytic and Selective Oxidation of Glycerol to Formate on 2D 3d-Metal Phosphate Nanosheets and Carbon-Negative Hydrogen Generation
Inderjeet Chauhan,
No information about this author
Pothoppurathu M. Vijay,
No information about this author
Ravi Ranjan
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et al.
ACS Materials Au,
Journal Year:
2024,
Volume and Issue:
4(5), P. 500 - 511
Published: June 4, 2024
In
the
landscape
of
green
hydrogen
production,
alkaline
water
electrolysis
is
a
well-established,
yet
not-so-cost-effective,
technique
due
to
high
overpotential
requirement
for
oxygen
evolution
reaction
(OER).
A
low-voltage
approach
proposed
overcome
not
only
OER
challenge
by
favorably
oxidizing
abundant
feedstock
molecules
with
an
earth-abundant
catalyst
but
also
reduce
energy
input
required
production.
This
alternative
process
generates
carbon-negative
H
Language: Английский
Electrooxidation of Glycerol to Formic Acid: from Catalyst Design Strategies to Key Coupled Systems
Chenyang Li,
No information about this author
Tasmia Azam,
No information about this author
Shengwei Li
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et al.
ChemSusChem,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 12, 2025
Abstract
As
a
major
by‐product
of
biodiesel
production,
glycerol
offers
significant
economic
potential
when
effectively
utilized.
The
electrooxidation
to
formic
acid
in
couped
systems
has
attracted
considerable
attentions
due
its
environmental
friendliness,
cost‐effectiveness,
low
energy
consumption
and
production
high‐value‐added
chemicals.
This
concept
presents
the
key
strategies
for
catalyst
design
rational
construction
representative
coupled
towards
efficient
acid.
Firstly,
we
overview
from
four
aspects,
including
heteroatom
doping,
vacancy
engineering,
interface
component
construct
highly
active
sites
tune
electronic
properties
electrocatalysts.
Subsequently,
discuss
oxidation
acid,
highlight
importance
high‐value
added
Finally,
conclude
by
outlining
current
challenges
proposing
future
perspectives,
arouse
further
research
interest
facilitate
development.
Language: Английский
Surface Nanostructuring of Copper Using Fluoride and Chloride
ChemElectroChem,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Sept. 13, 2024
Abstract
Copper
is
an
active
electrocatalyst
for
various
energy
conversion
reactions,
but
its
performance
depends
on
the
structure
of
surface
sites.
In
this
work,
we
propose
a
simple
strategy
to
tailor
both
roughness
and
site's
geometry
copper.
To
modify
copper,
oxidize
reduce
copper
polycrystalline
electrode
in
0.1
M
solutions
containing
sodium
fluoride
chloride
with
different
chloride/fluoride
molar
ratios:
(0.1‐x)
NaF+x
NaCl.
address
anion
effect
changes
geometry,
recorded
voltammetric
fingerprints
modified
electrodes
using
lead
underpotential
deposition
(UPD).
The
analysis
suggested
that
while
induces
(n10)
sites,
promotes
increase
area
growth
low‐coordinated
sites
(110)
or
(111)
geometry.
Solutions
anions
induced
motifs
covered
by
nanometric
clusters,
as
observed
scanning
electron
microscopy,
forming
highly
defect‐rich
surface.
Our
work
provides
direct
link
between
electrochemical
response
ex‐situ
structural
characterization,
compares,
detail,
nanostructuring
Language: Английский
Multifunctional NiO/Ti3+-TiO2 for concurrent Water Reduction and Glycerol Oxidation to Value added products by Sunlight driven photocatalysis
Journal of Materials Chemistry A,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Nov. 25, 2024
Self-doped
Ti
3+
containing
NiO/Ti
–TiO
2
catalysts
and
their
applications
towards
co-production
of
H
VAPs
from
a
glycerol
water
mixture
by
concurrent
utilization
electrons
holes.
Language: Английский