Multifunctional NiO/Ti3+-TiO2 for concurrent Water Reduction and Glycerol Oxidation to Value added products by Sunlight driven photocatalysis DOI
Sivaraj Rajendran,

Simi Saju,

Sunesh S. Mani

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 25, 2024

Self-doped Ti 3+ containing NiO/Ti –TiO 2 catalysts and their applications towards co-production of H VAPs from a glycerol water mixture by concurrent utilization electrons holes.

Language: Английский

A review on recent advances in the design and structure-activity correlation of TiO2-based photocatalysts for solar hydrogen production DOI Creative Commons
Sunesh S. Mani, Sivaraj Rajendran, Thomas Mathew

et al.

Energy Advances, Journal Year: 2024, Volume and Issue: 3(7), P. 1472 - 1504

Published: Jan. 1, 2024

The recent progress in visible light driven photocatalysis by describing the integration of TiO 2 with variety materials, and how it helps tailoring electronic, structural optical properties towards improved solar H production activity.

Language: Английский

Citations

18

Design of Bi-functional mixed oxide electrodes for selective oxidative C–C cleavage of glycerol to formate and synchronized green hydrogen production DOI
Arindam Saha,

Vasantharadevi Murugiah,

Ravi Ranjan

et al.

Sustainable Energy & Fuels, Journal Year: 2024, Volume and Issue: 8(13), P. 2954 - 2968

Published: Jan. 1, 2024

NiCoMn oxide nanoneedles with a cactus-like morphology are shown as bifunctional electrocatalysts that selectively oxidize glycerol to HCOOH and concurrently produce H 2 .

Language: Английский

Citations

9

Oxidative and selective C–C cleavage of glycerol to glycolaldehyde with atom-like Cu on Cu-TiO2: Photocatalytic water reduction with concurrent glycerol oxidation in sunlight DOI
Himanshu Bajpai,

Thazhath R. Nivedhitha,

Elsa Dais

et al.

Journal of Catalysis, Journal Year: 2024, Volume and Issue: 437, P. 115644 - 115644

Published: July 9, 2024

Language: Английский

Citations

5

Aqueous Glycerol to Glyceric Acid and Green Hydrogen by Visible-Light-Driven Photocatalysis with Ni/Co(PO4)2-TiO2: Parallel Utilization of Holes and Electrons DOI

Thazhath R. Nivedhitha,

Himanshu Bajpai,

Jiffin Varghese Oommen

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 20, 2024

Language: Английский

Citations

5

Electrocatalytic and Selective Oxidation of Glycerol to Formate on 2D 3d-Metal Phosphate Nanosheets and Carbon-Negative Hydrogen Generation DOI Creative Commons
Inderjeet Chauhan,

Pothoppurathu M. Vijay,

Ravi Ranjan

et al.

ACS Materials Au, Journal Year: 2024, Volume and Issue: 4(5), P. 500 - 511

Published: June 4, 2024

In the landscape of green hydrogen production, alkaline water electrolysis is a well-established, yet not-so-cost-effective, technique due to high overpotential requirement for oxygen evolution reaction (OER). A low-voltage approach proposed overcome not only OER challenge by favorably oxidizing abundant feedstock molecules with an earth-abundant catalyst but also reduce energy input required production. This alternative process generates carbon-negative H

Language: Английский

Citations

4

Electrooxidation of Glycerol to Formic Acid: from Catalyst Design Strategies to Key Coupled Systems DOI Open Access
Chenyang Li,

Tasmia Azam,

Shengwei Li

et al.

ChemSusChem, Journal Year: 2025, Volume and Issue: unknown

Published: March 12, 2025

Abstract As a major by‐product of biodiesel production, glycerol offers significant economic potential when effectively utilized. The electrooxidation to formic acid in couped systems has attracted considerable attentions due its environmental friendliness, cost‐effectiveness, low energy consumption and production high‐value‐added chemicals. This concept presents the key strategies for catalyst design rational construction representative coupled towards efficient acid. Firstly, we overview from four aspects, including heteroatom doping, vacancy engineering, interface component construct highly active sites tune electronic properties electrocatalysts. Subsequently, discuss oxidation acid, highlight importance high‐value added Finally, conclude by outlining current challenges proposing future perspectives, arouse further research interest facilitate development.

Language: Английский

Citations

0

Surface Nanostructuring of Copper Using Fluoride and Chloride DOI Creative Commons
Vicente Pascual‐Llorens, Albert Serrà, Pedro Mazaira

et al.

ChemElectroChem, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 13, 2024

Abstract Copper is an active electrocatalyst for various energy conversion reactions, but its performance depends on the structure of surface sites. In this work, we propose a simple strategy to tailor both roughness and site's geometry copper. To modify copper, oxidize reduce copper polycrystalline electrode in 0.1 M solutions containing sodium fluoride chloride with different chloride/fluoride molar ratios: (0.1‐x) NaF+x NaCl. address anion effect changes geometry, recorded voltammetric fingerprints modified electrodes using lead underpotential deposition (UPD). The analysis suggested that while induces (n10) sites, promotes increase area growth low‐coordinated sites (110) or (111) geometry. Solutions anions induced motifs covered by nanometric clusters, as observed scanning electron microscopy, forming highly defect‐rich surface. Our work provides direct link between electrochemical response ex‐situ structural characterization, compares, detail, nanostructuring

Language: Английский

Citations

1

Multifunctional NiO/Ti3+-TiO2 for concurrent Water Reduction and Glycerol Oxidation to Value added products by Sunlight driven photocatalysis DOI
Sivaraj Rajendran,

Simi Saju,

Sunesh S. Mani

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 25, 2024

Self-doped Ti 3+ containing NiO/Ti –TiO 2 catalysts and their applications towards co-production of H VAPs from a glycerol water mixture by concurrent utilization electrons holes.

Language: Английский

Citations

0